N-十一烷基-N′-(对氨基苯磺酸钠)硫脲光度法测定铜

研究了新显色剂长链饱和脂肪烃取代基化合物 (UPT)和微量 Cu2 反应。试验表明 ,在p H5.2～ 5.6的乙酸 -乙酸钠介质中 ,Cu2 与试剂形成摩尔比为 1∶ 3的淡黄绿色稳定络合物 ,其最大吸收为 30 0 .4nm,表观摩尔吸光系数为 ε30 0 .4 nm=2 .39× 1 0 5L·mol-1·cm-1。铜浓度在 2～ 1 2 μg/2 5ml的范围内符合比耳定律 ,相关系数 r=0 .9990。方法简便、灵敏 ,应用于样品测定 ,结果满意     

CuO／γ—Al2O3上CO和NO吸附的红外光谱研究：Ⅱ.还原态

应用红外光谱技术研究了CO和NO及其混合气体在还原态CuO/γ-Al_2O_3上的吸附.XRD分析样品物相仅有Cu~0,但是,XPS和IR都证明样品表面上除Cu~0外,还有Cu~(2+)和Cu~+。CO以分子态的形式吸附在Cu~+和Cu~0上(低于173K,无NO存在时,CO可以吸附在Cu~(2+)上);NO以分子态吸附在Cu~(2+)上,在Cu~0上为离解吸附(173K以下,无CO存在时,NO可以吸附在Cu~+上)。CO吸附时,表面还生成HCO_3~-、CO_3~(2-)、HCOO~-,NO吸附时,除被氧化为NO3~-外,表面上还出现N_2O物种;高于室温时,CO和NO共吸附,表面上除生成HCO_3~-、CO_3~(2-)和N_2O外,还有NCO~-物种生成,讨沦了CO和NO反应的基本步骤。     

Sol–gel silica antireflective coating with enhanced abrasion-resistance using polypropylene glycol as porogen

Silica antireflective (AR) coatings with high transmittance and enhanced abrasion-resistance were synthesized by sol–gel process using polypropylene glycol (PPG) as porogen. The effects of molecular weight of PPG and weight ratio of PPG to SiO₂ on the refractive index and abrasion-resistance of the coating were systematically studied and compared with those of polyethylene glycol (PEG). Experimental data showed that the refractive index decreased with increasing the weight ratio to SiO₂ and molecular weight of both PEG and PPG, but PPG was much more effective than PEG. In the case of same molecular weight, PPG modified coating has the higher porosity than PEG modified one. When the weight ratio of PPG to SiO₂ is in a low level, the PPG-containing silica AR coatings exhibit the good abrasion-resistance. PPG is liquid at room temperature and the better solubility than PEG. These effective and economic AR coatings with enhanced abrasion-resistance have potential value in the field of solar thermal collectors.     

Armor-like Inorganic-rich Cathode Electrolyte Interphase Enabled by the Pentafluorophenylboronic Acid Additive for High-voltage Li||NCM622 Batteries

Lithium metal batteries (LMBs) comprising Li metal anode and high-voltage nickel-rich cathode could potentially realize high capacity and power density. However, suitable electrolytes to tolerate the oxidation on the cathode at high cut-off voltage are urgently needed. Herein, we present an armor-like inorganic-rich cathode electrolyte interphase (CEI) strategy for exploring oxidation-resistant electrolytes for sustaining 4.8 V Li||LiNi_0.6Co_0.2Mn_0.2O₂ (NCM622) batteries with pentafluorophenylboronic acid (PFPBA) as the additive. In such CEI, the armored lithium borate surrounded by CEI up-layer represses the dissolution of inner CEI moieties and also improves the Li⁺ conductivity of CEI while abundant LiF is distributed over whole CEI to enhance the mechanical stability and Li⁺ conductivity compared with polymer moieties. With such robust Li⁺ conductive CEI, the Li||NCM622 battery delivered excellent stability at 4.6 V cut-off voltage with 91.2 % capacity retention after 400 cycles. The excellent cycling performance was also obtained even at 4.8 V cut-off voltage.     

CeCl3/Sm System Induced Reductive Cleavage of the Se‐Se Bond in Diaryl Diselenides: A Novel Method for the Synthesis of β‐Selenoesters and β‐Selenonitriles

The Se‐Se bond in diselenides was reduced by CeCl₃/Sm system to produce selenolate anions, which react with α,β‐unsaturated esters or α,β‐unsaturated nitriles to afford β‐selenoesters and β‐selenonitriles, respectively.     

Preparation of Water-suspensible Carbon Nanoparticles and Their Influence on the Properties of Epoxidized Natural Rubber Latex

A new kind of water-suspensible carbon nanoparticle was prepared by oxidizing carbon black (CB) using aqueous ammonium persulfate (APS) as an oxidant. The obtained water-suspensible carbon nanoparticles (APS-CBs) were still homogeneously distributed in water three weeks after sonication. Fourier transform infrared spectroscopy (FTIR) and thermogravimetric analysis (TGA) were employed to characterize the changes of the oxygen containing functional groups on the surfaces of the APS-CBs. Furthermore, a high performance of an epoxidized natural rubber latex (ENRL)/APS-CBs composite was obtained by a liquid latex blending method. The carbon nanoparticles were homogeneously distributed in the matrix. In comparison with the ENRL/pristine CBs composites, the APS-CBs improved the mechanical properties of the ENRL/APS-CBs composites. The dynamic rheological properties were also studied.     

A Convenient Method for the Preparation of Carbonyl Diazo Compounds from Aryl Substituted Carbazide

A new simple method for the preparation of bis (substituted phenyl) carbodiazone compounds (ArN=NCON=NAr) is reported. Nine of the compounds were synthesized by the oxidation of aryl substituted carbazide with ferric chloride in acid medium with good yield.     

C-ADS超导轮辐腔Spoke021的电磁设计与优化

为满足C-ADS项目建设对超导轮辐腔Spoke021的需求,对Spoke021进行了详细的电磁参数优化。对Spoke021的参数化模型进行参数扫描,针对腔体的关键电磁特征量寻找可能存在的极值,详细分析、解释了优化过程中各个参数发生变化的物理意义。在Spoke021各参数达到最终优化值时,表征腔体性能的两个关键比值分别为:E_p/E_(acc)=3.14,Bp/E_(aCC)=4.77 mT/(MV/m)。考虑到次级电子倍增(Multipacting,MP)对Spoke021运行中所能达到的性能指标有很重要影响,对腔体的MP进行了建模分析。结果表明,当Spoke021工作在E_(acc)=10 MV/m情况下,没有发生MP,优化得到的参数可以满足Spoke021工程设计的需要;最后计算了腔体的TTF曲线,表明该腔体具有较宽的速度接受度。