Thermoelastoplastic deformation of a thick-walled cylinder with a radial crack

The thermoelastoplastic fracture mechanics problem of a thick-walled cylinder subjected to internal pressure and a nonuniform temperature field is solved by the method of elastic solutions combined with the finite-element method. The correctness of the solution is provided by using the Barenblatt crack model, in which the stress and strain fields are regular. The elastoplastic problem of a cracked cylinder subjected to internal pressure and a nonuniform temperature field are solved. The calculation results are compared with available data. __________ Translated from Prikladnaya Mekhanika i Tekhnicheskaya Fizika, Vol. 49, No. 3, pp. 173–183, May–June, 2008.     

Axisymmetric frictionless contact of functionally graded materials

The main interest of this study is a new method to solve the axisymmetric frictionless contact problem of functionally graded materials (FGMs). Based on the fact that an arbitrary curve can be approached by a series of continuous but piecewise linear curves, the FGM is divided into a series of sub-layers with shear modulus varying linearly in each sub-layer and continuous at the sub-interfaces. With this model, the axisymmetric frictionless contact problem of a functionally graded coated half-space is investigated. By using the transfer matrix method and Hankel integral transform technique, the problem is reduced to a Cauchy singular integral equation. The contact pressure, contact region and indentation are calculated for various indenters by solving the equations numerically. An erratum to this article can be found at     

Water wave radiation by a sphere submerged in water with an ice-cover

Using the multipoles method, we formulate the problems of radiation (both heave and sway) of water waves by a submerged sphere in deep as well as in uniform finite depth water with an ice-cover, with the ice-cover being modelled as an elastic plate of very small thickness. In each case this leads to an infinite system of linear equations which are solved numerically by standard techniques. The added-mass and damping coefficients for a heaving and swaying sphere are obtained and depicted graphically against the wave number for various values of the radius of the submerged sphere and flexural rigidity of the ice-cover to show the effect of the presence of ice-cover on these quantities. When the flexural rigidity is taken to be zero, the numerical results for the added-mass and damping coefficient for water with a free surface are recovered.     

Numerical method and models for anti-plane strain of a system with a thin elastic wedge

The paper presents a general method to find asymptotics for a (multi-)wedge system containing a thin wedge. It employs separation of the symmetric and anti-symmetric parts of the boundary displacements and tractions of the wedge. The method is applicable when the angle of the thin wedge turns to zero. A physical interpretation of the derived equations is obtained by using power expansions of non-polynomial functions, which appear after the Mellin transform. We establish that the first term in the expansion of the symmetric part corresponds to shear, while the first term of the anti-symmetric part describes deflection of the wedge axis. Numerical experiments, performed by using a code developed on the basis of the theory, show that using only the first terms of the expansions insignificantly influence accuracy: the approximate results coincide with the exact values of roots to the third significant digit even for the wedge angle of 30°.     

Erratum: Preparation of size‐controlled In2O3 nanoparticles

The article referenced above was first published online on 7 August 2007 with incorrect pagination; the pagination has now been corrected online and in print. Copyright © 2007 John Wiley & Sons, Ltd.     

Synthesis of grafted poly(p‐phenyleneethynylene) with energy donor–acceptor architecture via atom transfer radical polymerization: Towards nonaggregating and hole‐facilitating light‐emitting material

In this contribution, we demonstrate a new effective methodology for constructing highly efficient and durable poly(p‐phenyleneethynylene) (PPE) containing emissive material with nonaggregating and hole‐facilitating properties through the introduction of hole‐transporting blocks into the PPE system as the grafting coils as well as building the energy donor–acceptor architecture between the grafting coils and the PPE backbone. Poly(2‐(carbazol‐9‐yl)ethyl methacrylate) (PCzEMA), herein, is chosen as the hole‐transporting blocks, and incorporated into the PPE system as the grafting coils via atom transfer radical polymerization. The chemical structure of the resultant copolymer, PPE‐g‐PCzEMA, was characterized by NMR and gel permeation chromatography, showing that the desirable copolymer was obtained with the narrow polydispersity. The increased thermal stability of PPE‐g‐PCzEMA was confirmed by thermogravimetric analysis and differential scanning calorimetry along with its macroinitiator. The optoelectronic properties of this copolymer were studied in detail by ultraviolet‐visible absorption, photoluminescence emission and excitation spectra, and cyclic voltammogram (CV). The results indicate that PPE‐g‐PCzEMA exhibits the solid‐state luminescent property dominated by individual lumophores, and also the energy transfer process from the PCzEMA blocks to the PPE backbone with a relatively higher energy transfer efficiency in the solid‐state compared to that of the solution state. Additionally, the hole‐injection property is greatly facilitated due to the presence of PCzEMA, as confirmed by CV profiles. All these data indicate that PPE‐g‐PCzEMA is a good candidate for use in optoelectronic devices. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 3776–3787, 2007     

Pd (II)‐catalyzed vinyl addition polymerization of novel functionalized norbornene bearing dimethyl carboxylate groups

Three novel functionalized polynorbornenes (PNB) with pendant dimethyl carboxylate group (carboxylates—acetate, propionate, and butyrate) are synthesized as a vinyl‐type with a palladium (II) catalyst in high yield. The effects of size of substitutents, molar ratio of monomer to catalyst, solvent polarity, reaction time, and temperature on the polymerization of exo‐norbornene dimethyl propionate were systematically investigated. The low molar ratio and temperature, as well as high polarity of solvent, and long reaction time, are favorable for the enhancement of the monomer conversion, especially, the solvent have an obvious effect on the catalyst activity. The resulting poly(cis‐norbornene‐exo‐2,3‐dimethyl carboxylates) (PNB‐dimethyl carboxylates) show good solubility in common organic solvent and high thermal stability up to 360 °C. The glass transition temperature was detected by DMA at 331, 324, and 318 °C for acetate, propionate, and butyrate, respectively. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 3391–3399, 2007