阵列碳纳米管的石墨化程度

采用化学气相沉积法制备了阵列碳纳米管薄膜,对阵列碳纳米管的石墨化程度进行了系统研究。利用扫描电子显微镜(SEM)、拉曼光谱(Raman)对样品形貌以及结构进行了表征。探讨了不同实验参数对阵列碳纳米管石墨化程度影响的机理。结果发现,在一定催化剂浓度范围内,催化剂浓度过低时,阵列碳纳米管的石墨化程度较差,而随着催化剂浓度的增加,阵列碳纳米管的石墨化程度逐渐变好;生长石墨化程度较好的阵列碳纳米管需要合适的进液速度,进液速度过低或过高都会使得碳纳米管的石墨化程度变差;此外,生长石墨化程度较好的阵列碳纳米管也需要合适的生长温度,生长温度过低或过高都会使得碳纳米管的石墨化程度变差。     

MnO_2/石墨烯复合电极材料的制备与储能性能

以葡萄糖为还原剂,天然石墨片为原料,采用Hummer法制备了石墨烯粉末(Graphene);并以该产物、KMnO4和HCl为原料,采用水热法制备了MnO2/Graphene复合材料。用扫描电子显微镜和X射线衍射对所制备的复合材料进行了表征,结果表明,水热法制备的MnO2材料为纯的α-MnO2相,且石墨烯粉末的加入并没有影响MnO2的晶体结构。在1mol/L Na2SO4电解液中进行了循环伏安和计时电位扫描测试,电极材料电化学性能稳定,具有较好的可逆性,在1.27mA/cm2电流密度下进行充放电测试时,电极比电容为147.9F/g;再循环1000次后,电极仍能保持稳定的电容,是一种理想的电化学电极材料。     

Optimal acquisition and production policy in a hybrid manufacturing/remanufacturing system with core acquisition at different quality levels

We study the acquisition and production planning problem for a hybrid manufacturing/remanufacturing system with core acquisition at two (high and low) quality conditions. We model the problem as a stochastic dynamic programming, derive the optimal dynamic acquisition pricing and production policy, and analyze the influences of system parameters on the acquisition prices and production quantities. The production cost differences among remanufacturing high- and low-quality cores and manufacturing new products are found to be critical for the optimal production and acquisition pricing policy: the acquisition price of high-quality cores is increasing in manufacturing and remanufacturing cost differences, while the acquisition price of low-quality cores is decreasing in the remanufacturing cost difference between high- and low-quality cores and increasing in manufacturing and remanufacturing cost differences; the optimal remanufacturing/manufacturing policy follows a base-on-stock pattern, which is characterized by some crucial parameters dependent on these cost differences.     

Weak Commutative Pseudoeffect Algebras

As noncommutative generalizations of effect algebras, we introduce weak commutative pseudoeffect algebras. In this paper, we prove that the generalized pseudoeffect algebras can be unitized if and only if they are weak commutative. Then we discuss the relationships between weak commutative pseudoeffect algebras and weak commutative generalized pseudoeffect algebras. We prove that the category of weak commutative pseudoeffect algebras is a reflective subcategory of weak commutative generalized pseudoeffect algebras. Similarly, we introduce weak commutative pseudodifference posets and show the relationships between weak commutative pseudoeffect algebras and weak commutative pseudodifference posets.     

运动轨迹对抛光误差的影响分析和轨迹优化研究

针对现有光学加工抛光头运动方式由于光栅形或螺旋形等对称扫描方式带来的运动轨迹间的迭代误差,提出随机轨迹抛光运动方式.随机轨迹方法通过随机轨迹算法随机生成镜面离散点的抛光顺序和抛光轨迹,采用随机轨迹驻留时间补偿方法控制镜面离散点的驻留时间,对各个点进行相应大小的材料去除.实验结果显示,随机轨迹方法产生的抛光运动轨迹表现为...     

LiNbO3波导中切伦科夫辐射型的倍频

对条波导中切伦科夫辐射型的倍频作了简要分析，着重分析了产生切伦科夫辐射倍频的，工从实验上实现了条波导中１．０６μｍ红外光到０．５３１ｍ绿光的倍频辐射，转换效率为的０．９％，对应的输入光功率为１０ｍＷ。     

Natural negation of interval-valued <Emphasis Type="Italic">t</Emphasis>-(co) norms and implications

In this paper, we investigate interval-valued fuzzy negations induced by interval-valued \(t\)-norms, \(t\)-conorms or implications. Some properties of interval-valued fuzzy negations induced by interval-valued sup-morphism \(t\)-norms, inf-morphism \(t\)-conorms or \(R\)-implications are firstly obtained. We also show interval-valued automorphisms acting on the interval-valued fuzzy negations induced by interval-valued \(t\)-norms, \(t\)-conorms or implications. Finally, the relations among the interval-valued fuzzy negations induced by interval-valued \(t\)-norms, \(t\)-conorms or implications are explored.     

溶液相有机化合物pKa的量子化学计算

寻找一种理论计算方法来验证和补充实验数据,得到较为精确的溶剂化自由能和pK_a值,是众多理论化学家长期以来研究的重要方向。本综述较为详细地总结了近年发展起来的PCM理论模型在溶液相化合物溶剂化自由能、特别是近十年来有机化合物pK_a值的量子化学计算中的最新成果,比较了各种不同计算方法的精确性和各自特点。     

含参数泛函微分方程概周期正解的存在性

研究了一类含参数泛函微分方程概周期正解的存在性问题.结合有界性及渐近概周期性获得了系统存在概周期正解的几组充分条件,并将结果应用于几类种群动力学模型,分别获得了系统在概周期环境下存在概周期解的一组充分条件.     

液态低沸点气体的表面张力

利用双毛细管法测定了液氮沸点温度下液氮的表面张力。用非线性方程γ＝γ&#176;（１－Ｔ／Ｔｃ）＾ｎ描述了液态Ｎ２、Ｏ２、ＡｒＸｅ、Ｈ２、Ｎｅ、Ｈｅ、Ｆｅ和Ｋｒ的表面张力与温度的关系，并采用一元性回归的方法拟合了上述各流体的参数γ&#176;和ｎ，准确度高于文献值，说明方程能正确表达表面张力与温度的关系。这些数据有利于对上述低沸点气体进行准确的热力学计算。