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101.
The three-dimensional elasticity problem of the radial vibrations of a composite hollow spherical shell laminated of spherically orthotropic layers is considered. After formulating the equations, the exact determinantal equation from which the frequencies of vibration can be extracted is developed. Some calculated results for combinations of isotropic and orthotropic materials indicate the sensitivity of the frequencies to the geometry and material make up of the shells. 相似文献
102.
A robust, self-starting picosecond pulse source based on ytterbium (Yb3+) doped fiber laser is described. Utilizing a chirped-fiber-Bragg-grating (C-FBG) for dispersion control, solitary mode-locking is obtained without bulk dispersion compensation elements. A semiconductor saturable absorber (SESAM) is used for stable self-starting. 3.6 ps pulses are produced, with 45 MHz basic repetition-rate and mW scale average output power at 1060 nm. Detailed numerical simulations based on the modified nonlinear Schrödinger equation agree well with the experimental results and are used as a design tool for the solitary mode-locked picosecond laser. The presented design can be simply employed in an all-fiber environmentally-stable system. 相似文献
103.
Dvora Barnea Ovadia Shoham Yehuda Taitel A.E. Dukler 《International Journal of Multiphase Flow》1980,6(3):217-225
Experimental measurements of flow patterns for gas-liquid flow in inclined pipes are reported. The results compare well with a recently published theory for the prediction of flow patterns in horizontal and inclined pipes (Taitel & Dukler 1976). 相似文献
104.
Macroscopic modelling of transport phenomena in porous media. 2: Applications to mass,momentum and energy transport 总被引:1,自引:0,他引:1
In this second paper, the averaging rules presented in Part 1 are employed in order to develop a general macroscopic balance
equation and particular equations for mass, mass of a component, momentum and energy, all of a phase in a porous medium domain.
These balance equations involve averaged fluxes. Then macroscopic equations are developed for advective, dispersive and diffusive
fluxes, all in terms of averaged state variables of the system. These are combined with the macroscopic balance equations
to yield field equations that serve as the core of the mathematical models that describe the transport of extensive quantities
in a porous medium domain.
It is shown that the methodology of averaging leads to a better understanding of the effective stress concept employed in
dealing with transport phenomena in deformable porous media. 相似文献
105.
Two new polycyclic alkaloids, njaoamines G (1) and H (2) and 1,2,3,4-tetrahydroquinolin-4-one (3) have been isolated from the sponge Neopetrosia sp. collected at Pemba Island, Tanzania. Compounds 1 and 2 are close in structure to njaoamines A-F. Compound 3, known synthetically, is a new natural compound. The structures and relative stereochemistries of compounds 1 and 2 were elucidated on the basis of spectroscopic data. Njaoamines G and H are potent brine shrimp toxins with LD50 values of 0.17 μg/mL and 0.08 μg/mL for 1 and 2, respectively. 相似文献
106.
The widespread and long-term use of TNT has led to extensive study of its thermal and explosive properties. Although much research on the thermolysis of TNT and polynitro organic compounds has been undertaken, the kinetics and mechanism of the initiation and propagation reactions and their dependence on the temperature and pressure are unclear. Here, we report a comprehensive computational DFT investigation of the unimolecular adiabatic (thermal) decomposition of TNT. On the basis of previous experimental observations, we have postulated three possible pathways for TNT decomposition, keeping the aromatic ring intact, and calculated them at room temperature (298 K), 800, 900, 1500, 1700, and 2000 K and at the detonation temperature of 3500 K. Our calculations suggest that at relatively low temperatures, reaction of the methyl substituent on the ring (C-H alpha attack), leading to the formation of 2,4-dinitro-anthranil, is both kinetically and thermodynamically the most favorable pathway, while homolysis of the C-NO(2) bond is endergonic and kinetically less favorable. At approximately 1250-1500 K, the situation changes, and the C-NO(2) homolysis pathway dominates TNT decomposition. Rearrangement of the NO(2) moiety to ONO followed by O-NO homolysis is a thermodynamically more favorable pathway than the C-NO(2) homolysis pathway at room temperature and is the most exergonic pathway at high temperatures; however, at all temperatures, the C-NO(2) --> C-ONO rearrangement-homolysis pathway is kinetically unfavorable as compared to the other two pathways. The computational temperature analysis we have performed sheds light on the pathway that might lead to a TNT explosion and on the temperature in which it becomes exergonic. The results appear to correlate closely with the experimentally derived shock wave detonation time (100-200 fs) for which only the C-NO(2) homolysis pathway is kinetically accessible. 相似文献
107.
It is shown that the antiaromatic character of certain conjugated cyclic hydrocarbons is due to the presence of an even number of distinct electron pairs in the system (such as, but not necessarily π electrons). In these systems, the ground state is constructed from an out‐of‐phase combination of two valence bond (VB) structures, and its equilibrium geometry is necessarily distorted along the coordinate that interchanges these structures. If a new symmetry element appears during the transition between the two structures, the ground electronic state at the symmetric point transforms as one of the nontotally symmetric irreducible representations of the point group. The conjugate excited state, formed from the in‐phase combination of the same two structures, transforms as the totally symmetric representation of the group and is strongly bound. Its structure is similar to that of the ground state at the symmetric point, and the energy separation between the two states is small compared to that of conjugated cyclic hydrocarbons having an odd number of distinct electron pairs. Motion along the “Kekulé‐type” vibrational mode on the excited‐state potential surface is very similar to motion along the reaction coordinate connecting the two distorted structures on the ground‐state surface. It is characterized by a significantly higher vibrational frequency compared to frequencies of similar modes in ground‐state molecules. These qualitative predictions are supported by quantum chemical calculations on cyclobutadiene, cyclooctatetraene, and pentalene. ©1999 John Wiley & Sons, Inc. Int J Quant Chem 71: 133–145, 1999 相似文献
108.
Esther Azizi Felix Pavlotsky Avraham Kudish Pazit Flint Arie Solomon Yehuda Lerman Bernice Oberman Siegal Sadetzki 《Photochemistry and photobiology》2012,88(6):1507-1512
The objective of this study was to evaluate the effect of reduced sun exposure of outdoor workers on vitamin D status using different modalities of sun protection, for primary prevention of skin cancer. 25‐OH‐D3 measurements were performed in two successive winters, 8 (interim) and 20 months after initiation of the study, in three groups of male outdoor workers, enrolled in either a complete, partial or minimal sun protection program. Ambient solar UVB radiation was monitored simultaneously. No intragroup or intergroup differences were observed between the interim‐ and postintervention measurements of mean 25‐OH‐D3, which were close to 30 ng mL?1. Significant risk factors for postintervention 25‐OH‐D3 levels >33.8 ng mL?1 (a surrogate for reduced sun protection) were: previous sunburn episodes (OR 2.5; 95% CI 1.01–6.3; P = 0.05) and younger age (OR 0.92; 95 CI 0.86–0.98; P = 0.009). Outdoor workers of Western, compared with those of Eastern paternal origin had a borderline significant risk (OR 2.4; 95% CI 0.9–6.3; P = 0.07). A borderline significant effect (OR 2.9; 95% CI 0.97–10.1; P = 0.085) was also noted for those in the minimal intervention group. In conclusion, sun protection among outdoor workers following a successful intervention did not suppress mean winter 25‐OH‐D3. 相似文献
109.
Yehuda Gavriel Roth 《International Journal of Theoretical Physics》2012,51(12):3847-3855
Quantum measurement requires an observer to prepare a specific measuring device among alternatives where the prepared basis of states, representing the device, is the way the observer interprets quantum reality into his macroscopic word. We redefine that observer role through a new concept: The observer determination, that is, a selection between the measurement options facing the observer. Unlike the measurement itself that is rationalized as dictated by nature, the observer determination can neither be measured nor proven to be true or false. In this paper we propose a mathematical formalism demonstrating how to define the observer determination. Moreover, we present a scheme showing how the apparently subjective observer determination transform into a measurable quantity. 相似文献
110.
Flow with evaporation in parallel lines with common inlet and outlet headers may result in an uneven flow distribution among the parallel pipes. The prediction of the flow rate distribution in steady state as well as under transient conditions was based on simplified models. In this paper a more accurate time dependent model based on the temporal-local flow pattern in the pipe is presented. The pipe is subdivided into numerical sections and the calculation of the pressure drop in each cell is based on mechanistic models that are specific for the flow pattern in the cell. 相似文献