首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   44637篇
  免费   7556篇
  国内免费   5402篇
化学   31585篇
晶体学   635篇
力学   2756篇
综合类   371篇
数学   5163篇
物理学   17085篇
  2024年   154篇
  2023年   853篇
  2022年   1427篇
  2021年   1517篇
  2020年   1694篇
  2019年   1648篇
  2018年   1445篇
  2017年   1396篇
  2016年   2091篇
  2015年   2090篇
  2014年   2533篇
  2013年   3156篇
  2012年   3814篇
  2011年   4031篇
  2010年   2779篇
  2009年   2711篇
  2008年   3005篇
  2007年   2662篇
  2006年   2559篇
  2005年   2029篇
  2004年   1629篇
  2003年   1394篇
  2002年   1346篇
  2001年   1062篇
  2000年   1047篇
  1999年   982篇
  1998年   831篇
  1997年   763篇
  1996年   741篇
  1995年   667篇
  1994年   571篇
  1993年   462篇
  1992年   457篇
  1991年   365篇
  1990年   327篇
  1989年   255篇
  1988年   229篇
  1987年   188篇
  1986年   171篇
  1985年   166篇
  1984年   107篇
  1983年   78篇
  1982年   68篇
  1981年   40篇
  1980年   19篇
  1979年   13篇
  1978年   4篇
  1977年   3篇
  1975年   4篇
  1957年   4篇
排序方式: 共有10000条查询结果,搜索用时 9 毫秒
181.
This article concerns the existence of global smooth solution for scalar conservation laws with degenerate viscosity in 2-dimensional space. The analysis is based on successive approximation and maximum principle.  相似文献   
182.
The184Au→184Pt decay, studied on-line with the UNISOR facility at HHIRF, is discussed. Gamma-ray and conversion-electron spectroscopy of184Pt as well as on-line nuclear orientation measurements of184Au were done. A new low-lying level scheme of184Pt is proposed. Two coexisting bands with different deformations and their respective γ-vibrational bands are established. Internal conversion coefficients for interband transitions between states with the same spin are extracted from the spectroscopy measurements. The relative E0 contents of the transitions are determined by combining internal conversion coefficients with E2/M1 mixing ratios deduced from gamma-ray anisotropies measured from oriented nuclei.  相似文献   
183.
许志才 《数学杂志》1998,18(4):466-468
设M^n是De Sitter空间S1^n+1中具有常数平均曲率且第二基本形式长度的平方为常数的完备类空超曲面,若S≤2(n-1)^1/2,则M^n是等参超曲面。  相似文献   
184.
氮化硼固相转变的船形模型   总被引:1,自引:1,他引:0       下载免费PDF全文
 船形转变模型是有rBN结构向wBN结构的固相转变模型。在静高压下,相比于以椅形方式,rBN更容易以船形方式转变。  相似文献   
185.
The terephthalate dianion and the bis(imidazolyl)benzene ligand of the title compound, {[Zn(C8H4O4)(C20H14N4)]·C2H6O}n, each bridges two adjacent zinc centers, resulting in a layer‐type coordination polymer; the zinc center shows tetrahedral coordination. The disordered ethanol solvent molecules occupy the spaces between the layers and are hydrogen bonded to the layers. The two symmetry‐independent dianions lie on different inversion sites.  相似文献   
186.
Frame Wavelets with Compact Supports for L^2(R^n)   总被引:1,自引:0,他引:1  
The construction of frame wavelets with compact supports is a meaningful problem in wavelet analysis. In particular, it is a hard work to construct the frame wavelets with explicit analytic forms. For a given n × n real expansive matrix A, the frame-sets with respect to A are a family of sets in R^n. Based on the frame-sets, a class of high-dimensional frame wavelets with analytic forms are constructed, which can be non-bandlimited, or even compactly supported. As an application, the construction is illustrated by several examples, in which some new frame wavelets with compact supports are constructed. Moreover, since the main result of this paper is about general dilation matrices, in the examples we present a family of frame wavelets associated with some non-integer dilation matrices that is meaningful in computational geometry.  相似文献   
187.
On the basis of the crystallographic characteristics of lithium niobate (LN) crystals, Law of Bravais and Pauling's third rule (i.e. Polyhedral Sharing Rule) are employed with the aim to find the relationship between the crystal structure and morphological faces of LN powders. In order to validate our analytical results, we have successfully synthesized LN powders and measured the corresponding X-ray powder diffraction. Our results show that the structural analysis is consistent with the experimental data and is helpful and effective for us to control the single-crystal growth and to design superstructures at the specific plane, starting from the viewpoint of the microscopic behaviors of constituent chemical bonds and polyhedra in the crystallographic frame.  相似文献   
188.
In this contribution, we demonstrate a new effective methodology for constructing highly efficient and durable poly(p‐phenyleneethynylene) (PPE) containing emissive material with nonaggregating and hole‐facilitating properties through the introduction of hole‐transporting blocks into the PPE system as the grafting coils as well as building the energy donor–acceptor architecture between the grafting coils and the PPE backbone. Poly(2‐(carbazol‐9‐yl)ethyl methacrylate) (PCzEMA), herein, is chosen as the hole‐transporting blocks, and incorporated into the PPE system as the grafting coils via atom transfer radical polymerization. The chemical structure of the resultant copolymer, PPE‐g‐PCzEMA, was characterized by NMR and gel permeation chromatography, showing that the desirable copolymer was obtained with the narrow polydispersity. The increased thermal stability of PPE‐g‐PCzEMA was confirmed by thermogravimetric analysis and differential scanning calorimetry along with its macroinitiator. The optoelectronic properties of this copolymer were studied in detail by ultraviolet‐visible absorption, photoluminescence emission and excitation spectra, and cyclic voltammogram (CV). The results indicate that PPE‐g‐PCzEMA exhibits the solid‐state luminescent property dominated by individual lumophores, and also the energy transfer process from the PCzEMA blocks to the PPE backbone with a relatively higher energy transfer efficiency in the solid‐state compared to that of the solution state. Additionally, the hole‐injection property is greatly facilitated due to the presence of PCzEMA, as confirmed by CV profiles. All these data indicate that PPE‐g‐PCzEMA is a good candidate for use in optoelectronic devices. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 3776–3787, 2007  相似文献   
189.
Single-crystal magnetite nanowires with average diameter of ca. 20 nm and length of up to several micrometers were prepared by a simple alkaline surfactant-free hydrothermal process. The crystallinity, purity, morphology, and structural features of the as-prepared magnetite nanowires were investigated by powder X-ray diffraction, transmission electron microscopy (TEM) and selected area electron diffraction. The composition and length of nanowires depends on the pH, with higher pH favoring longer nanowires composed entirely of Fe3O4. A mechanism for nanowire growth is proposed.  相似文献   
190.
一种新型有机电致微腔结构的双模发射   总被引:4,自引:4,他引:0  
采用结构Glass/DBR/ITO/NPB/NPB:Alq/Alq/Al制作了有机微腔电致发光器件。将空穴传输材料与发光材料以一定比例混合作为发光层,为了便于对比,在不改变有机层的膜厚的情况下同时制作了传统的异质结微腔器件,发现两种器件的发光光谱有很大不同,器件的复合效率与传统的异质结器件相比也得到了很大提高,这是因为将两种有机材料混合能消除界面势垒,提高器件的复合效率,从而提高了器件的发光性能,实现了微腔双模发射,且两个模式的半峰全宽分别为8nm和12nm。通过进一步优化器件结构可以实现微腔白光发射。  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号