Development of chromatographic methods to monitor the synthesis of (tributylstannyl)methanol through unstable lithiated intermediates

Simple and robust derivatization methods for monitoring the formation of (tributylstannyl)methanol from tributyltin hydride via unstable lithiated intermediates have been developed and validated. These analytes present both chromatographic and detection difficulties in their native states due to low volatility, poor aqueous solubility/stability, and lack of a chromophore. Derivatization of these analytes to trimethylsilyl analogues for gas chromatographic analysis or to benzenesulfonyl urethane analogues for reversed-phase liquid chromatographic analysis was evaluated. The derivatization/gas chromatographic methods developed were demonstrated to be more specific and sensitive for impurity monitoring during (tributylstannyl)methanol preparation.     

CR-39 sensitivity analysis on heavy ion beam with atomic force microscope

Preliminary results of feasibility study to apply atomic force microscope (AFM) to the quantitative analysis for minute etch pits on CR-39 are reported comparing with the optical microscope observation. The growth curves of the Si track diameter and length obtained by both technqiues were discussed in relation to the track sensitivity and the etch induction time.     

Measurement of longitudinal atom density distributions in a graphite tube furnace using coherent forward scattering

A method for measuring longitudinal atom density distributions in a graphite tube furnace using coherent forward scattering is proposed. A transverse magnetic field is locally applied to the atomic vapor in a graphite tube. Relative atom density distributions for the elements Cd, Cu, Mn, Ni and Pb are measured.     

Room temperature magnetoresistance anisotropies in p-type (001) Si on sapphire

Magnetoresistance anisotropies, differing from those of bulk p-type Si, have been observed on p-type Si film on sapphire (SOS). They may arise from the valence band split and deformed by a large compressive strain due to thermal expansion coefficient difference between Si and sapphire.     

Photoaddressable polymers for liquid crystal alignment

We demonstrate reversible photoinduced in situ reorientation of low molecular mass liquid crystals (LCs) by means of photoaddressable polymers (PAPs). These polymers contain mesogenic azobenzene side chains optimized to reorient cooperatively and effectively upon illumination with polarized light. Various low molecular mass LCs were introduced between two PAP layers and these sandwich devices were tested with respect to stability and reversibility of photoinduced orientation. Dissolution of the PAP layer by the low molecular mass LC was observed for several material combinations and systematically investigated. Different anisotropic dyes were added as fluorescence markers in order to monitor the photoinduced LC orientation. With an optimized material combination, more than 10 reversible reorientation processes could be realized with polarized light of either 514 or 405 nm wavelength, without any reduction in alignment quality. Further, microscopic polarized fluorescence patterns could be produced and erased within short exposure times.     

Methane plasma polymerization by low‐temperature cascade arc discharge for enhanced adhesion of primer to thermoplastic olefins

Improvement of primer adhesion to thermoplastic olefins (TPOs) by methane plasma polymerization with a low‐temperature cascade arc discharge was investigated. Methane plasma with a low‐temperature cascade arc plasma torch can be used for improving the primer adhesion to TPOs. Tape‐adhesion tests (ASTM 3359‐92a method) demonstrated this improvement, with a rating of 0 for untreated TPOs and 5 for methane plasma‐polymerized TPOs at certain plasma conditions even for aging at 60 °C and 80% relative humidity for 5 days. The adhesion to primer for the soft, flexible TPOs (ETA‐3041c and ETA‐3101) was easily enhanced. The adhesion to primer for the hard and brittle TPOs (ETA‐3183) needs to optimize the plasma conditions to pass the dry‐ and wet‐adhesion test with methane plasmas. To relate the surface characteristics of methane plasma‐polymerized TPOs to adhesion performance with primer, the wettability and polarity of TPOs were evaluated by the contact‐angle measurements of primer and deionized water to TPOs. TPO surface morphology was evaluated with scanning electron microscopy. The surface composition was characterized with electron spectroscopy for chemical analysis. © 2003 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 41: 2004–2021, 2003     

Distribution of polymer deposition in plasma polymerization. II. Effect of reactor design

The effects of relative positions of the monomer inlet and the r.f. coil, and of the inlet and outlet, on the distribution of polymer deposition in plasma polymerization of ethylene were investigated using an electrodeless glow discharge by a 13.5-MHz radiofrequency source. The diffusional transport of active species created under the r.f. coil, diffusional transport of polymer forming species, and flow of gas in the system are important factors that determine the distributions of polymer deposition observed in plasma polymerization of ethylene. The mechanisms of polymer deposition are discussed in conjunction with postulated plasma polymerization mechanisms.     

Classical stability of direct products of spheres in gravitational systems

Classical stability of Einstein spaces S^d₁ ×?×S^d_n(d_j ? 2) against all fluctuations is investigated in euclidean gravity with a cosmological constant. It is shown that S^d is classically stable, while S^d₁ ×?× S^d_n(n ? 2) is classically unstable. As a generalization of this analysis it is proved that a compact Einstein space B₁ ×?× B_n(n ? 2) which is a direct product of each Einstein space is classically unstable. Non-Einstein spaces M² × S⁴ (M² × S² × S²) are also considered in six- dimensional Einstein-Maxwell theory and are shown to be classically stable (unstable).     

Intrinsic Josephson effects in 60-K phase YBCO thin film mesas

We fabricatedc-axis oriented meas on YBa₂Cu₃O_7−δ thin films. Columnar structures with an area of 20×20 μm² and a depth of 0.1 μm were formed on oxygen deficient films with a critical temperature (T _c ) of 64 K or less. The devices showed hysteretic I–V curves without any branches. The dependence of the critical current density on the temperature nearT _c is explained by the Ambegaokar-Baratoff relation.