排序方式: 共有47条查询结果,搜索用时 15 毫秒
21.
Dr. Yufeng Luo Dr. Zhenhan Fang Dr. Shaorong Duan Hengcai Wu Dr. Haitao Liu Dr. Yuxing Zhao Dr. Ke Wang Prof. Qunqing Li Prof. Shoushan Fan Prof. Zijian Zheng Prof. Wenhui Duan Prof. Yuegang Zhang Prof. Jiaping Wang 《Angewandte Chemie (International ed. in English)》2023,62(11):e202215802
The polysulfide (PS) dissolution and low conductivity of lithium sulfides (Li2S) are generally considered the main reasons for limiting the reversible capacity of the lithium-sulfur (Li-S) system. However, as the inevitable intermediate between PSs and Li2S, lithium disulfide (Li2S2) evolutions are always overlooked. Herein, Li2S2 evolutions are monitored from the operando measurements on the pouch cell level. Results indicate that Li2S2 undergoes slow electrochemical reduction and chemical disproportionation simultaneously during the discharging process, leading to further PS dissolution and Li2S generation without capacity contribution. Compared with the fully oxidized Li2S, Li2S2 still residues at the end of the charging state. Therefore, instead of the considered Li2S and PSs, slow electrochemical conversions and side chemical reactions of Li2S2 are the determining factors in limiting the sulfur utilization, corresponding to the poor reversible capacity of Li-S batteries. 相似文献
22.
The presence of cocaine on US paper currency has been known for a long time. Banknotes become contaminated during the exchange, storage, and abuse of cocaine. The analysis of cocaine on various denominations of US banknotes in the general circulation can provide law enforcement circles and forensic epidemiologists objective and timely information on epidemiology of illicit drug use and on how to differentiate money contaminated in the general circulation from banknotes used in drug transaction. A simple, nondestructive, and accurate capillary gas chromatographic method has been developed for the determination of cocaine on various denominations of US banknotes in this study. The method comprises a fast ultrasonic extraction using water as a solvent followed by a SPE cleanup process with a C(18) cartridge and capillary GC separation, identification, and quantification. This nondestructive analytical method has been successfully applied to determine the cocaine contamination in US paper currency of all denominations. Standard calibration curve was linear over the concentration range from the LOQ (2.00 ng/mL) to 100 microg/mL and the RSD less than 2.0%. Cocaine was detected in 67% of the circulated banknotes collected in Southeastern Massachusetts in amounts ranging from approximately 2 ng to 49.4 microg per note. On average, $5, 10, 20, and 50 denominations contain higher amounts of cocaine than $1 and 100 denominations of US banknotes. 相似文献
23.
A rapid, accurate and reliable analytical method was developed for the simultaneous determination of five major anthraquinones, aloe-emodin, chrysophanol, emodin, physcion, and rhein, in radix Polygoni multiflori, a traditional Chinese herbal medicine. The method comprises a fast ultrasonic extraction with methanol and derivatization with N,O-bis(trimethylsilyl)trifluoroacetamide (BSTFA)+1% trimethylchlorosilane (TMCS) followed by capillary gas chromatographic (GC) separation. The effect of reaction time on the derivatization of anthraquinones was examined. A baseline separation of the anthraquinone and internal standard derivatives was achieved in 15min. The detection limits range from 0.22 to 0.60microg/mL for the five anthraquinones. The calibration curves are linear over the concentration range studied (from the detection limits to 40.0microg/mL) with the squares of correlation coefficients, R2, greater than 0.998. The developed method was successfully applied to the simultaneous determination of anthraquinones in radix P. multiflori samples. The peak identification was confirmed using GC-MS. The contents of anthraquinones in radix P. multiflori samples studied were 27.41, 289.6, 64.22, 202.1, 288.6microg/g for chrysophanol, emodin, aloe-emodin, physcion, rhein, respectively. All relative standard deviations are less than 3.2%. The recoveries range from 80.2% to 119.3% for the five analytes. To the authors' best knowledge, this is the first GC method reported for the simultaneous determination of the five anthraquinones in radix P. multiflori. 相似文献
24.
Deng L Wu F Deng N Zuo Y 《Journal of photochemistry and photobiology. B, Biology》2008,91(2-3):117-124
The photochemical and biological reduction of Hg(II) in the presence of algae, anabaena cylindrical, was investigated under the irradiation of metal halide lamps placed in cooling trap for maintaining constant temperature by water circulation (lambda >or=365 nm, 250 W). The photoreduction rate of Hg(II) increased with increasing algae concentration. The addition of Fe(III) and humic substances into the suspensions of algae also enhanced the photoreduction of Hg(II). Alteration of pH value affected the photoreduction of Hg(II) in aqueous solution with or without the addition of algae. The concentration of dissolved gaseous mercury (DGM), the reduced product of Hg(II), increased with increasing exposure time and then gradually approached to a steady state. The influence of initial Hg(II) concentration on the photoreduction of Hg(II) with algae was studied by irradiating the suspensions of anabaena cylindrical at pH 7.0 with initial concentrations (C(0)) of Hg(II) at 50, 100, 120, 150 and 180 microg L(-1), respectively, the light-induced reduction of Hg(II) followed the apparent pseudo first-order kinetics. The initial photoreduction rate could be expressed by the equation: r(A)=0.0871+0.00129 C(0), with a correlation coefficient R=0.9994. The overall mercury mass balance study on the photo-reductive process revealed that more than 39.86% of Hg(II) from the algal suspension was reduced to volatile metallic mercury. 相似文献
25.
26.
Wanfei Li Shuang Cheng Jian Wang Yongcai Qiu Zhaozhao Zheng Hongzhen Lin Sanjay Nanda Qian Ma Yan Xu Fangmin Ye Meinan Liu Lisha Zhou Yuegang Zhang 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2016,128(22):6516-6520
Most simple magnesium salts tend to passivate the Mg metal surface too quickly to function as electrolytes for Mg batteries. In the present work, an electroactive salt [Mg(THF)6][AlCl4]2 was synthesized and structurally characterized. The Mg electrolyte based on this simple mononuclear salt showed a high Mg cycling efficiency, good anodic stability (2.5 V vs. Mg), and high ionic conductivity (8.5 mS cm−1). Magnesium/sulfur cells employing the as‐prepared electrolyte exhibited good cycling performance over 20 cycles in the range of 0.3–2.6 V, thus indicating an electrochemically reversible conversion of S to MgS without severe passivation of the Mg metal electrode surface. 相似文献
27.
Surface plasmonic polariton(SPP) waves with complicated wavefronts have important implications in nanophotonic sciences and applications. The surface electromagnetic wave holography method is applied to designed grooves on a metal surface for coupling a plane wave in free space to complicated wavefront SPP waves.The grooves illuminated by the plane wave incident from free space serve as secondary SPP waves sources, that radiate cylindrical SPP waves. New controllable wavefronts originate from these secondary SPP waves interfering with each other, based on the Huygens–Fresnel principle. Several applications of the method are demonstrated, such as converting coupling waves in free space into focusing SPP waves on a metal surface. 相似文献
28.
29.
关于谢邦杰的一个定理的推广 总被引:2,自引:0,他引:2
本文采用[1]的术语.1978年,谢邦杰将著名的Hadamard不等式推广到四元数体上,即:设A=(a_ij)_n×n为四元数体上可中心化的非奇异矩阵,则等号成立当且仅当A的各行广义正交.本文给出关于四元数体上长方阵的不等式(2).当m=n,且A是可中心化的非奇异矩阵时,(2)式即为(1)式. 相似文献
30.
Uric acid is the end-product of purine metabolism and a major antioxidant in humans. The concentrations of uric acid in plasma and urine are associated with various diseases and routinely measured in clinical and biomedical laboratories using enzymatic conversion and colorimetric measurement. In this study a hydrophilic interaction chromatographic (HILIC) method was developed for simultaneous determination of uric acid and creatinine, a biomarker of urine dilution and renal function, in human urine. Urine samples were pretreated by dilution, protein precipitation, centrifugation and filtration. Uric acid and creatinine were separated from other components in urine samples and quantified using HILIC chromatography. A linear relationship between the ratio of the peak area of the standards to that of the internal standard and the concentration of the standards was obtained for both uric acid and creatinine with the square of correlation coefficients >0.999 for both analytes. The detection limits were 0.04 μg/mL for creatinine and 0.06 μg/mL for uric acid. The described HILIC method has proved to be simple, accurate, robust and reliable. 相似文献