KdV方程和Kupersmidt方程的递推求解公式

根据Ｐａｉｎｌｅｖｅ分析的已知结果,给出了ＫｄＶ方程和Ｋｕｐｅｒｓｃｈｍｉｄｔ方程的新的递推求解公式。     

Base-promoted O-deprotonation/alkylation reaction of P(O)–OH compounds with alkyl halides

A novel base-promoted O-deprotonation/alkylation reaction of P(O)–OH compounds with alkyl halides has been developed. The protocol is practical, representing a simple way to produce a broad spectrum of functionalized phosphinates, phosphonates, and phosphates from basic starting materials with good to excellent yields. A plausible mechanism was proposed for this reaction.     

1.82-μm distributed feedback lasers with InGaAs/InGaAsP multiple-quantum wells for a H2 O sensing system

High-strained InGaAs/InGaAsP multiple quantum wells （MQWs） distributed feedback （DFB） lasers, fabricated using metal organic chemical vapor deposition, are presented at 1.82 μm with a high side-mode-suppression ratio of 49.53 dB. The current- and temperature-tuning rates of the DFB mode wavelength are 0.01 nm/mA and 0.13 nm/℃, respectively. A characteristic temperature of 51 K is also confirmed. The DFB laser demonstrates good performance and can be applied to H₂ O concentration sensing.     

Enantiomeric separation of six beta-adrenergic blockers on Chiralpak IB column and identification of chiral recognition mechanisms by molecular docking technique

Enantiomeric separation of six β-adrenergic blockers was systematically studied for the first time on a polysaccharide-based chiral stationary phase, i.e. Chiralpak IB, under the normal-phase mode. The effect of alcohol modifiers, alcohol content and basic additive on enantiomeric separation was evaluated and optimized. Under the optimal conditions, the enantiomers of atenolol, bevantolol, cartelol, esmolol, metoprolol and propranolol were all baseline resolved with resolutions of 1.50, 8.56, 2.05, 2.11, 3.56 and 4.02, respectively. Additionally, molecular docking was tested to explain chiral recognition mechanisms of this set of the drug enantiomers on Chiralpak IB. The details of the various interactions affecting enantiomeric separation were confirmed from the molecular level and the modeling data were in agreement with the chromatographic results concerning the enantioselectivity.     

Effects of minerals containing sodium,calcium, and iron on oxy-fuel combustion reactivity and kinetics of Zhundong coal via synthetic coal

Journal of Thermal Analysis and Calorimetry - The greatly high contents of alkali and alkali earth metals in Zhundong coal have a negative impact on the combustion and utilization of the coal,...     

光电化学水分解中铁酸盐光阴极的制备与改性

由n型半导体光阳极和p型半导体光阴极组成的无偏压光电化学电池通过太阳能可以将水直接转化为高能量密度的氢气,为解决太阳能利用过程中存在的间歇性和储存问题提供了一种潜在的经济有效的解决途径。金属氧化物具有低成本和易制备等优势,相比于发展较成熟的n型光阳极金属氧化物材料,传统的p型光阴极金属氧化物材料由于金属离子易受到光电腐蚀的影响,光电极寿命的提升是个很大的挑战。作为新型的金属氧化物光阴极材料,铁酸盐具有合适的带隙、较好的光稳定性、较正的起始电位以及较低的制备成本,正在成为光电化学电池实际应用中的有力竞争者。本文阐述了光电化学水分解的基本原理与提升光电极性能的一般方法,总结了近年来颇受关注的代表性铁酸盐光阴极材料CuFeO₂、CaFeO₄与LaFeO₃在制备方法、元素掺杂以及表面修饰等方面取得的重要进展,并对铁酸盐光阴极的未来发展趋势做了展望。     

含无关项布尔函数的对称变量检测算法

为简化布尔函数中12类对称变量的检测过程,提出了含无关项布尔函数基于最小项展开系数的对称变量检测算法.该算法通过判别布尔函数有序特征值矩阵的约束条件以实现对称变量的快速检测.应用结果表明,与现有方法相比,算法在适用的布尔函数变量数、检测类型、检测含无关项布尔函数和检测过程的复杂度方面表现较优.     

Progress of the key materials for organic solar cells

Organic solar cells have attracted academic and industrial interests due to the advantages like lightweight, flexibility and roll-to-roll fabrication. Nowadays, 18% power conversion efficiency has been achieved in the state-of-the-art organic solar cells. The recent rapid progress in organic solar cells relies on the continuously emerging new materials and device fabrication technologies, and the deep understanding on film morphology, molecular packing and device physics. Donor and acceptor materials are the key materials for organic solar cells since they determine the device performance. The past 25 years have witnessed an odyssey in developing high-performance donors and acceptors. In this review, we focus on those star materials and milestone work, and introduce the molecular structure evolution of key materials. These key materials include homopolymer donors, D-A copolymer donors, A-D-A small molecular donors, fullerene acceptors and nonfullerene acceptors. At last, we outlook the challenges and very important directions in key materials development.     

Nanosilica induced dose-dependent cytotoxicity and cell type-dependent multinucleation in HepG2 and L-02 cells

The prevalent exposure to nanosilica gained concerns about health effects of these particles on human beings. Although nanosilica-induced multinucleation has been confirmed previously, the underlying mechanism was still not clear; this study was to investigate the origination of multinucleated cells caused by nanosilica (62 nm) in both HepG2 and L-02 cells. Cell viability and cellular uptake was determined by MTT assay and transmission electron microscope (TEM), respectively. Giemsa staining was applied to detect multinucleation. To clarify the origination of multinucleated cells, fluorescent probes, PKH26 and PKH67, time-lapse observation were further conducted by confocal microscopy. Results indicated that nanosilica particles were internalized into cells and induced cytotoxicity in a dose-dependent manner. Quantification analysis showed that nanosilica significantly increased the rates of binucleated and multinucleated cells, which suggested mitotic catastrophe induction. Moreover, dynamic visualization verified that multinucleation resulted from cell fusion in HepG2 cells not in L-02 cells after nanosilica exposure, suggesting cell type-dependent multinucleation formation. Both multinucleation and cell fusion were involved in genetic instability, which emphasized the significance to explore the multinucleation induced by nanosilica via environmental, occupational and consumer product exposure.