Copper-catalyzed annulation of 2-bromobenzoic esters with terminal alkynes towards 3-substituted isocoumarins

An efficient method for the synthesis of 3-substituted isocoumarins that are an important class of biologically active scaffolds via annulation of 2-bromobenzoic esters with terminal alkynes by copper catalyzed is described. The advantages of this method include mild reaction conditions, high yield and regioselectivity, and wide tolerance toward functional groups.     

不同离子液体双水相萃取钯

为实现贵金属钯的绿色、高效萃取,本文使用有“绿色溶剂”之称的离子液体与磷酸钾形成的双水相体系,不加入其它萃取剂对钯(Ⅱ)进行萃取,并采用浊点法对所研究的6种咪唑类离子液体的双结线和系线进行测定。 结果表明,基于氯离子和溴离子的离子液体成相能力和萃取率无显著差异。 阳离子上支链的疏水性是影响咪唑类离子液体成相能力的关键因素之一。 与不含官能团的离子液体相比,支链上嵌入氨基和腈基的离子液体,成相能力较低,但萃取率分别提高了11.57%和34.26%。 当含腈基的离子液体浓度和磷酸钾浓度分别为5.00%和39.55%时,离子液体双水相体系对钯(Ⅱ)的萃取率可达到100%。 本文的研究成果为设计/选择可利用其双水相体系高效萃取钯(Ⅱ)的离子液体提供了理论基础和数据支持。     

Pesticide residue determination in vegetables from western China applying gas chromatography with mass spectrometry

In this study,an effort has been made to evaluate the pesticide residues in vegetables from western China. Fifty‐one pesticides, including organophosphorus, organochlorine, carbamate and pyrethroid, were detected in 369 commonly used vegetables by GC‐MS. Concentrations of organophosphorus pesticides were detected ranging from 0.0008 to 18.8200 mg/kg, among which organophosphorus pesticide concentrations exceeded their maximum residue levels (MRLs) in five samples. Carbamate and organochlorine pesticides were determined to have concentrations in the range of 0.0012–0.7928 mg/kg. The residual concentrations of carbamate pesticides in six samples and organochlorine pesticides in four samples exceeded their MRLs. The residual concentrations of five pyrethroid pesticides were within the range of 0.0016–6.0827 mg/kg and the pyrethroid residues in two samples exceeded their MRLs. The results revealed that pesticide residues in 70.73% of the vegetables samples were not detected, while in the rest of vegetables there were one or more pesticide residues and some even exceeded their MRLs, which would threaten the health of consumers. Our work provides significant information for the food safety regulations to control the excessive use of some pesticides on those kinds of vegetables from western China. Copyright © 2016 John Wiley & Sons, Ltd.     

离心压气机实际气体准三元数值计算

1前言目前，化工用高压离心式压缩机的工质繁多，它们大都为真实气体。针对压缩理想气体而言的流场分析结果，显然不能简单地用来比拟压缩实际气体的流场．在生产和科学研究中，对压气机进行实际气体的性能测试和流场详细测量都比工质使用空气（理想气体）的难度大得多。因此分析比较理想气体和实际气体这两种不同工质的流场，寻找它们之间的内在联系对指导实际气体的设计工作有重要的指导意义。在这方面，文献[1]已做了大量工作，本文采用了一些不同的方法，做了新的尝试。目的是讨论离心式叶轮内理想气体与实际气体流场分析结果之间的差异…     

First-principle study of electronic structure and stability of Sn0.5Sb0.5O2

A theoretical study on Sb-doped SnO₂ has been carried out by means of periodic density functional theory (DFT) at generalized gradient approximation (GGA) level. Stability and conductivity analyses were performed based on the formation energy and electronic structures. The results show that Sn_0.5Sb_0.5O₂ solid solution is stable because the formation energy of Sn_0.5Sb_0.5O₂ is −0.06 eV. The calculated energy band structure and density of states showed that the band gap of SnO₂ narrowed due to the presence of the Sb impurity energy levels in the bottom of the conduction band, namely there is Sb 5s distribution of electronic states from the Fermi level to the bottom of conduction band after the doping of antimony. The studies provide a theoretical basis to the development and application of Sn_1−xSb_xO₂ solid solution electrode.     

Impact of symmetric gate-recess length on the DC and RF characteristics of InP HEMTs

We fabricated a set of symmetric gate-recess devices with gate length of 70 nm.We kept the source-to-drain spacing(L_SD)unchanged,and obtained a group of devices with gate-recess length(L_recess)from 0.4μm to 0.8μm through process improvement.In order to suppress the influence of the kink effect,we have done SiN_X passivation treatment.The maximum saturation current density(ID_max)and maximum transconductance(g_m,max)increase as L_recess decreases to 0.4μm.At this time,the device shows ID_max=749.6 mA/mm at V_GS=0.2 V,V_DS=1.5 V,and g_m,max=1111 mS/mm at V_GS=?0.35 V,V_DS=1.5 V.Meanwhile,as L_recess increases,it causes parasitic capacitance C_gd and g_d to decrease,making f_max drastically increases.When L_recess=0.8μm,the device shows f_T=188 GHz and f_max=1112 GHz.     

一类新的四相最优序列集

对于一类正整数J, 利用两值自相关序列和四相最优序列, 构造了一类新的具有参数(2^2J-1,2^J+1,2^J+1)$的四相序列集. 新构造的序列集达到了Welch下界, 适用于CDMA通信系统.     

Hybrid algorithm for the two-dimensional rectangular layer-packing problem

In this paper, a rectangular layer-packing algorithm (RLPA) combined with modified genetic algorithm (GA) or particle swarm optimization (PSO) algorithm is developed to solve the problem with emerging restraints, which is raised from the two-dimensional rectangular packing problem with some small rectangles that need to be packed into a fixed rectangular object. RLPA is designed from the BL algorithm and lowest horizontal line algorithm. GA and PSO are also modified to satisfy the constraint conditions. Best GA or PSO parameters are obtained by conducting experiments on some typical instances. The results are also compared, which validate the quality of the solutions and show the effectiveness of the modified algorithm.