Potentiometric Sensor Based on Thebaine-Reineckate Ion Association as Electroacitve Material for Thebaine Assay

Thebaine is one of the five major alkaloids of opium. It is a controlled substance (opiate) listed in the US code of Federal Regulations, Title 21 Part 1308,12(1985).Various methods have been developed for its determination, e.g. GC,HPLC, TLC, RIA, CZE, spectrometry, etc. Although potentiometric membrane sensors have been widely used in pharmaceutical analysis, no data has so far been reported for determination of thebaine by potentiometric membrane sensors.     

Co-Ag与Co-Au合金团簇核层结构模拟

钴基二元合金团簇具有特殊催化和电磁性能已成为研究的热点.探究Co-Ag与Co-Au团簇稳定结构是研究其性质的重要步骤.运用基于内核构建的自适应免疫优化算法对大尺寸Co_(55)Ag_n、Co_(55)Au_n(n=1-55, 60, 70, 80, 92)团簇结构进行优化.基于紧束缚势二阶矩近似的多体Gupta势函数被用于描述合金团簇原子间相互作用.计算结果显示Co_(55)Ag_n、Co_(55)Au_n(n=1-55, 60)最稳定结构的主要构型为Mackay二十面体.原子分布分析显示Co原子位于内层,而Ag、Au原子均趋于分布在外层,呈现出核层状态.对于大尺寸Co_(55)Ag_n、Co_(55)Au_n(n=80, 92)团簇,Co-Ag团簇采取无定形结构,而Co-Au团簇为规则的二十面体结构.     

Quantum Wave Equation of Non-conservative System

It is well known that Schr?dinger’s equation is only suitable for the particle in conservative force field. In atomic and molecular field, a particle can suffer the action of non-conservative force. In this paper, a new quantum wave equation is proposed, which can describe the particle in non-conservative force field. We think the new quantum wave equation can be used in many fields.     

海藻酸钙凝胶微球粒径的理论计算与实验

通过静电液滴发生器制备海藻酸钙凝胶微球,通过理论推导得到了微球粒径的计算公式.理论计算的结果表明,凝胶微球粒径的大小取决于静电压、电极距离、针头内径大小、注射器流速、海藻酸钠粘度和表面张力以及凝胶化体积收缩系数.理论计算结果与实验结果吻合得相当好.     

Scale-Invariance Exists in the Series of Character Intervals in the Four Great Chinese Novels *

The scale-invariance behavior has been widely observed in English or other phonetic language texts. In the present study, we examine whether the semantic language, Chinese can also show this behavior. Typically, the scale-invariance behavior is examined in the series of character intervals for the four great Chinese novels by a method of detrended fluctuation analysis. We observe that the scale-invariance behavior characterized by a scaling exponent around 0.60 exists in each novel. Moreover, we divide each novel into three parts with equal number of chapters, and we also observe the existence of scale-invariance in the interval series for each part. Interestingly, we find that there is evident difference in the scaling exponents between the first (or second) part and the third part in the novel of A dream of red mansions, and the difference between parts is not evident for the other three novels. Our observation suggests that there are two writing styles in A dream of red mansions, which are consistent with current prevailing view that the first 80 chapters and the last 40 chapters were accomplished by Xueqin Cao and E Gao, respectively. Our method may shed light on the identification of writing styles in written texts.     

Observation of the 2005 January 20 GLE Event Using Yangbajing Solar Neutron Telescope & Neutron Monitor

A solar cosmic rays Ground Level Enhancement(GLE) event associated with a X7.1/2b solar flare in 2005 January 20 was observed by the Yangbajing solar neutron telescope(SNT) and neutron monitor(NM), located at Yangbajing Tibet(90.53°E, 30.11°N, 4310m a.s.l) with the highest vertical geomagnetic cut-off rigidity of 14.1GV in NM network. The statistical significance of the counting rate enhancement recorded by solar neutron telescope in >40MeV channel was 3.7σ in the time window of 07:00—07:05UT and 6.0σ in the time window of 07:00—07:20UT, respectively. The onset time of 06:51—06:52UT for this GLE event was clearly observed by the Yangbajing NM. Our observation indicates that solar protons have been accelerated up to energies of >10GeV during this solar event.     

甚高频激发的容性耦合Ar+O_2等离子体电负特性研究

利用探针辅助的脉冲激光诱导负离子剥离诊断技术对掺入5%O_2的容性耦合Ar等离子体电负特性进行了诊断研究.首先详细解析了脉冲激光剥离后探针的电信号,分析了探针偏压在低于或高于空间电位下的探针收集信号特征;根据探针偏压与探针收集信号之间的依赖关系,用来描述Ar+O_2等离子体电负特性的等离子体电负度被定义为脉冲激光剥离出的电子电流与偏压高于空间电位的探针收集到的背景电子电流的饱和比值,并对等离子体电负度随放电气压、射频功率以及轴向位置的变化进行了诊断测量.实验结果表明等离子体的电负度随着射频功率的增加而减小、随着放电气压的上升而变大;由于非对称电极的分布特性,在轴向方向上靠近功率电极时等离子体电负度有升高的趋势,这种趋势可能与鞘层边界附近二次电子的动力学行为以及负离子的产生与消失过程有关.     

On the contribution of a hard galactic plane component to the excesses of secondary particles

The standard model of cosmic ray propagation has been very successful in explaining all kinds of galactic cosmic ray spectra. However, high precision measurement have recently revealed an appreciable discrepancy between data and model expectations, from spectrum observations of gamma-rays, e+/e- and probably the B=C ratio starting from ~10 GeV energy . In this work, we propose that a hard galactic plane component, supplied by the fresh cosmic ray sources and detained by local magnetic elds, can contribute additional secondary particles interacting with local materials. By properly choosing the intensity and spectral index of the harder component up to multi-T eV energy , a two-component gamma-ray spectrum is obtained and agrees very well with the observation. Simultaneously , the expected neutrino numbers from the galactic plane could contribute ~60% of IceCube observed neutrino number below a few hundreds of TeV under our model. In addition to these studies, we nd that the same pp-collision process responsible for the excess gamma ray emission could account for a signi cant amount of the positron excess, but a more detailed mechanism is needed for a full agreement. It is expected that the excesses in the p=p and B=C ratio will show up when energy is above ~10 GeV. We look forward this model being tested in the near future by new observations from AMS02, IceCube, AS-gamma, HA WC and future  experiments such as LHASSO, HiSCORE and CTA.     

Quantum Theory of Electronic Double-Slit Diffraction

Phenomena of electron, neutron, atomic and molecular diffraction have been studied in many experiments, and these experiments have been explained by some theoretical works. We study electronic double-slit diffraction with a quantum mechanical approach and obtain the following results： （1） When the ratio of d ＋ a /a=n （n = 1,2, 3,...）, orders n, 2n, 3n,... are missing in diffraction pattern. （2） When the ratio of d＋a/a≠ n （n =1,2, 3,...）, there is a not missing order in diffraction pattern. （3） The slit thickness c has a large affect on the electronic diffraction pattern, which is a new quantum effect. We believe that all the predictions in our work can be tested by the electronic double slit diffraction experiment.