Synthesis and study of N,N-disubstituted 4-aminophenylazobenzaldehydes

A series of ^N , ^N -disubstituted 4-aminophenylazobenzaldehydes (azo dyes) were synthesized by the reaction of phenylpiperazine derivatives with 4-formylbenzenediazonium tetrafluoroborate. The salt was easily prepared by reacting poly(aminobenzaldehyde) with sodium nitrite in the presence of tetrafluoroboric acid. A representative sample was studied by crystallography, and the charge distribution of the molecule was calculated with the aim of understanding the form of molecular stacking on the basis of crystal data. The mesogenic behaviour of the azo dyes was also studied.     

Synthesis of phytosphingosine using olefin cross-metathesis: a convenient access to chain-modified phytosphingosines from d-lyxose

This work establishes a general protocol for synthesizing phytosphingosines with various lengths of lipid chains. The synthetic strategy included the Wittig reaction and olefin cross-metathesis as key steps. Combining these two C-C bond formation methods provide rapid access to adequately protected phytosphingosine backbones.     

Optimal actuator locations and precision micro-control actions on free paraboloidal membrane shells

Flexible paraboloidal shells, as key components, are increasingly utilized in antennas, reflectors, optical systems, aerospace structures, etc. To explore precise shape and vibration control of the paraboloidal membrane shells, this study focuses on analysis of microscopic control actions of segmented actuator patches laminated on the surface of a free paraboloidal membrane shell. Governing equations of the membrane shell system and modal control forces of distributed actuator patches are presented first, and followed by the analysis of dominating micro-control actions based on various natural modes, actuator locations and geometrical parameters. Finally, according to the parametric analysis, simulation data reveal main factors significantly influencing active control behavior on smart free-floating paraboloidal membrane shell systems, thus providing design guidelines to achieve optimal control of paraboloidal shell systems.     

Synthesis and characterization of nanostructured Ba<Subscript>5</Subscript>Ta<Subscript>4</Subscript>O<Subscript>15</Subscript> by sol–gel process

Hexagonal Ba₅Ta₄O₁₅ were synthesized by a sol–gel process at temperatures of 700–900 °C. The microstructure properties and morphology are studied by X-ray diffraction and scanning electron microscope. Traces of the Ba₅Ta₄O₁₅ component were detected by energy dispersive X-ray analysis. A higher temperature enhanced higher atom mobility and caused the growth direction to change and created hexagonal square makes obvious good quality of samples. The visible light absorption edges of the Ba₅Ta₄O₁₅ nanorods and were corresponded to band-gap energies of 4.0 eV.     

Synthesis and study of N,N-disubstituted 4-aminophenylazobenzaldehydes

A series of ^N,^N-disubstituted 4-aminophenylazobenzaldehydes (azo dyes) were synthesized by the reaction of phenylpiperazine derivatives with 4-formylbenzenediazonium tetrafluoroborate. The salt was easily prepared by reacting poly(aminobenzaldehyde) with sodium nitrite in the presence of tetrafluoroboric acid. A representative sample was studied by crystallography, and the charge distribution of the molecule was calculated with the aim of understanding the form of molecular stacking on the basis of crystal data. The mesogenic behaviour of the azo dyes was also studied.     

质点的相对论式的汉密尔敦运动式与相对论式的哈生堡方程式

在本文中,作者推得一组相对论式的汉密尔敦运动式;并根据此运动式,详细地讨论了一质点之运动;由此还可以很自然地看出,在量子力学中,狄拉克电子方程式似乎是一个必然的波动方程式。在狄拉克理论中的取平方根步骤在这里找到它在古典物理学中的对照。同时根据了上面的理论,作者还推得到一个相对论式的哈生堡方程式,最后则讨论了此方程式在狄拉克电子理论中的一些应用;同时并指出,在相对论的观点上,此方程式可以引导出一些比较对称的及有比较普遍形式的物理的量。     

Structure-property study of polyimides derived from PMDA and BPDA dianhydrides with structurally different diamines

A series of aromatic diamines were polymerized with two aromatic dianhydrides, pyromellitic dianhydride and 3,3^′,4,4^′-biphenyltetracarboxylic dianhydride, and the resulting poly(amic acid)s were thermally cyclodehydrated to aromatic polyimides. The polyimides were characterized by determining the glass transition temperatures (T_g), thermal stability, coefficients of thermal expansion, and wide-angle X-ray diffraction. Structure-property relationships are elucidated and discussed in terms of the structural fragments in the polymer chain. The PMDA-based polyimides generally revealed a higher T_g than the corresponding BPDA-based analogues. Generally, the dilution of the imide content by the insertion of oxyphenylene segments into the diamines significantly reduced the T_g. The introduction of m- or o-phenylene units into the polymer backbone usually resulted in a decrease in T_g. The attachment of pendant groups on the backbone may lead to decreased or increased T_gs, depending on the structure of pendant groups. As evidenced by X-ray diffraction, the polyimides derived from rigid, rod-like diamines or the diamines having two or three p-oxyphenylene showed a higher crystalline tendency. The presence of aliphatic pendant groups slightly reduced the thermal stability of the polyimides. The other structural changes did not show a dramatic influence on the thermal stability. Some polyimides obtained from p- or m-phenylenediamine had low thermal expansion coefficients below 2×10−5°C⁻¹.     

Multiple injection techniques for microfluidic sample handling

This paper presents an experimental and numerical investigation into electrokinetic focusing flow injection for bioanalytical applications on 1 x N (i.e., 1 sample inlet port and N outlet ports) and M x N (i.e., M sample inlet ports and N outlet ports) microfluidic chips. A novel device is presented which integrates two important microfluidic phenomena, namely electrokinetic focusing and valveless flow switching within multiported microchannels. The study proposes a voltage control model which achieves electrokinetic focusing in a prefocusing sample injection system and which allows the volume of the sample to be controlled. Using the developed methods, the study shows how the sample may be prefocused electrokinetically into a narrow stream prior to being injected continuously into specified outlet ports. The microfluidic chips presented within this paper possess an exciting potential for use in a variety of techniques, including high-throughput chemical analysis, cell fusion, fraction collection, fast sample mixing, and many other applications within the micrototalanalysis systems field.     

Glucose orientation and dynamics in alpha-, beta-, and gamma-cyclodextrins

We investigate, using molecular dynamics (MD) computer simulations, the conformational behavior of alpha-, beta-, and gamma-cyclodextrins (CDs). Our analysis of a 30 ns trajectory of CD solution dynamics reveals the underlying conformational behaviours of the CDs that explain their relative flexibility. The distributions of the torsion angles related to the glycosidic linkages, P(phi,psi) were calculated for the three CDs. Most noticeable is the limited range in phi torsion rotations compared with psi rotations for all the CDs. This difference between the three CDs is amplified in the motion and dynamics of their glucose monomers when we monitor their orientational and librational positions relative to the macrocyclic mean plane. The relaxation times of the monomers to their equilibrium orientations follow the pattern gamma-CD > alpha-CD > beta-CD. The root-mean-square deviations of the motion of the monomer centers of mass from the mean macrocyclic planes exhibit the same trend.     

A 13C solid-state NMR analysis of steroid compounds

(13)C CP/MAS solid-state NMR spectroscopy has been utilized to analyze six steroid compounds, namely testosterone (Tes), hydrocortisone (Cor), trans-dehydroandrosterone (Adr), prednisolone (Prd), prednisone (Pre) and estradiol (Est). Among them, Tes displays a doublet pattern for all residues, whereas Prd, Pre and Est, exhibit exclusively singlets. For Cor and Adr, the (13)C spectra contain both doublet and singlet patterns. The (13)C doublet signal, with splittings of 0.2-1.5 ppm, are ascribed to local differences in the ring conformations associated with polymorphism. We have assigned all of the (13)C resonances to the different residues in these steroid compounds on the basis of solution NMR data. The C-7, C-8, C-10, C-15 and C-16 residues of Tes, Cor and Adr consistently give rise to singlets or doublets with splittings of less than 0.5 ppm, indicating similar local conformations. Accompanying hydration and dehydration processes, a reversible phase transformation between delta- and alpha-crystal forms has been observed in Tes, corresponding to singlet and doublet (13)C patterns, respectively. To further characterize the ring conformations in the alpha-form, we have successfully extracted chemical shift tensor elements for the (13)C doublets. It is demonstrated that (13)C solid-state NMR spectroscopy provides a reliable and sensitive means of characterizing polymorphism in steroids.