Zn掺杂的LaCoO3钙钛矿用于乙醇水蒸气重整制氢反应

利用一步柠檬酸络合法合成了钙钛矿LaCo1-xZnxO3(x=0,0.05,0.1,0.2,0.3,0.5),并将其用于乙醇水蒸气重整反应.利用X射线衍射、程序升温还原和X射线光电子能谱对催化剂进行了表征.结果表明,Zn的加入不利于形成LaCo1-xZnxO3钙钛矿结构,当x≥0.1时产生了一些分离相.新鲜LaCo0....     

综合管廊早龄期混凝土温度应力仿真模拟

以汉中市综合管廊为工程背景,通过有限元软件,首先模拟分析综合管廊早龄期温度场,随后将温度场结果附加到管廊结构中求解温度应力,从而分析综合管廊早龄期混凝土温度应力与浇筑长度的关系。模拟分析发现:综合管廊在混凝土浇筑早期,温度场沿长度方向变化不显著,且随着浇筑长度的增加,温度场不变;在墙体温度上升阶段,墙体内部沿长度方向的应力主要为压应力,当墙体混凝土内部温度达到最高,混凝土开始降温,结构内变形由膨胀逐渐变为收缩,内力由压应力逐渐变为拉应力,随着时间的变化,墙体内外温差趋于稳定,墙体温度应力也逐渐平稳,此时温度应力主要受外界环境变化影响;当综合管廊浇筑长度在60m范围内,浇筑长度越大,温度应力越大,但当浇筑长度超过60m,温度应力不再增加。     

中国自然灾害时空变化及其社会经济效应

自然灾害的频繁发生对实现全球可持续发展目标构成了严重威胁。中国自然灾害时空演化规律及其社会经济效应研究,对落实国家防灾减灾救灾政策、实现社会经济更高质量发展具有重要的理论和现实意义。通过构建灾情指数模型评估了2000—2018年中国31个省级行政单元的自然灾害受灾程度,采用空间计量模型和地理加权回归（GWR）模型揭示了自然灾害时空格局演变的社会经济效应。结果表明：（1）2000—2018年中国自然灾害受灾程度总体有所下降,空间上呈南高北低的格局,高受灾中心集中在西南、东南地区;（2）受灾面积对经济发展、人口增长、农业生产有明显抑制作用且空间溢出效应显著,而倒塌房屋数量对本地区及邻近省域经济发展有正向促进作用;（3）自然灾害对经济发展、人口增长的负效应自东向西逐渐增加;农业生产效应呈西正东负的格局,这与省域受灾程度、灾害种类及防灾减灾能力密切相关。     

含万向铰偏斜旋转轴的组合共振及其稳定性分析

基于欧拉方程推导出了含万向铰偏斜旋转轴的横向振动模型,利用多尺度方法对该模型进行求解,得出了该偏斜系统可能出现的多种共振模式,进而对含万向铰偏斜轴系横向振动和型组合共振、差型组合共振进行稳定性分析,并对该类偏斜系统横向振动和型组合共振响应进行数值计算与仿真,检验所得稳定性理论分析结果。研究表明:对于和型组合共振而言,其稳定性边界与输入扭矩T0、支撑轴承安装位置l、轴承刚度Kx2和Ky2等因素有关;当轴承安装位置距万向铰中心较近或者轴承弹簧刚度系数较小时,系统在频率(ω10+ω20)/2附近产生和型组合共振的区域减小,即能够抑制系统和型组合共振的产生。该研究可为偏斜轴系振动与噪声抑制提供理论支持。     

板片空间结构初始缺陷的动力稳定性影响分析

对板片空间结构体系的研究大都局限于静力载荷工况,结构在动力载荷作用下的稳定性及失效特征研究仍相对缺乏．板片空间钢结构先天存在各样缺陷,而缺陷对结构稳定性的影响不可忽略．本文引入拉丁超立方法,结合Budiansky-Roth 准则,提出适用于求解含初始缺陷结构动力临界荷载的方法,对板片空间结构初始缺陷的动力稳定性开展研究．研究表明,相比于其它抽样方法,拉丁超立方法能显著减少样本数,有效提高计算效率．针对典型的板片空间结构,施加不同方向的阶跃荷载,分析了节点位置偏差缺陷、杆件截面尺寸缺陷以及板片厚度缺陷对板片空间结构临界承载力的影响．结果显示,节点位置偏差缺陷对该结构临界承载力影响最为显著,其它两类缺陷影响甚微．     

Hydrogen bond activated glycosylation under mild conditions

Herein, we report a new glycosylation system for the highly efficient and stereoselective formation of glycosidic bonds using glycosyl N-phenyl trifluoroacetimidate (PTFAI) donors and a charged thiourea hydrogen-bond-donor catalyst. The glycosylation protocol features broad substrate scope, controllable stereoselectivity, good to excellent yields and exceptionally mild catalysis conditions. Benefitting from the mild reaction conditions, this new hydrogen bond-mediated glycosylation system in combination with a hydrogen bond-mediated aglycon delivery system provides a reliable method for the synthesis of challenging phenolic glycosides. In addition, a chemoselective glycosylation procedure was developed using different imidate donors (trichloroacetimidates, N-phenyl trifluoroacetimidates, N-4-nitrophenyl trifluoroacetimidates, benzoxazolyl imidates and 6-nitro-benzothiazolyl imidates) and it was applied for a trisaccharide synthesis through a novel one-pot single catalyst strategy.

A mild glycosylation system was developed using glycosyl imidate donors and a charge-enhanced thiourea H-bond donor catalyst. The method can be used for the effective synthesis of O-, C-, S- and N-glycosides and chemoselective one-pot glycosylation.     

正交异性材料平面裂纹尖端应力场

根据正交各向异性材料力学性能确定出了用应力函数表示的弹性力学基本方程,利用坐标变换和复变函数方法求解了正交异性材料平面裂纹体的应力边值问题。借鉴一般断裂力学解法构造了I型和II型裂纹问题的应力函数,推导出了正交各向异性板裂纹尖端区的奇异应力场。通过数值计算说明了裂纹尖端应力表达式的正确性,验证了裂尖前沿应力变化规律,即σx与材料特征参数h2成正比,而σy和τxy不随材料特性变化。     

Design and application of an S-box using complete Latin square

Since a substitution box (S-box) is the nonlinearity part of a symmetric key encryption scheme, it directly determines the performance and security level of the encryption scheme. Thus, generating S-box with high performance and efficiency is attracting. This paper proposes a novel method to construct S-box using the complete Latin square and chaotic system. First, a complete Latin square is generated using the chaotic sequences produced by a chaotic system. Then an S-box is constructed using the complete Latin square. Performance analyses show that the S-box generated by our proposed method has a high performance and can achieve strong ability to resist many security attacks such as the linear attack, differential attack and so on. To show the efficiency of the constructed S-box, this paper further applies the S-box to image encryption application. Security analyses show that the developed image encryption algorithm is able to encrypt different kinds of images into cipher images with uniformly distributed histograms. Performance evaluations demonstrate that it has a high security level and can outperform several state-of-the-art encryption algorithms.

     

Highly efficient and reusable dendritic catalysts derived from N-prolylsulfonamide for the asymmetric direct aldol reaction in water

The direct aldol reactions catalyzed by chiral dendritic catalysts derived from N-prolylsulfonamide gave the corresponding products in high isolated yields (up to 99%) with excellent anti diastereoselectivities (up to >99:1) and enantioselectivities (up to >99% ee) in water. In addition, catalyst 1e may be recovered by precipitation and filtration and reused for at least five times without loss of catalytic activity.     

Zero extension for Poisson’s equation

In this paper, we present a necessary and sufficient condition to guarantee that the extended function of the solution for Poisson's equation in a smaller domain by zero extension is still the solution of the corresponding extension problem in a larger domain. We prove the results under the frameworks of classical solutions, strong solutions and weak solutions. Furthermore, we give some observations for the nonlinear pLaplace equation.