在反转恢复测试中磁化矢量的演化特征:辐射阻尼效应

在强辐射阻尼存在下,水样(90% H₂O in D₂O)的反转恢复实验表明:当两脉冲的相位相差180°且反转脉冲角<180°时,或两脉冲相位一致但反转脉冲角>180°时,在检测期观测到的信号强度将不发生从负极大值到正极大值的突变;在同样的条件下,如果存在频率偏置,信号强度存在波动,即beating效应.只有当两脉冲的相位一致而反转脉冲角<180°时,或两脉冲的相位相差180°但反转脉冲角>180°时,在检测期信号强度才发生突变,即jumping效应.这些现象都可通过辐射阻尼理论予以合理地解释.另外,在检测期当磁化矢量运动到-z轴附近(对应于τ=T_rdln{tan[(π±δ)/2]}),信号强度与理论预计的偏差实际上与T₁弛豫效应有关.     

The Periodicity of Persistent Currents in Mesoscopic Rings

In a tight-binding model, we find that the equation of the Green's function in a onedimensional mesoscopic ring threaded by a Aharonov-Bohm (AB) flux can be exactly solved. From the poles of the Green's function, the eigenvalues are obtained and are periodic in the AB flux with period h/e. However, the periodicity of the persistent currents is determined by the number of electrons in the ring.     

氢化物发生-原子荧光法测定中药中痕量汞

应用AFS-2202a型双道原子荧光分光光度计和断续流动的氢化物发生技术,采用HNO₃-H₂O₂体系和聚四氟乙烯高压釜消解中药样品,并优化了实验条件,建立了氢化物发生-原子荧光法测定中药中痕量汞。同时,研究了硼氢化钾浓度,光电管负高压,灯电流,原子化器高度,屏蔽气和载气流量等因素对测定结果的影响。在选定实验条件下,汞的检出限为0.021 μg·L-1, 桃叶(GBW08501)验证结果与推荐值一致,6次测定结果相对标准偏差为0.34%。此方法简便、快速、灵敏、准确,以工作曲线法和加入作图法对照,对于实际中药样品的测定得到了满意的结果。     

载体MCM-41对Tb(aspirin)3phen发光性能的影响

在室温下,乙二胺环境中合成了高度有序的介孔材料MCM-41,并将经热处理的发光客体Tb(aspi-rin)3phen组装进其孔道,通过激发发射光谱对其光致发光性能进行了研究。结果表明,Tb(aspirin)3phen240～375 nm区间的宽激发峰归属于配体aspirin羰基n→π*跃迁、苯环π→π*跃迁,和phen的杂菲基团吸收,Tb3 的特征发射是由于Antenna效应引起的。相对于纯Tb(aspirin)3phen,Tb(aspirin)3phen-MCM-41B和Tb(aspirin)3phen/MCM-41A的激发谱带出现了明显的分裂,而Tb(aspirin)3phen-MCM-41A只在353nm处剩下了相对较窄的单峰。Tb(aspirin)3phen-MCM-41B,Tb(aspirin)3phen/MCM-41A和Tb(aspirin)3phen-MCM-41A的短波段激发峰依次减弱消失,长波段激发峰逐渐增强,而405 nm发射峰强度IL和544 nm发射峰强度ILn的比值I(I=IL/ILn)依次减小。MCM-41骨架与Tb(aspirin)3phen成键后,不同程度降低了配体aspirin和phen单重态S1和三重态T1能级,且对phen的影响大于aspirin。不同的MCM-41表面晶格场对配体能级的影响顺序为:MCM-41B外表面>MCM-41A外表面>MCM-41A内表面。I值可定性表示MCM-41表面晶格场对配体能级影响程度和MCM-41表面Tb(aspirin)3phen的含量。     

Measurement of the KLL Dielectronic Recombination Resonances in He-like to C-like Kr Ions

The KLL dielectronic recombination processes of highly charged He-like to C-like Kr ions have been studied experimentally. The measurement was performed on the newly developed Shanghai electron beam ion trap （Shanghai-EBIT） facility. Characteristic x-rays from both dielectronic recombination and radiative recombination are detected as the electron beam energy is scanned through the resonances. The KLL resonant strengths obtained are 5.41×10^-19, 4.33×10^-19, 3.59×10^-19, 2.05×10^-19 and 0.98×10^-19 cm^2 eV for He-like to C-like Kr ions, respectively.     

亚音速轴流压气机转子非轴对称轮毂端壁的数值研究

修改端壁型线是减小二次流损失提高压气机性能的有效方法之一.本文针对某高亚音速压气机转子,首先利用三角函数造型法完成了非轴对称轮毂端壁造型,然后对带非轴对称端壁结构的轴流压气机内部流场进行了详细的数值模拟,数值计算所获得的总性能与试验结果符合较好,该非轴对称轮毂端壁结构的引入能使得压气机的峰值效率提高约0.3285%.详细分析了非轴对称端壁结构对压气机内部流场结构的影响,结果表明:非轴对称轮毂端壁结构的采用能够改善轮毂端壁附近载荷分布,有效地降低叶片通道的二次流流动,从而提高轴流压气机的性能.     

无穷时滞泛函微分方程的正周期解

利用范数形式的锥拉伸和锥压缩不动点定理讨论具有无穷时滞泛函微分方程的周期解问题,获得了正周期解的存在性定理,并给出了定理的若干应用.     

具有相交性质的近小扭转映射的不变环面的保持性

In this paper we investigate the nearly small twist mappings with intersection property. With a certain non-degenerate condition, we proved that the most of invariant tori of the original small twist mappings will survive afer small perturtations. The persisted invariant tori are close to the unperturbed ones when the perturbation are small. The orbits reduced by those mappings are quasi-periodic in the invariant tori with the frequences closing to the original ones.     

Similarity orbits in the Calkin algebra

Let B(H) be the algebra of all bounded linear operators on a complex separable infinite dimensional Hilbert space H.Denote by π the quotient map of B(H) onto the Calkin algebra A(H).In 1984,Apostol et al.raised the following conjecture:If an operator T on H is not similar to a compact perturbation of a Jordan operator,then the similarity orbit of π(T) in A(H) coincides with the π-image of the similarity orbit of T.In this paper,we investigate the structure of similarity orbits in the Calkin algebra and give...     

基于太赫兹技术的药物检测

鉴于太赫兹辐射特有的光谱分辨性、功能性成像特点以及良好的穿透性和安全性等,太赫兹波谱技术迅速成为物质分析与检测等的重要工具。文章基于太赫兹时域光谱技术的实验数据,结合泛函密度理论(DFT)和HIPHOP模型,对一系列降糖类药物进行分子解析和功能基团识别;结合支持向量机理论(SVM),对4种郁金类中草药进行分析识别;并结合差式扫描量热法对葡萄糖—水合物的结晶水状态进行测定;最后对太赫兹时域技术在药物检测方面的优势和不足做了进一步的分析与展望。