基于偶联反应新极谱法测定痕量亚硝酸根的研究——Ⅱ.以苯酚为偶联试剂

本文研究了苯酚在氨性缓冲溶液中与NO_2~--磺胺重氮盐偶联反应的实验条件,建立了一个灵敏快速测定痕量NO_2~-的新方法。NO_2~-离子浓度在1.0×10~(-10)～4.8×10~(-7)g/ml范围内,与峰高呈良好的线性关系.4000倍量NO_3~-存在不干扰.     

一个具有线性约束的Goldfarb方法的改进算法

本文对具有线性约束的非线性规划问题给出一个Goldfarb方法的改进算法,并且在与[1]同样的条件下,给出了算法之超线性收敛性证明.     

Effect of carbon content on the microstructure and the cracking susceptibility of Fe-based laser-clad layer

The laser cladding of Fe-based alloys on a medium carbon steel substrate was performed using a CO₂ laser and Ar shielding gas that was blown into a molten pool. The microstructure and cracking susceptibility of the laser-clad layers were studied in terms of carbon additions. Results show that the small change of the carbon content in the alloy powders can obviously change the microstructure and properties of the layers. When the carbon content is in the range of 0.3–0.4 wt.%, the decrease of the carbon content in alloy powders will increase the hardness and toughness of the layers simultaneously under the same process parameters. As a result, crack-free coatings with high hardness can be obtained. As the carbon content increases from 0.2 wt.% to 0.4 wt.%, the segregation ratio of chromium increases, while the segregation ratios of nickel, manganese, and silicon first decrease and then increase. At the same time, a new designing principle concerning the composition and microstructure has been put forward, and the principal mechanisms of strengthening and toughening of the layers are fine-grain strengthening and low carbon martensitic phase transformation strengthening.     

全同超形变带转动惯量的粒子数守恒计算

利用推转壳模型的粒子数守恒方法计算了超形变(SD)转动带¹⁹²Hg和¹⁹⁴Hg(1,2,3)的带首转动惯量.分析了带首附近的组态结构及带首转动惯量随对力强度的变化.带首转动惯量之差δJ₀对对力强度十分敏感,而对Nilsson能级参数K、μ及形变参数并不敏感.对力及堵塞效应是造成带首转动惯量差别的主要因素.但与正常形变核相比,对力强度似有较大程度减弱.     

参数曲面保凸的一个定理

本文讨论了参数曲面的凸性，给出了参数曲面为凸的充要条件．并给出了具体的应用实例．     

光电光谱法分析钢中钙

本文研究了用光电光谱法测定钢中钙的方法 ,确定了最佳分析条件 ,分析了共存元素的干扰情况。用本方法测定钢中钙 ,具有良好的准确度和精密度 ,结果令人满意。     

焊接自动化专业引入机器人离线编程的教学探索

机器人焊接已成为焊接自动化技术现代化的主要标志。文中通过阐述机器人离线编程系统的组成原理和主流软件，认为须在焊接自动化专业构筑起机器人离线编程的相关课程体系，才可将机器人离线编程技术引入焊接自动化专业。以此提升焊接自动化的理论和实践教学，提高学生的职业技能。     

四能级原子系统中量子相干增强的Kerr非线性效应的研究

应用密度矩阵方程计算了四能级原子系统中三阶非线性极化率随信号光和探针光频率失谐的变化关系。结果表明，由于量子干涉对信号光强度的敏感性，使四能级原子介质的交叉Kerr非线性作用大大增强，与三能级系统相比，四能级原子介质的Kerr非线性系数可增强两个数量级。     

Numerical analysis of the rotating viscous flow approaching a solid sphere

A numerical simulation is performed to investigate the flow induced by a sphere moving along the axis of a rotating cylindrical container filled with the viscous fluid. Three‐dimensional incompressible Navier–Stokes equations are solved using a finite element method. The objective of this study is to examine the feature of waves generated by the Coriolis force at moderate Rossby numbers and that to what extent the Taylor–Proudman theorem is valid for the viscous rotating flow at small Rossby number and large Reynolds number. Calculations have been undertaken at the Rossby numbers (R_o) of 1 and 0.02 and the Reynolds numbers (R_e) of 200 and 500. When R_o=O(1), inertia waves are exhibited in the rotating flow past a sphere. The effects of the Reynolds number and the ratio of the radius of the sphere and that of the rotating cylinder on the flow structure are examined. When R_o ? 1, as predicted by the Taylor–Proudman theorem for inviscid flow, the so‐called ‘Taylor column’ is also generated in the viscous fluid flow after an evolutionary course of vortical flow structures. The initial evolution and final formation of the ‘Taylor column’ are exhibited. According to the present calculation, it has been verified that major theoretical statement about the rotating flow of the inviscid fluid may still approximately predict the rotating flow structure of the viscous fluid in a certain regime of the Reynolds number. Copyright © 2004 John Wiley & Sons, Ltd.