双齿配位过渡金属化合物化学——Ⅲ.钒的邻巯基苯酚配合物的顺磁谱研究

测定了二个顺磁性化合物(Ph_1P)[V_2(mp)_6](Ⅰ)和(Ph_4P)_2[NaV(mp)_3 (MeCN)(MeOH)](Ⅱ)(H_2mp=邻巯基苯酚,o-HO_1C_6H_4SH)的固态和/或溶液中的顺磁波谱。(Ⅰ)的77K固态谱及(Ⅱ)的室温固态谱均经模拟计算,认为它们的钒原子处在S=l/2的Ⅰ=7/2状态,(Ⅱ)的低温(77K)溶液谱(乙腈)与Ⅱ的固态谱相同,均有特征的八条精细结构,认为非配对电子基本上定域在钒原子的周围。     

“J—646”新型光学光敏胶胶合工艺简介

“J—646”光敏胶具有透光率好,收缩率小,粘接强度适中,耐老化,毒性小和成本低廉等特点。本文简要介绍了该胶的胶合工艺。     

200兆赫高功率CW锁模YAG激光泵浦源研究

本文报导一台200MHz 12W平均功率的CW锁模Nd:YAG激光泵浦源,输出脉宽约100ps,能够可靠地长期稳定运转。     

不稳定晶格的能带计算

由于导电高分子是宽能带体系,紧束缚近似下的Su-Schrieffer-Heeger(缩写为SSH)模型存在一系列问题,需要加以改进才能满意地研究导电高分子的一维晶格的不稳定性。本工作将稳定晶格的Wannier函数方法加以推广,用来计算不稳定晶格的电子能带。数值结果表明,本方法的收敛性很快,取到三近邻时,能带的准确度可优于1％。同时能很精确地确定不稳定性所引起的二聚化。 关键词：     

Bayesian sequential reliability for Weibull and related distributions

Assume that the probability density function for the lifetime of a newly designed product has the form: [H(t)/Q()] exp{–H(t)/Q()}. The Exponential(), Rayleigh, WeibullW(, ) and Pareto pdf's are special cases.Q() will be assumed to have an inverse Gamma prior. Assume thatm independent products are to be tested with replacement. A Bayesian Sequential Reliability Demonstration Testing plan is used to eigher accept the product and start formal production, or reject the product for reengineering. The test criterion is the intersection of two goals, a minimal goal to begin production and a mature product goal. The exact values of various risks and the distribution of total number of failures are evaluated. Based on a result about a Poisson process, the expected stopping time for the exponential failure time is also found. Included in these risks and expected stopping times are frequentist versions, thereof, so that the results also provide frequentist answers for a class of interesting stopping rules.This research was supported by NSF grants DMS-8703620 and DMS-8923071, and forms part of the Ph.D. Thesis of the first author, the development of which was supported in part by a David Ross grant at Purdue University. The authors thank the editors and a referee for insightful comments and suggestions.     

食饵种群具有常数收获率的捕食—食饵模型分析

本文研究食饵种群具有常数收获效的捕食－食饵模型：｛ｄｘ／ｄｔ＝ｂｘ＾２（１－ｘ／ｋ）－βｘｙ－ｈｄｙ／ｄｔ＝－ｃｙ＋ｄｘｙ讨论了极限环的存在性、唯一性和正平衡点的全局稳定性以及分界线环的存在性。