全文获取类型
收费全文 | 178篇 |
免费 | 13篇 |
国内免费 | 10篇 |
专业分类
化学 | 120篇 |
力学 | 15篇 |
综合类 | 1篇 |
数学 | 9篇 |
物理学 | 56篇 |
出版年
2024年 | 3篇 |
2023年 | 23篇 |
2022年 | 20篇 |
2021年 | 29篇 |
2020年 | 30篇 |
2019年 | 11篇 |
2018年 | 7篇 |
2017年 | 6篇 |
2016年 | 10篇 |
2015年 | 3篇 |
2014年 | 7篇 |
2013年 | 11篇 |
2012年 | 6篇 |
2011年 | 7篇 |
2010年 | 1篇 |
2009年 | 3篇 |
2008年 | 7篇 |
2007年 | 2篇 |
2006年 | 3篇 |
2005年 | 2篇 |
2004年 | 2篇 |
1999年 | 3篇 |
1998年 | 1篇 |
1996年 | 1篇 |
1994年 | 2篇 |
1957年 | 1篇 |
排序方式: 共有201条查询结果,搜索用时 15 毫秒
81.
82.
83.
Xixin Zhang Yuhang Yang Zhiyong Li Xin Ning Yilang Qin Weiwei Cai 《Entropy (Basel, Switzerland)》2021,23(4)
In the research of green vegetation coverage in the field of remote sensing image segmentation, crop planting area is often obtained by semantic segmentation of images taken from high altitude. This method can be used to obtain the rate of cultivated land in a region (such as a country), but it does not reflect the real situation of a particular farmland. Therefore, this paper takes low-altitude images of farmland to build a dataset. After comparing several mainstream semantic segmentation algorithms, a new method that is more suitable for farmland vacancy segmentation is proposed. Additionally, the Strip Pooling module (SPM) and the Mixed Pooling module (MPM), with strip pooling as their core, are designed and fused into the semantic segmentation network structure to better extract the vacancy features. Considering the high cost of manual data annotation, this paper uses an improved ResNet network as the backbone of signal transmission, and meanwhile uses data augmentation to improve the performance and robustness of the model. As a result, the accuracy of the proposed method in the test set is 95.6%, mIoU is 77.6%, and the error rate is 7%. Compared to the existing model, the mIoU value is improved by nearly 4%, reaching the level of practical application. 相似文献
84.
针对BT20钛合金锻件当量孔损伤进行激光沉积修复试验,考察了修复试样的组织和力学特点。修复区与基材之间形成了致密冶金结合,Al,Zr,Mo,V合金元素由锻件基体到激光修复区均匀分布,无宏观偏析,硬度分布从基材到修复区依次提高。热影响区组织是由基材的双态组织过渡到网篮组织;修复区组织为粗大的原始柱状β晶,晶粒内为α/β网篮组织,晶内α片层取向随机,宽0.4~0.5μm。修复过程中发现,激光加工工艺参数选择不当、坡度过大等原因会造成修复区组织形成气孔和熔合不良等缺陷,但是通过优化工艺参数可以获得无缺陷修复试样。修复试样的室温静拉伸结果表明,试样的抗拉强度接近锻件基体强度,但修复件的韧性比锻件稍有提高。 相似文献
85.
86.
We demonstrate Mach-Zehnder interferometers (MZI) assembled using optical microfibers or nanofibers (MNFs) drawn from silica fibers and tellurite glasses. As-assembled MZIs, with dimensions of tens to hundreds of micrometers, show good interference fringes with extinction ratios of approximately 10 dB. The path-length difference of the MZI can be tuned by micromanipulation under an optical microscope. The MNF-assembled MZIs demonstrated here show advantages of easy fabrication, in situ tunability, and compact size. 相似文献
87.
Wei Zhang Yuhang Dai Ruwei Chen Zhenming Xu Jianwei Li Wei Zong Huangxu Li Zheng Li Zhenyu Zhang Jiexin Zhu Fei Guo Xuan Gao Zijuan Du Jintao Chen Tianlei Wang Guanjie He Ivan P. Parkin 《Angewandte Chemie (International ed. in English)》2023,62(5):e202212695
Aqueous zinc-ion batteries have drawn increasing attention due to the intrinsic safety, cost-effectiveness and high energy density. However, parasitic reactions and non-uniform dendrite growth on the Zn anode side impede their application. Herein, a multifunctional additive, ammonium dihydrogen phosphate (NHP), is introduced to regulate uniform zinc deposition and to suppress side reactions. The results show that the NH4+ tends to be preferably absorbed on the Zn surface to form a “shielding effect” and blocks the direct contact of water with Zn. Moreover, NH4+ and (H2PO4)− jointly maintain pH values of the electrode-electrolyte interface. Consequently, the NHP additive enables highly reversible Zn plating/stripping behaviors in Zn//Zn and Zn//Cu cells. Furthermore, the electrochemical performances of Zn//MnO2 full cells and Zn//active carbon (AC) capacitors are improved. This work provides an efficient and general strategy for modifying Zn plating/stripping behaviors and suppressing side reactions in mild aqueous electrolyte. 相似文献
88.
Runtian Zheng Yuhang Li Dr. Haoxiang Yu Xikun Zhang Dr. Ding Yang Dr. Lei Yan Prof. Yu Li Prof. Jie Shu Prof. Bao-Lian Su 《Angewandte Chemie (International ed. in English)》2023,62(23):e202301629
Ammonium-ion batteries (AIBs) have recently attracted increasing attention in the field of aqueous batteries owing to their high safety and fast diffusion kinetics. The NH4+ storage mechanism is quite different from that of spherical metal ions (e.g. Li+, Na+, K+, Mg2+, and Zn2+) because of the formation of hydrogen bonds between NH4+ and host materials. Although many materials have been proposed as electrode materials for AIBs, their performances hardly meet the requirement of future electrochemical energy storage devices. It is thus urgent to design and exploit advanced materials for AIBs. This review highlights the state-of-the-art research on AIBs. The insights into the basic configuration, operating mechanism and recent progress of electrode materials and corresponding electrolytes for AIBs have been comprehensively outlined. The electrode materials are classified and compared according to different NH4+ storage behaviour in the structure. The challenges, design strategies and perspectives are also discussed for the future development of AIBs. 相似文献
89.
Tian Wang Jiadong Chen Xinyi Ren Jincheng Zhang Jie Ding Yuhang Liu Kang Hui Lim Junhu Wang Xuning Li Hongbin Yang Yanqiang Huang Sibudjing Kawi Bin Liu 《Angewandte Chemie (International ed. in English)》2023,62(10):e202211174
Electrochemically reducing CO2 to valuable fuels or feedstocks is recognized as a promising strategy to simultaneously tackle the crises of fossil fuel shortage and carbon emission. Sn-based catalysts have been widely studied for electrochemical CO2 reduction reaction (CO2RR) to make formic acid/formate, which unfortunately still suffer from low activity, selectivity and stability. In this work, halogen (F, Cl, Br or I) was introduced into the Sn catalyst by a facile hydrolysis method. The presence of halogen was confirmed by a collection of ex situ and in situ characterizations, which rendered a more positive valence state of Sn in halogen-incorporated Sn catalyst as compared to unmodified Sn under cathodic potentials in CO2RR and therefore tuned the adsorption strength of the key intermediate (*OCHO) toward formate formation. As a result, the halogen-incorporated Sn catalyst exhibited greatly enhanced catalytic performance in electrochemical CO2RR to produce formate. 相似文献
90.
Tao Zhong Chengyihan Gu Yuhang Li Jun Huang Jian Han Prof. Dr. Chengjian Zhu Jie Han Prof. Dr. Jin Xie 《Angewandte Chemie (International ed. in English)》2023,62(42):e202310762
The involvement of manganese radical for halogen atom transfer (XAT) reactions has been esteemed as one reliable method but encountered with limited catalytic models. In this paper, a novel bimetallic relay catalysis of Mn2(CO)10 and cobaloxime has been developed for divergent dehydrogenative difluoroalkylation of alkenes using commercially available difluoroalkyl bromides. A wide range of structurally diverse terminal, cyclic and internal alkenes as well as tetrasubstituted alkenes are found to be good coupling partners to deliver difluoroalkylated allylic products and difluoromethylated cyclic products, accompanied with the production of H2 as the by-product. This bimetallic relay strategy features broad substrate scope, mild reaction conditions and excellent functional group compatibility. Its success represents an important step-forward to expedite the construction of a rich library of difluoroalkylated products. 相似文献