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101.
102.
103.
The three-dimensional elasticity problem of the radial vibrations of a composite hollow spherical shell laminated of spherically orthotropic layers is considered. After formulating the equations, the exact determinantal equation from which the frequencies of vibration can be extracted is developed. Some calculated results for combinations of isotropic and orthotropic materials indicate the sensitivity of the frequencies to the geometry and material make up of the shells. 相似文献
104.
A robust, self-starting picosecond pulse source based on ytterbium (Yb3+) doped fiber laser is described. Utilizing a chirped-fiber-Bragg-grating (C-FBG) for dispersion control, solitary mode-locking is obtained without bulk dispersion compensation elements. A semiconductor saturable absorber (SESAM) is used for stable self-starting. 3.6 ps pulses are produced, with 45 MHz basic repetition-rate and mW scale average output power at 1060 nm. Detailed numerical simulations based on the modified nonlinear Schrödinger equation agree well with the experimental results and are used as a design tool for the solitary mode-locked picosecond laser. The presented design can be simply employed in an all-fiber environmentally-stable system. 相似文献
105.
Dvora Barnea Ovadia Shoham Yehuda Taitel A.E. Dukler 《International Journal of Multiphase Flow》1980,6(3):217-225
Experimental measurements of flow patterns for gas-liquid flow in inclined pipes are reported. The results compare well with a recently published theory for the prediction of flow patterns in horizontal and inclined pipes (Taitel & Dukler 1976). 相似文献
106.
The widespread and long-term use of TNT has led to extensive study of its thermal and explosive properties. Although much research on the thermolysis of TNT and polynitro organic compounds has been undertaken, the kinetics and mechanism of the initiation and propagation reactions and their dependence on the temperature and pressure are unclear. Here, we report a comprehensive computational DFT investigation of the unimolecular adiabatic (thermal) decomposition of TNT. On the basis of previous experimental observations, we have postulated three possible pathways for TNT decomposition, keeping the aromatic ring intact, and calculated them at room temperature (298 K), 800, 900, 1500, 1700, and 2000 K and at the detonation temperature of 3500 K. Our calculations suggest that at relatively low temperatures, reaction of the methyl substituent on the ring (C-H alpha attack), leading to the formation of 2,4-dinitro-anthranil, is both kinetically and thermodynamically the most favorable pathway, while homolysis of the C-NO(2) bond is endergonic and kinetically less favorable. At approximately 1250-1500 K, the situation changes, and the C-NO(2) homolysis pathway dominates TNT decomposition. Rearrangement of the NO(2) moiety to ONO followed by O-NO homolysis is a thermodynamically more favorable pathway than the C-NO(2) homolysis pathway at room temperature and is the most exergonic pathway at high temperatures; however, at all temperatures, the C-NO(2) --> C-ONO rearrangement-homolysis pathway is kinetically unfavorable as compared to the other two pathways. The computational temperature analysis we have performed sheds light on the pathway that might lead to a TNT explosion and on the temperature in which it becomes exergonic. The results appear to correlate closely with the experimentally derived shock wave detonation time (100-200 fs) for which only the C-NO(2) homolysis pathway is kinetically accessible. 相似文献
107.
It is shown that the antiaromatic character of certain conjugated cyclic hydrocarbons is due to the presence of an even number of distinct electron pairs in the system (such as, but not necessarily π electrons). In these systems, the ground state is constructed from an out‐of‐phase combination of two valence bond (VB) structures, and its equilibrium geometry is necessarily distorted along the coordinate that interchanges these structures. If a new symmetry element appears during the transition between the two structures, the ground electronic state at the symmetric point transforms as one of the nontotally symmetric irreducible representations of the point group. The conjugate excited state, formed from the in‐phase combination of the same two structures, transforms as the totally symmetric representation of the group and is strongly bound. Its structure is similar to that of the ground state at the symmetric point, and the energy separation between the two states is small compared to that of conjugated cyclic hydrocarbons having an odd number of distinct electron pairs. Motion along the “Kekulé‐type” vibrational mode on the excited‐state potential surface is very similar to motion along the reaction coordinate connecting the two distorted structures on the ground‐state surface. It is characterized by a significantly higher vibrational frequency compared to frequencies of similar modes in ground‐state molecules. These qualitative predictions are supported by quantum chemical calculations on cyclobutadiene, cyclooctatetraene, and pentalene. ©1999 John Wiley & Sons, Inc. Int J Quant Chem 71: 133–145, 1999 相似文献
108.
Intramolecular charge transfer can lead to substantial stabilization of singlet ground state and a corresponding increase of the singlet-triplet gap for molecules isoelectronic with the dianions of antiaromatic hydrocarbons. The formal biradicals 2,5-di-heterosubstituted-pentalenes and 1,5-di-heterosubstituted-cyclooctatetraenes are theoretically predicted to have the potential to be stable, persistent non-Kekulé molecules, as supported by high-level quantum chemical calculations. The singlet-triplet energy gaps and the S(0)-S(1) excitation energies of these molecules are similar to those of aromatic molecules rather than standard biradicals. These formal biradicals have a pronounced zwitterionic character, having a singlet ground state. The marked stabilization of the ground-state singlet for these non-Kekulé molecules is accompanied by a significant destabilization of the highest occupied molecular orbital (HOMO), leading to a low ionization potential (IP). This apparent inconsistency is explained by analyzing the electronic structure of the molecules. In the case of di-aza-pentalene, the energy of the first electronic excited state is only slightly lower than the ionization potential, making it a candidate for molecular autoionization. 相似文献
109.
A methodology for eliminating nondominant effects in models that describe transport phenomena in porous media is presented. The methodology is based on the introduction of dimensionless numbers and on a proper evaluation of the order of magnitude of terms. These dimensionless numbers are redefined as characteristics of transport and transformation phenomena in porous media. It is shown that different time scales and different length scales may have to be employed for different variables. A method for evaluating the order of magnitude of the error of prediction when terms are deleted, is presented. 相似文献
110.
The multiphoton ionization and two-photon excited fluorescence action spectra of nitric oxide are compared. At low fluence the two spectra differ when more than three photons are required for ionization. This may be due to the presence of several energy acquisition routes, providing new spectroscopic information on intermediate slates. 相似文献