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排序方式: 共有119条查询结果,搜索用时 31 毫秒
11.
本文报告了明渠非定常水流垂向结构的实验研究,通过 LDV 激光测速,我们给出了非定常水流的速度削面,湍流度,Eulerian质量输运速度的垂向分布。实验结果表明:在非定常周期很长时非定常流动的速度剖面,湍流强度及其粗糙度的影响基本上与定常流动相一致,当非定常流动为纯往复流动时,存在一个逆时针方向的环流,这种环流有利于底部的质量输运。 相似文献
12.
本文将两相流动的雷诺方程沿深度方向进行平均,出求了平均后的运动方程、连续方程和能量方程式,在适当的物理假定下,简化得到可适用于考虑固-液流动及气-液流动两种情况下的两相层状流动基本方程. 相似文献
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In this paper, the differences of turbulent coherent structure between the smooth and rough boundary layers are analysed. Based on the discussing the transient properties from the smooth wall to the rough wall, the physical model of coherent structure for the rough boundary layer are established. The width of slowly-moving turbulent spot and the bursting time are obtained, which are in agreement with experimental results.The project supported by the National Nature Science Foundation of China 相似文献
15.
Bo?Xiao Yulu?Zhang XinXiang?Zhang Haibing?Lv Lianghong?Yan Bo?JiangEmail author 《Journal of Sol-Gel Science and Technology》2011,60(1):11-16
The poly(isopropylene oxide) glycerolether (PO) modified silica antireflective (AR) coating films were prepared by sol–gel
method. The properties of the silica sols and AR films were characterized by particle size analyzer, transmission electron
microscope, UV–Vis spectro-photometry, spectroscopic ellipsometer and contact angle measurement. The results show that PO
addition has inconspicuous effect on the transmittance of AR coatings; the maximum transmittance reached 99.5%. Thicknesses
of films increase and refractive index decrease with increase of PO concentration. The contact angle with water for the silica
films with and without PO was 68.5o and 28.5o, respectively, which indicates an increase of hydrophobicity of the modified coating. When the films were placed in 95% relative
humidity at room temperature for 30 days, transmittance loss for the unmodified and modified silica films were 2.5 and 0.6%
respectively. Moisture-resistance of the film is greatly improved by PO addition. 相似文献
16.
本文报道了五种新的芳氨基硫脲类化合物,即1-(4-溴-2-羧基苯基)-4-烷基氨基硫脲的电子轰击质谱(EIMS)。结果表明,该类化合物的分子离子峰(M+)很弱,但却具有效强的[M-H]+峰。分子离子的断裂以N-N键和C-N键的断裂为主,并伴随着六员环或四员环过渡态氢重排,生成相应的芳氨基正离子和芳肼基正离子,这两种离子继续失水或失其它小分子,从而形成一系列特征离子,包括骨架重排离子。 相似文献
17.
Qiuying Li Yulu Ma Chifei Wu Shengying Qian 《Journal of Macromolecular Science: Physics》2013,52(5):837-846
The influence of the basic properties of carbon black, such as structure, panicle size, and surface activity on the vulcanization and mechanical properties of filled natural rubber compounds was investigated in detail. This is important for a better understanding of the rubber performance and the mechanism of reinforcement. In particular, the effect of carbon black surface activity, which was changed by introducing one kind of hindered amine light stabilizer on rubber reinforcement is emphasized. 相似文献
18.
Yulu Jiang Dr. Taro Ozaki Mei Harada Tadachika Miyasaka Dr. Hajime Sato Dr. Kazunori Miyamoto Dr. Junichiro Kanazawa Dr. Chengwei Liu Prof. Dr. Jun-ichi Maruyama Dr. Masaatsu Adachi Dr. Atsuo Nakazaki Prof. Dr. Toshio Nishikawa Prof. Dr. Masanobu Uchiyama Dr. Atsushi Minami Prof. Dr. Hideaki Oikawa 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(41):18152-18158
Lolitrems are tremorgenic indole diterpenes that exhibit a unique 5/6 bicyclic system of the indole moiety. Although genetic analysis has indicated that the prenyltransferase LtmE and the cytochrome P450 LtmJ are involved in the construction of this unique structure, the detailed mechanism remains to be elucidated. Herein, we report the reconstitution of the biosynthetic pathway for lolitrems employing a recently established genome-editing technique for the expression host Aspergillus oryzae. Heterologous expression and bioconversion of the various intermediates revealed that LtmJ catalyzes multistep oxidation to furnish the lolitrem core. We also isolated the key reaction intermediate with an epoxyalcohol moiety. This observation allowed us to establish the mechanism of radical-induced cyclization, which was firmly supported by density functional theory calculations and a model experiment with a synthetic analogue. 相似文献
19.
Jiadong Chen Yulu Zhang Prof. Dr. Shengbiao Tang Prof. Dr. Ying Shao Prof. Dr. Jiangtao Sun 《European journal of organic chemistry》2023,26(32):e202300605
One-step process for the preparation of a 1,3-dienyl-5-ester motif from readily available substrate remains a challenging work in organic synthesis. We herein report the first example of C5-regioselective esterification of unactivated dienyl alcohols, using free carboxylic acids as nucleophiles under mild conditions, providing a series of 1,3-dienyl-5-ester compounds in excellent regioselectivity and E-selectivity. 相似文献
20.
Formaldehyde decomposition is not only an attractive method for hydrogen production, but also a potential approach for gaseous formaldehyde removal. In this research, we prepare some assembled organoruthenium through coordination reaction between Ru(p-Cymene)Cl2 and bridge-linking ligands. It is a creative approach for Ru(p-Cymene)Cl2 conversion into heterogeneous particles. The rigidity of bridge-linking ligand enables assembled organoruthenium to have highly ordered crystalline structure, even show clear crystal lattice with spacing of 0.19 nm. XPS shows the N−Ru bond are formed between bridge-linking ligand and Ru(p-Cymene)Cl2. The assembled organoruthenium has high abundant active sites for formaldehyde decomposition at low temperature. The reaction rate could increase linearly with temperature and formaldehyde concentration, with a TOF of 2420 h−1 at 90 °C. It is promising for gaseous formaldehyde decomposition in wet air or nitrogen. Formaldehyde conversion is up to 95 % over Ru-DAPM is 4,4′-diaminodiphenylmethane at 90 °C in air. Gaseous formaldehyde decomposition is a two-steps process under oxygen-free condition. Firstly, formaldehyde dissolve in water, and be converted into hydrogen and formic acid through formaldehyde-water shift reaction. Then intermediate formic acid will further decompose into hydrogen and carbon dioxide. We also find formaldehyde decomposition is a synergetic catalysis process of oxygen and water in moist air. Oxygen is conducive to formic acid desorption and decomposition on the active sites, so assembled organoruthenium exhibit slightly higher conversion for formaldehyde decomposition in moist air. This work proposes a distinctive method for gaseous formaldehyde decomposition in the air, which is entirely different from formaldehyde photocatalysis or thermocatalysis oxidation. 相似文献