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151.
Yoshikatsu Miyashita Yoshimasa Takahashi Yasuhiko Yotsui Hidetsugu Abe Shin-Ichi Sasaki 《Analytica chimica acta》1981,133(4):615-624
A graph-theoretical algorithm based on the minimal spanning tree (MST) is applied to structure—activity problems. The method is helpful in interpreting the results of cluster analysis, and becomes useful by combining with the mapping method that illustrates approximations of a multidimensional data structure. The antibacterial spectra of cephalosporins are analyzed by the MST approach and a linear mapping method. The main diameter obtained by MST gives the representative data set and clarifies the substituent effect on the antibacterial spectra. Relations between the central nervous system activity of benzodiazepine derivatives and their physicochemical parameters are also analyzed by MST and nonlinear mapping methods. These results for cephalosporins and benzodiazepines prove that MST is very useful in understanding the position of compounds in feature space and their activities. 相似文献
152.
A new application of monoacidic dyes is reported for the determination of strychnine and methylatropine. The method is based on solvent extraction into 1,2-dichloroethane of the ion-pair or addition compound formed between tetrabromophenolphthalein ethyl ester and quaternary ammonium salts or alkaloids. The absorbance of the extracts is linearly dependent on the concentration of strychnine or methylatropine initially present in the aqueous solution. 相似文献
153.
Mathematische Annalen - 相似文献
154.
N. Sakai 《Zeitschrift fur Physik C Particles and Fields》1981,10(2):153-157
We propose a resummation of QCD radiative corrections in large transverse momentum hadronic processes, based on the introduction of an infrared cut-off, linked to the confinement radius. An analysis of the inclusive reactionspp → π0 X andpp → γX and of γ/π0 ratio is presented. 相似文献
155.
The heats of fusion of methoxycarbonyl-benzenes (12 isomers) and -naphthalenes (32 isomers) have been determined by the differential scanning calorimetric method and the correlation of numbers and positions of methoxycarbonyl groups against the parameters of fusion (melting point, enthalpy and entropy) are discussed. The enthalpy—entropy relationship shows two correlation lines depending on the symmetry of the molecules including the positions of the substituents. 相似文献
156.
157.
Toshimasa Hashimoto Tetsuya Sakai Seizo Miyata 《Journal of Polymer Science.Polymer Physics》1978,16(11):1965-1971
Thermally stimulated current (TSC) has been observed in extended-chain crystals of polyethylene above room temperature. The TSC spectra exhibit two current peaks of opposite polarity. The peaks were separated into separate components by curve fitting. The position of the negative peak, which appears at 123°C, is independent of charging conditions. The positive current increases after γ irradiation or aging of the samples. 相似文献
158.
159.
Yasuhiko H. Mori Hiroshi Sano Kazunari Komotori 《International Journal of Multiphase Flow》1980,6(3):255-266
Cinemicrophotography is applied to the boiling of emulsions of water dispersed in oils whose boiling points are higher than that of water. The layer of emulsion is made thin enough to make possible a microscopic observation by transmitted light through the layer. Two alternative processes of bubble formation are found: a periodical bubble formation at specified sites on the heated solid surface contacting the emulsion and a casual bubble formation some distance away from the surface. The basic mechanisms of those processes are discussed. 相似文献
160.
The magnetic susceptibility of RB2C2 has been measured in the temperature range of 3–300 K. Curie-Weiss fits to the susceptibilities led to effective moments in agreement with those expected for R3+ ions. The RB2C2 (R = Ce, Nd, Sm, Gd, Tb, Er, and Tm) compounds are antiferromagnetic. Metamagnetic transitions at low fields were observed for CeB2C2 and TbB2C2. The compounds, DyB2C2 and HoB2C2, are ferromagnets with complex magnetic structures. Praseodymium borocarbide becomes a Van Vleck paramagnet at low temperature. The magnetic ordering temperatures of these compounds are discussed in terms of their crystal structure and the RKKY theory. 相似文献