Enantioselective Michael addition of 3-ethyl carboxylate substituted pyrazolones to 5-alkenyl thiazolones catalyzed by squaramide organocatalyst

Asymmetric Michael addition between 3-ethyl carboxylate substituted pyrazolones and 5-alkenylthiazolones catalyzed by a series of chiral bifunctional hydrogen bonding organocatalysts was investigated. Good yields (up to 96%) and excellent enantioselectivities (up to 99% ee) were achieved by using a squaramide containing piperidine group derived from (1S, 2S)-cyclohexanediamine. This strategy provides facile access to a diverse library of thiazole-pyrazolone derivatives with potential bioactivity.     

二维准晶的声子及其熔化性质

本文研究具有五次对称性的二维Penrose 准晶的声子及其熔化性质.我们找到了一个相似变换矩阵, 利用它成功地对动力学矩阵进行约化.这约化一方面大大地减少了计算量, 另一方面通过它可解析地得出振动模中有2/3是双重简并的, 而余下的1/ 3 是非简并的结论.利用原子均方位移判据, 我们研究了二维Penrose 准晶格的熔化性质, 得出边界较内部先熔化, 原子间相互作用大的系统不易熔化等合理结论。 关键词：     

延长速调管使用寿命的方法

描述了一种延长EPR波谱仪中速调管使用寿命的方法.根据这种方法,只要正确地调谐微波桥的工作状态和适当地调整功率电平器的功率校正电平.即使对于已经严重老化的速调管仍然可以继续使用一段时间,维持仪器的正常运行.     

Generalized Hopf Bifurcation for Planar Filippov Systems Continuous at the Origin

In this paper, we study the existence of periodic orbits bifurcating from stationary solutions of a planar dynamical system of Filippov type. This phenomenon is interpreted as a generalized Hopf bifurcation. In the case of smoothness, Hopf bifurcation is characterized by a pair of complex conjugate eigenvalues crossing through the imaginary axis. This method does not carry over to nonsmooth systems, due to the lack of linearization at the origin which is located on the line of discontinuity. In fact, generalized Hopf bifurcation is determined by interactions between the discontinuity of the system and the eigen-structures of all subsystems. With the help of geometrical observations for a corresponding piecewise linear system, we derive an analytical method to investigate the existence of periodic orbits that are obtained by searching for the fixed points of return maps.     

磁绝缘传输线电压的初步测量

针对快脉冲直线变压器驱动源装置上的真空磁绝缘传输线（MITL)电压测量的需求,开展了微分型电容分压器和电感分压器的设计、标定和实验。通过不同的电压值、负载阻抗的装置实验中探头输出结果的分析和比较,讨论了测量方法的可行性和适用范围。实验结果表明：微分型电容分压器能够应用于完全磁绝缘状态下的MITL电压测量,但容易受阴极电子发射的影响导致探头输出波形发生畸变。电感分压器受分布电容和电感的影响导致输出信号存在寄生振荡,采用波形重建的方法初步获得了合理的测量结果。     

紫外光电材料ZnO的反应溅射制备及研究

采用直流反应溅射法分别在Si(111),Si(001),及K4玻璃衬底上制备ZnO薄膜,研究了氧氩比、衬底温度以及退火处理对于晶体结晶质量的影响,发现生长过程中的退火处理提高了薄膜质量和晶面取向.通过优化生长条件,在衬底温度为350℃,氧氩比为1:2的条件下生长出了XRD半高宽为01°、C轴取向高度一致的ZnO薄膜.     

MONOTONE ITERATION FOR ELLIPTIC PDEs WITH DISCONTINUOUS NONLINEAR TERMS

In this paper, we use monotone iterative techniques to show the existence of maximal or minimal solutions of some elliptic PDEs with nonlinear discontinuous terms. As the numerical analysis of this PDEs is concerned, we prove the convergence of discrete extremal solutions.     

金属薄膜中的量子尺寸效应

运用最子统计的方法，计算金属薄膜中电子的态密度、电子密度、弛豫时间、计算结果表明：这些物理量都是金属薄膜厚度的函数，且随着薄膜厚度作周期性振荡。     

Effect of the nonlinearity of the CCD in Fourier transform profilometry on spectrum overlapping and measurement accuracy

In Fourier transform profilometry (FTP), we must restrain spectrum overlapping caused by the nonlinearity of the charge coupled device (CCD) and increase the measurement accuracy of the object shape. Firstly, the causes of producing higher-order spectrum components and inducing spectrum overlapping are analysed theoretically, and a simple physical explanation and analytical deduction are given. Secondly, aiming to suppress spectrum overlapping and improve measurement accuracy, the influence of spatial carrier frequency of projection grating on them is analysed. A method of increasing the spatial carrier frequency of projection grating to restrain or reduce the spectrum overlapping significantly is proposed. We then analyze the mechanism of how the spectrum overlapping is reduced. Finally, the simulation results and experimental measurements verify the correction of the proposed theory and method.     

Bound states to critical quasilinear Schr?dinger equations

In this paper, we consider the critical quasilinear Schr?dinger equations of the form