零视距地物长波红外特征场景仿真研究

为仿真地物长波红外场景图像,根据地表温度随时间变化的规律,并结合气象状况、背景材质、热特性参量、热状态等参数,在对太阳辐射、大气长波辐射、大气温度和地表热传导等影响地表温度变化的因素进行分析的基础上,建立了基于热平衡理论和热传导过程的方程。解算出多种常见地表一日之中的温度变化情况,并将其应用于由相同景物可见光纹理图像反演出的相应红外纹理图像中。在考虑景物表面自身发射、反射的辐射计算模型的前提下,生成了具有相似红外纹理细节的地表红外场景。结果表明,该方法可生成接近真实感的红外场景,有效地模拟仿真地物的长波红外特征。     

Optimizing GaN photocathode structure for higher quantum efficiency

To improve the quantum efficiency of GaN photocathode, we optimized the photocathode's structure in three aspects. We use AlN replacing GaN as the buffer layer, which can act as potential barrier to reflect electrons back to surface. The optimal thickness of emission layer is calculated as 162.5 nm, and considering the graded doping profile, we optimized the thickness as 180 nm. Three built-in electric fields are introduced by Mg graded dope, and the intensities of the high fields are calculated to give the quantitive results of their influence. After surface cleaning and activation, quantum efficiency of the optimized sample was increased and the highest value of 56% was achieved at 240 nm. More quantum efficiency enhancement is possible by further optimizing the photocathode structure.     

消色差相位型超分辨光瞳滤波器的设计研究

提出并设计了一种消色差的相位型超分辨光瞳滤波器。详细分析了滤波器的设计参数对成像系统的光斑压缩比和斯特雷尔比影响。分别以方解石晶体和石英玻璃材料为例进行了设计,当光斑压缩比为0.83时,得到两种材料的消色差超分辨光瞳滤波器,可以分别在380～555nm和300～600nm的波长范围内实现消色差,同时可以有较高的斯特雷尔比。     

First principle study of the influence of vacancy defects on optical properties of GaN

We employ plane-wave with ultrasoft pseudopotential method to calculate and compare the total density of states and partial density of states of bulk-phase GaN,Ga0.9375 N,and GaN0.9375 systems based on the first-principle density-functional theory(DFT).For Ga and N vacancies,the electronic structures of their neighbor and next-neighbor atoms change partially.The Ga0.9375 N system has n-type semiconductor conductive properties,whereas the GaN0.9375 system has p-type semiconductor conductive properties.By studying the optical properties,the influence of Ga and N vacancy defects on the optical properties of GaN has been shown as mainly in the low-energy area and very weak in high-energy area.The dielectric peak influenced by vacancy defects expands to the visible light area,which greatly increases the electronic transition in visible light area.     

Minimal Active Space for Diradicals Using Multistate Density Functional Theory

This work explores the electronic structure as well as the reactivity of singlet diradicals, making use of multistate density functional theory (MSDFT). In particular, we show that a minimal active space of two electrons in two orbitals is adequate to treat the relative energies of the singlet and triplet adiabatic ground state as well as the first singlet excited state in many cases. This is plausible because dynamic correlation is included in the first place in the optimization of orbitals in each determinant state via block-localized Kohn–Sham density functional theory. In addition, molecular fragment, i.e., block-localized Kohn–Sham orbitals, are optimized separately for each determinant, providing a variational diabatic representation of valence bond-like states, which are subsequently used in nonorthogonal state interactions (NOSIs). The computational procedure and its performance are illustrated on some prototypical diradical species. It is shown that NOSI calculations in MSDFT can be used to model bond dissociation and hydrogen-atom transfer reactions, employing a minimal number of configuration state functions as the basis states. For p- and s-types of diradicals, the closed-shell diradicals are found to be more reactive than the open-shell ones due to a larger diabatic coupling with the final product state. Such a diabatic representation may be useful to define reaction coordinates for electron transfer, proton transfer and coupled electron and proton transfer reactions in condensed-phase simulations.     

Vacancy defect influences on optoelectronic properties for In0.875Ga0.125As0.25P0.75: a first-principles study

Optical Review - InGaAsP photocathodes show great potential for near-infrared applications, particularly at 1.06 μm. However, vacancy defects are unavoidable in InGaAsP crystals...     

Synthesis of {CB11} Monocarborane Sulfonamides by B2-Selective Rhodium-Catalyzed B−H Activation

The synthesis of monocarborane sulfonamides is reported. The methodology relies on coupling of the anionic {CB₁₁} boron cluster to sulfonyl azides. Under rhodium catalysis and with the assistance of a pyridine or pyrimidine directing group at the C1 position, the cluster undergoes B−H activation. Conditions have been identified that lead to B2-selective mono-sulfonamidation with concomitant loss of N₂. The protocol requires no additional ligand, oxidant or base and enables B−N bond formation with various monocarborane and sulfonyl azide inputs. The new products possess the structure [1-(heteroaryl)-2-(NHSO₂Ar)−CB₁₁H₁₀]⁻ and have been fully characterized by NMR spectroscopy and mass spectrometry. In addition, three solid state structures confirm the particular B2 substitution pattern. Furthermore, the stoichiometric reaction of the pyridinyl monocarborane precursor with Rh(III) affords a cyclometalated complex with a direct B−Rh bond that has also been characterized by X-ray crystallography.     

Hyperbranched Polyborosiloxanes: Non-traditional Luminescent Polymers with Red Delayed Fluorescence

Non-traditional fluorescent polymers have attracted significant attention for their excellent biocompatibility and diverse applications. However, designing and preparing non-traditional fluorescent polymers that simultaneously possess long emission wavelengths and long fluorescence lifetime remains challenging. In this study, a series of novel hyperbranched polyborosiloxanes (P1–P4) were synthesized. As the electron density increases on the monomer diol, the optimal emission wavelengths of the P1–P4 polymers gradually red-shift to 510, 570, 575, and 640 nm, respectively. In particular, P4 not only exhibits red emission but also demonstrates delayed fluorescence with a lifetime of 9.73 μs and the lowest critical cluster concentration (1.76 mg/mL). The experimental results and theoretical calculations revealed that the synergistic effect of dual heteroatom-induced electron delocalization and through-space O⋅⋅⋅O and O⋅⋅⋅N interaction was the key factor contributing to the red-light emission with delayed fluorescence. Additionally, these polymers showed excellent potential in dual-information encryption. This study provides a universal design strategy for the development of unconventional fluorescent polymers with both delayed fluorescence and long-wavelength emission.     

森林公园声景对心理恢复效益的影响——以福州国家森林公园为例

声景是森林公园恢复性环境的重要组成部分。该研究以福州国家森林公园为例，其20个森林公园环境视听视频为研究材料(有声视频和无声视频各10个)，借助短版修订恢复量表和声景感知评价问卷探究森林公园声景对心理恢复效益的影响。结果表明：不同森林公园环境心理恢复效益不同，在综合恢复性评价、认知和行为维度上有显著差异；除谈话声和儿童嬉戏声较突出的样地(S5)外，视听组合刺激促进心理恢复的能力均比单一视觉刺激强；声景感知与综合恢复性评价及情感、认知和行为维度的最优尺度回归模型具有统计学意义，鸟鸣声、蝉鸣声、流水声等自然声是心理恢复效益的重要预测变量，对心理恢复有积极影响。基于研究结果提出森林公园恢复性声景设计策略，为森林公园恢复性声环境的优化设计提供参考思路。     

Durable High-Temperature Proton Exchange Membrane Fuel Cells Enabled by the Working-Temperature-Matching Palladium-Hydrogen Buffer Layer

The durability degradation during stack-operating conditions seriously deteriorates the lifetime and performance of the fuel cell. To alleviate the rapid potential rise and performance degradation, an anode design is proposed to match the working temperature of high-temperature proton exchange membrane fuel cells (HT-PEMFCs) with the release temperature of hydrogen from palladium. The result is significantly enhanced hydrogen oxidation reaction (HOR) activity of Pd and superior performance of the Pd anode. Furthermore, Pd as hydrogen buffer and oxygen absorbent layer in the anode can provide additional in situ hydrogen and absorb infiltrated oxygen during local fuel starvation to maintain HOR and suppress reverse-current degradation. Compared with the traditional Pt/C anode, the Pd/C also greatly improved HT-PEMFCs durability during start-up/shut-down and current mutation. The storage/release of hydrogen provides innovative guidance for improving the durability of PEMFCs.