Synthesis and Crystal Structure of Bis[O,O'-di(2-phenylethyl) dithiophosphato](α,α'-bipyridine)copper(Ⅱ)

A ternary adduct Cu[S2P(OCH2CH2Ph)2]2·bipy (bipy=a,a'-bipyridine) was syn-thesized and characterized by elemental analysis,IR and single-crystal X-ray diffraction.The crystal belongs to the trielinic system,space group P(1) with a=10.2320(2),b=11.5249(3),c=18.0916(3) (A),α=98.95(1),β =103.601(1),γ= 91.272(2)°,V= 2044.49(7) (A)3,Z=2,Dc=1.453 g/cm3,T= 153(2) K,C42H44CuN2O4P2S4,Mr= 894.51,λ(MoKa)=0.71073 (A),μ=0.86 mm-1,S=0.999,(△/σ)max=0.002,the final R=0.0243 and wR=0.0704.A total of 9221 unique reflections were collected,of which 8573 with I>2σ(I) were observed.The Cu(Ⅱ) atom is five-coordinated in a rather distorted trigonal bipyramidal geometry (r value=0.537).The Cu-S distances range from 2.3491(4) to 2.4829(4) (A),and the Cu-N distances are 1.9987(12) and 2.0584(11) (A),respectively.An interesting feature of this adduct resides in its two-dimensional (2D) open framework constructing through hydrogen bonding and π-π interactions.     

Optimization of Experimental Discharge Parameters to Increase the Arc Efficiency of the Bucket Ion Source

Arc efficiency is a critical criterion for assessing the performance of the ion source. High are efficiency is necessary for a high power ion source, because it can decrease the load of the arc power supply. Thus the relationship between the discharge parameters （gas pressure, arc voltage, filament current, bias resistance connecting between the anode and plasma grid） and the arc efficiency is investigated in experiment especially. It is found that with increasing pressure, the arc efficiency increases fast if the pressure is below 0.4 Pa, but when it is above 0.4 Pa, the arc efficiency remains unchanged or increases slowly. If we increase the arc voltage or filament current, the arc efficiency decreases. The bias resistance also influences the arc efficiency, at the same pressure the arc efficiency increases with resistance.     

具有相关索赔风险模型的破产概率

本文考虑了具有两类索赔的风险模型,这两类索赔的计数过程是相关的Poisson过程和Erlang过程.通过Laplace变换方法,得到了该风险模型在索赔额为任意分布情形下破产概率的计算公式,并在索赔额为指数分布的情形下,得到了破产概率的精确表达式.     

含有一阶导数的二阶边值问题的正解

应用锥理论和不动点指数方法,获得了一类含有一阶导数的二阶边值问题正解的存在性结果.     

Boundedness of Calderón-Zygmund operators in product Hardy spaces

By means of vector-valued product Calderón-Zygmund operators and some subtle estimates,the boundedness in product Hardy spaces on R^n × R^m of Calderón-Zygmund operators introduced by J.L. Journé is established.     

双需求集货送货一体化车辆路径问题的数学模型及算法

本文研究了具有总时间和车容量约束的双需求集货送货一体化车辆路径问题,在综合考虑运输费用和车辆出行固定费用的前提下,建立了该问题的整数线性规划模型,并分别给出了求解该模型的精确算法和基于节约准则的启发式算法。最后通过一个具体实例验证了算法的有效性。     

基于单目视觉的SLAM算法研究

利用一种新型的人工路标系统-MR二维码,提出了基于单目视觉和里程计的SLAM方法.首先介绍了MR二维码系统,然后在对机器人运动模型和视觉传感器观测模型进行分析和验证的基础上,给出了一种实用的里程计位置估计误差模型.机器人移动过程中,利用扩展卡尔曼滤波器对视觉信息与里程计信息进行融合.在室内环境下进行了实际实验,实验结果表明该算法可提高机器人定位和构建地图的精度,验证了算法的有效性.     

强激光诱导冲击波参数的计算研究

首先简要介绍了强激光诱导冲击波研究的重要性,然后讨论了强激光诱导冲击波的形成机理,在此基础上得到了利用材料的特性参数、激光参数和环境参数计算该冲击波参数的数学模型,并实际计算了激光参数为I_0=0～10~9w/cm~2,τ=15ns,λ=1.06μm,材料为铝时的结果,通过实验验证,其计算结果与其它方法所得结果基本吻合.     

关于随机阶的几个结果

在较弱条件下,对独立随机变量序列的极大值序列,给出了几个关于随机阶的结果.