纳米粒子稳定乳液及其在纳米结构合成中的应用*

本文在介绍常规乳状液、微乳液和固体稳定乳液的基础上,着重综述了纳米粒子稳定乳液的特点及其在纳米结构合成中的应用进展,并对目前该研究领域亟待解决的问题进行了分析。纳米粒子稳定乳液具有独特的油、水、固三相环境和水油、水固、油固三个相界面,分散相液滴尺寸可以在微米、亚微米乃至纳米尺度调节,因而可以作为合成组成、结构和性能极为丰富多样的纳米结构的介质。纳米粒子对乳液稳定作用的机理,以及纳米粒子稳定乳液中化学反应的特殊规律还有待深入研究。本文在介绍固体稳定乳液的基础上,着重综述了纳米粒子稳定乳液的特点及其在纳米结构合成中的应用进展,并对目前该研究领域亟待解决的问题进行了分析。纳米粒子稳定乳液具有独特的油、水、固三相环境和水油、水固、油固三个相界面,分散相液滴尺寸可以在微米、亚微米乃至纳米尺度调节,因而可以作为合成组成、结构和性能极为丰富多样的纳米结构的介质。纳米粒子对乳液稳定作用的机理,以及纳米粒子稳定乳液中化学反应的特殊规律还有待深入研究。     

On-line Time Differential Perturbed Angular Correlation with Light Probe Nucleus 19F

An on-line time differential perturbed angular correlation technique has been developed with the light probe nucleus ¹⁹F. The first on-line TDPAC measurement was carried out to determine the field gradient in Cd and quadrupole moment of ¹⁹F (0.197 MeV: I ^π = 5/2⁺, T_1/2 = 89 ns). This revised version was published online in September 2006 with corrections to the Cover Date.     

相干光脉冲位置调制信道容量及传信率最大化研究

分析了相干光脉冲位置调制的信道容量及传信率最大化条件.通过分析光外差接收的脉冲位置调制信号具有的概率分布特性,推导出采用最大似然检测的相干脉冲位置调制信道具有的转移概率矩阵和信道容量,证明在检测器散粒噪声极限假设下,信道容量只取决于接收脉冲能量和脉冲位置调制阶数.利用Jensen不等式化简信道容量得到其下限,该下限能够近似实际通信链路的信道容量.基于此估计出达到最高传信率时的脉冲位置调制阶数同粒子数反转的重建时间之间的关系,给出了二者在一定范围内的一般映射.数值仿真表明,在接收能量使信道误码率优于10-2时,估箅出的脉冲位置调制阶数能够使传信率接近最大值.     

约束层阻尼板动力学问题的半解析解

利用条形传递函数方法(SDTFM)得到了约束层阻尼(CLD)板动力学问题的半解析解.首先对CLD板沿纵向离散成多个条形单元,基于Hamilton原理推导出条形单元的刚度矩阵和质量矩阵,仿照有限元法组集得到系统的总刚度矩阵和总质量矩阵.经Laplace变换后引入状态向量,采用分布参数传递函数方法在状态空间内建立CLD板的控制方程并进行求解.最后以对边固支和悬臂CLD板为例,得到了板的动力学特性和频响曲线,并与NASTRAN或相关文献结果进行了比较,吻合良好,验证了该方法的有效性.从推导过程和算例可以看出,该方法所需的单元数目少,获得的是半解析解,计算效率高且准确可靠.     

Organocatalytic Asymmetric C(sp2)−H Allylic Alkylation: Enantioselective Synthesis of Tetrasubstituted Allenoates

Herein we describe the first organocatalytic asymmetric C(sp²)−H allylation of racemic trisubstituted allenoates with Morita–Baylis–Hillman (MBH) carbonates to access axially chiral tetrasubstituted allenoates. Various trisubstituted allenoates and MBH carbonates were well tolerated under mild reaction conditions, providing novel chiral tetrasubstituted allenoates with adjacent axial chirality and tertiary carbon stereocenters in high yields with good to excellent diastereoselectivities and enantioselectivities.     

“汇编语言程序设计”CAI课件的设计与实现

本文叙述了“８０８６汇程序设计”ＣＡＩ课件的设计思想及特点，对其模拟解释器，可视化接口，语言语义及语用的在线解释及帮助，智能出错处理的实现分别作了介绍。通过本课件的实现，Ｖｉｓｕａｌ Ｂａｓｉｃ是课件很好的实现工具及实现框架。     

超高偏振模色散光纤中光脉冲传输行为的研究

利用耦合非线性薛定谔方程分析了光脉冲在超高偏振模色散光纤中传输时，偏振模色散引起脉冲分裂。并用基模的两正交偏振分量耦合走离解释了脉冲分裂的成因。利用偏振模色散为237．95ps／km^1/2的光纤进行了实验验证。     

Determination of power-time curves of bacterial growth

Bacterial growth power-time curves were determined with a 2277 Thermal Activity Monitor. Bacterial multiplication curves were measured at different temperatures and an experimental model was established. Both growth rate constants and lowest growth temperatures were calculated.Supported by the Natural Science Foundation of Shandong Province.     

One-dimensional polyaniline nanostructures synthesized by interfacial polymerization in a solids-stabilized emulsion

One-dimensional polyaniline nanostructures were synthesized by interfacial polymerization in a solids-stabilized oil/water emulsion for the first time. The products were characterized with TEM, FTIR and UV-vis. FTIR analyses proved the polyaniline synthesized were of emeraldine salt form; the results of TEM showed that when MgCO₃ and CaCO₃ particles were used as emulsifiers, polyaniline nanofibers with an average diameter of 33 nm and nanotubes with an average outer diameter of 28 nm were obtained, respectively. Comparing to ordinary interfacial polymerization approach, our new route needed much less amount of oil phase and shorter polymerization time. A possible mechanism for the formation of one-dimensional polyaniline nanostructures was suggested.     

贝叶斯对数线性估计

用Logits变换方法来讨论列联表的贝叶期估计，这时的估计称为贝叶斯对数线性估计，最早是由Lconard（1973，1975）提出的．Leonard讨论了二维表的对数线性贝叶斯估计；其后，Nazerat（1987）给出了三维表的贝叶斯对数线性估计．该文采用矩阵求微商方法，立足于高维表贝叶斯线性估计的较一般的表达形式；具体对四维表讨论员叶斯对数线性估计的表达和计算．