全文获取类型
收费全文 | 796篇 |
免费 | 18篇 |
国内免费 | 1篇 |
专业分类
化学 | 654篇 |
晶体学 | 9篇 |
力学 | 10篇 |
数学 | 43篇 |
物理学 | 99篇 |
出版年
2021年 | 6篇 |
2020年 | 17篇 |
2019年 | 5篇 |
2018年 | 12篇 |
2017年 | 8篇 |
2016年 | 10篇 |
2015年 | 17篇 |
2014年 | 7篇 |
2013年 | 43篇 |
2012年 | 46篇 |
2011年 | 43篇 |
2010年 | 13篇 |
2009年 | 30篇 |
2008年 | 45篇 |
2007年 | 53篇 |
2006年 | 39篇 |
2005年 | 30篇 |
2004年 | 34篇 |
2003年 | 34篇 |
2002年 | 37篇 |
2001年 | 16篇 |
2000年 | 17篇 |
1999年 | 9篇 |
1998年 | 11篇 |
1997年 | 10篇 |
1996年 | 11篇 |
1995年 | 7篇 |
1994年 | 6篇 |
1993年 | 8篇 |
1992年 | 14篇 |
1991年 | 13篇 |
1990年 | 7篇 |
1989年 | 10篇 |
1988年 | 8篇 |
1987年 | 10篇 |
1986年 | 5篇 |
1985年 | 19篇 |
1984年 | 22篇 |
1983年 | 3篇 |
1982年 | 14篇 |
1981年 | 11篇 |
1980年 | 10篇 |
1979年 | 10篇 |
1978年 | 8篇 |
1977年 | 5篇 |
1976年 | 2篇 |
1975年 | 6篇 |
1974年 | 7篇 |
1973年 | 3篇 |
1968年 | 2篇 |
排序方式: 共有815条查询结果,搜索用时 15 毫秒
71.
72.
The adsorption of ten gases on the flexible metal organic framework material [Cu(dhbc)(2)(4,4'-bpy)]·H(2)O (Cu(db)) has been measured over a wide range of temperatures and pressures. The gate opening condition and driving force behind gate adsorption for Cu(db) were discussed by examining the adsorption isotherms. The adsorption isotherms for each adsorbate can be generalized to a characteristic curve using the adsorption potential energy (ε) and the adsorption volume. The adsorption potential (ε(gate)) at gate opening is almost constant over a wide range of temperatures; thus, the gate pressure at a desired temperature can be deduced using the ε(gate) evaluated from one adsorption isotherm. The gate opening capacity of the gases was arranged in the order: CO(2)≒N(2)O>C(2)H(4)≒Xe>CH(4)>CO>O(2)>Ar≒N(2)>H(2), which is governed by the interaction energy between the outer surface of Cu(db) and the adsorbate. It is suggested that the gate effect is brought about when the integral interaction energy of adsorbates with the Cu(db) surface exceeds a defined limit correlating with the π-π stacking energy of Cu(db) layers. 相似文献
73.
Enantioselective total synthesis of the biologically important indole alkaloids (+)-lysergol, (+)-isolysergol, and (+)-lysergic acid is described. Key features of these total synthesis include (1) a facile synthesis of a chiral 1,3-amino alcohol via the Pd(0)- and In(I)-mediated reductive coupling reaction between L-serine-derived 2-ethynylaziridine and formaldehyde; (2) the Cr(II)/Ni(0)-mediated Nozaki-Hiyama-Kishi (NHK) reaction of an indole-3-acetaldehyde with iodoalkyne; and (3) Pd(0)-catalyzed domino cyclization of an allene bearing amino and bromoindolyl groups. This domino cyclization enabled direct construction of the C/D ring system of the ergot alkaloids skeleton, as well as the creation of the C5 stereogenic center with transfer of the allenic axial chirality to the central chirality. 相似文献
74.
Yamamoto Y Yamashita K Nishiyama H 《Chemical communications (Cambridge, England)》2011,47(5):1556-1558
A ruthenium cyclic biscarbene complex reacted with a H(2)O molecule under mild conditions to produce η(5)-oxapentadienyl complex, that proved to be the intermediate in the catalytic hydrative cyclization of a diyne. 相似文献
75.
76.
A. Sagisaka A.S. Pirozhkov H. Daido A. Fukumi Z. Li K. Ogura A. Yogo Y. Oishi T. Nayuki T. Fujii K. Nemoto S. Orimo M. Nishiuchi Y. Hayashi M. Mori M. Kado S. Nakamura A. Noda I.W. Choi J.H. Sung D.-K. Ko J. Lee 《Applied physics. B, Lasers and optics》2006,84(3):415-419
A two-color interferometer for preformed plasma characterization is developed. We observe the electron density distribution of preformed plasmas on a 5 μm-thick copper target irradiated with a high-intensity Ti:sapphire laser. The two-color interferometer extended the observable electron density region using a fundamental (800 nm) probe beam to cover the lower density region and a second harmonic (400 nm) probe beam to cover the higher density region, simultaneously. This characterization of the electron density distribution of preformed plasmas with femtosecond time resolution significantly contributes to the understanding of high-intensity laser–thin-foil interactions during high-energy electron, ion, and X-ray generation. PACS 52.38.-r; 52.50.Jm; 52.70.-m 相似文献
77.
78.
79.
80.
Yoshihiko Ito Hiroshi Imai Takaharu Matsuura Takeo Saegusa 《Tetrahedron letters》1984,25(29):3091-3094
This paper describes the finding that BF3 etherate effectuates the conjugate additions of copper(I) aldimines, generated in situ from lithium aldimines and Cu(I) halide, to α,β-unsaturated carbonyl compounds to produce 4-(N-alkylimino)-ketones, which give on acid hydrolysis 1,4-diketone derivatives. 相似文献