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171.
Poly(2-vinylpyridine) or poly(4-vinylpyridine) coated on a piezoelectric quartz crystal adsorbed copper, thus decreasing the oscillation frequency. The bound copper could be removed by EDTA solution. Poly(4-vinylpyridine) is recommended to determine copper (5–35 μM) in a maleate buffer at pH 6.6 flowing over the coated crystal for 5 min. Iron(III) and cadmium interfered. 相似文献
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We have determined the orientational distribution of cyano-substituted side chains of a rubbed polyimide film, and a liquid crystal monolayer adsorbed on the film, by means of optical second harmonic generation. With the orientational distribution of a main chain that was measured in a previous study by means of near-edge X-ray absorption fine structure (NEXAFS) spectroscopy, we have obtained the correlation of all the orientational distributions contributing to the alignment of LC molecules, i.e. pretilt angle. We find that the side chain plays a role in increasing the pretilt angle, but in the case of rubbing strength dependence, the main chain has stronger correlation with the pretilt angle than has the side chain. 相似文献
175.
Akashi H. Sakai Y. Takahashi N. Sasaki T. 《IEEE transactions on plasma science. IEEE Nuclear and Plasma Sciences Society》1999,27(1):8-9
Dynamics of a filament discharge in a discharge-excited XeCl excimer laser medium has been simulated for a sequence of discharge pulses (shots). In the present model a filament discharge is triggered at a microprotrusion on a cathode surface. After the first discharge initiation, a hot spot is created near the cathode, then filament develops toward the anode in the second shot. Images of the filament discharge development and its properties in a XeCl excimer laser are presented 相似文献
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本文利用广义逆矩阵,提出了解决非线性屈曲问题的广义增量法。并用该法分析了非线性荷载-位移关系曲线(其中包括极值点)。最后,给出一数值算例—三维扁平桁架结构的弹塑性屈曲分析,证明了本文方法的正确性和实用性。 相似文献
178.
Nitroxyl radicals (nitroxides) with unpaired electron are widely used as antioxidants, contrast agents, and spin probes. Although piperidine nitroxyl radicals have many applications, these are mainly tetramethylpiperidine compounds, and only a few reports consider the substitution of N-O surround as a reaction site, such as 2,2,6,6-tetrasubstituted piperidine nitroxyl radicals. Our results revealed that the 2,6-position of the 2,2,6,6-tetramethylpiperidin-4-one compound was substituted by cyclohexyl groups to produce 2,2,6,6-tetrasubstituted piperidin-4-one derivatives under mild reaction conditions. An interesting result was obtained by using 15N-labeled NH4Cl instead of 14NH4Cl: it gave 15N-labeled 2,2,6,6-tetrasubstituted piperidin-4-one-1-oxyls with a high 15N content. In conclusion, the new method for the synthesis of nitroxyl radicals readily yields 2,2,6,6-tetrasubstituted piperidin-4-one under mild conditions. 相似文献
179.
Optical limiting effects of silicon phthalocyanine (SiPc) oligomers have been examined in the Q band region in order to demonstrate a novel concept for controlling the wavelength of optical limiting effects. 相似文献
180.
Kazuhiro Fukumori Yoshikatsu Akiyama Yoshikazu Kumashiro Jun Kobayashi Masayuki Yamato Kiyotaka Sakai Teruo Okano 《Macromolecular bioscience》2010,10(10):1117-1129
Ultra thin poly(N‐isopropylacrylamide) (PIPAAm) modified glass coverslips (PIAPAm‐CS) using electron beam irradiation exhibited a clear relationship between the polymer thickness and thermal cell adhesion/detachment behavior. The polymer thickness dependency and the characteristic of ultra thin PIPAAm layer, has been illustrated in terms of the molecular motion of the modified PIPAAm chains. PIPAAm‐CSs surfaces with various area‐polymer densities and thicknesses were characterized by AFM and protein adsorption assay. The newly obtained results gave a further insight into the illustration. Finally, the future application of intelligent surfaces was discussed for fabricating tissue and organ.