首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   144801篇
  免费   10161篇
  国内免费   6978篇
化学   69475篇
晶体学   1408篇
力学   10996篇
综合类   517篇
数学   39617篇
物理学   39927篇
  2024年   228篇
  2023年   1400篇
  2022年   2280篇
  2021年   2469篇
  2020年   2522篇
  2019年   2423篇
  2018年   12056篇
  2017年   11671篇
  2016年   8701篇
  2015年   3868篇
  2014年   3925篇
  2013年   5133篇
  2012年   9492篇
  2011年   16063篇
  2010年   9446篇
  2009年   9759篇
  2008年   10506篇
  2007年   12240篇
  2006年   3757篇
  2005年   4339篇
  2004年   3943篇
  2003年   3793篇
  2002年   2657篇
  2001年   1752篇
  2000年   1699篇
  1999年   1709篇
  1998年   1519篇
  1997年   1309篇
  1996年   1418篇
  1995年   1184篇
  1994年   1081篇
  1993年   957篇
  1992年   821篇
  1991年   726篇
  1990年   604篇
  1989年   538篇
  1988年   424篇
  1987年   406篇
  1986年   356篇
  1985年   346篇
  1984年   244篇
  1983年   212篇
  1982年   186篇
  1981年   151篇
  1980年   128篇
  1979年   93篇
  1978年   90篇
  1977年   70篇
  1975年   73篇
  1973年   82篇
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
101.
The binding of lomefloxacin to bovine lactoferrin (BLf) in a dilute aqueous solution was studied using fluorescence spectra. The binding constant (K) and the number of binding sites (n) were obtained by a fluorescence quenching method. The binding distance (r) and energy-transfer efficiency (E) between lomefloxacin and bovine lactoferrin were also obtained according to the mechanism of Fo?rster-type dipole-dipole nonradiative energy-transfer. The effect of lomefloxacin on the conformation of bovine lactoferrin was also analyzed by synchronous fluorescence spectroscopy. The interaction between lomefloxacin and bovine lactoferrin is strong. Lomefloxacin can affect the conformation of bovine lactoferrin to some degree.  相似文献   
102.
In this note, we examine the algorithm of Drezner and Wesolowsky for locating a facility with maximin rectilinear distance to a given set of demand points. The concept of the closest-point constraint is introduced as a technique for increasing the efficiency of the algorithm. This potential increase in efficiency is demonstrated by an example.  相似文献   
103.
Molecular magnet {NBu4[Fe Cr(ox)3]}x (NBu4+=tetra(n-buty1) ammonium ion; ox2−=oxalate ion) was synthesized under an applied low magnetic field of 0.3 T in comparison to that synthesized without a field. Their crystallinities, morphologies and magnetic properties were characterized by using the X-ray diffractionmeter, the transmission electron microscope, and a superconducting quantum interference device. It is found that the average size of particles synthesized under the applied field appears larger than that synthesized without a field. Moreover, its crystallinity, morphology and magnetic susceptibility have also been improved. However, its chemical structure and ferromagnetic phase transition temperature Tc do not change. Possible reasons to explain this effect are also discussed.  相似文献   
104.
105.
The complete convergence theorem implies that starting from any initial distribution the one dimensional contact process converges to a limit ast. In this paper we give a necessary and sufficient condition on the initial distribution for the convergence to occur with exponential rapidity.This work was discussed while the authors were visiting the Nankai Mathematics Institute in Tianjin.Partially supported by the National Science Foundation, the Army Research Office through the Mathematical Sciences Institute at Cornell University, and a Guggenheim fellowship.Research supported by the National Science Foundation of China.  相似文献   
106.
We have measured the resistivity of the YBa2Cu3O7–Ag composite system with Ag volume fraction,p Ag ranging from 0–100%. The percolation behavior and the normal-state resistivity are studied. We find a three-dimensional threshold for the Ag matrix occurring atp Ag 20% and a threshold for the superconducting matrix occurring at 1–p Ag30%. The electrical resistivity is interpreted in terms of a resistivity model for granular YBa2Cu3O7 proposed by Halbritter et al. [Z. Phys. B —Condensed Matter71, 411 (1988)]. Based on this model, we show that the resistivities between the YBa2Cu3O7 grains and flaws in the grains are greatly diminished in the samples, indicating significantly improved grain growth behavior of the YBa2Cu3O7 phase resulting from the addition of Ag. With the diminishing of the grain boundary resistivities, an intrinsic value for the temperature coefficient of resistivity, (1/gr)(d/dT), can be inferred, which is 3.3×10–3/K at 300 K. This value is very close to that observed in the Cu–O2 planes in single crystals and epitaxial films of YBa2Cu3O7.  相似文献   
107.
If we fit a-vector stationary time series using observationsx(1), ...,x(T) with AR models , then the spectral densityf() of {x(t)} can be estimated byf k (T) ()=(2) A k (T) (e )–1 k (T) A k (T) (e i), where are estimates of the variance matrix of(t), the residuals of the best linear prediction. By extending some results for the scalar case, this paper treats the asymptotic properties of the estimates in the multichannel case.  相似文献   
108.
Molecular dynamics simulations on surfactant octadecylammonium chloride at the air/liquid interface were performed. It was found that the alkyl chains of octadecylammonium would change to order with increasing the concentration of octadecylammonium at the air/liquid interface. Some functions, such as the concentration distributions, the radial distribution function and the mean squared displacement (MSD) were evaluated to investigate the structural properties of interface. We found that the salts can affect octadecylammonium aggregate at the interface: (1) univalent ions, such as chloride and sodium ions, affect slightly the structure of monolayer and (2) bivalent ions, such as sulfate or calcium ions, affect greatly, especially for the bivalent negative ions.  相似文献   
109.
The neutron irradiated potassium hexacyanoferrate(III) solutions were analyzed for Fe(CN)64?, Fe(CN)63?, and Prussian blue. The retention values (1.1%) were constant throughout the pH and concentration ranges studied, and did not change with the length of irradiation. The complex behavior of the radiochemical yield of the Fe(CN)64? and Prussian blue was attributed to the competition of the various reactions involved in the irradiation.  相似文献   
110.
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号