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961.
A mild and general cycloaddition of arynes with iodonium ylides protocol has been developed for the synthesis of benzofurans. In the presence of CsF, ortho-silyl aryltriflates were reacted with iodonium ylides smoothly at room temperature in moderate to good yields. 相似文献
962.
本文以KH560、苯乙烯、马来酸酐为连接组分,将二氧化钛接枝到聚(苯乙烯-二乙烯基苯)微球的表面,成功制备了无孔和多孔纳米复合微球。研究了硅烷偶联剂(KH560)和苯乙烯对二氧化钛在无孔微球表面的分散性和接枝数量以及支撑微球的多孔性质对接枝到微球内部的二氧化钛数量的影响。结果表明,KH560和苯乙烯能够提高二氧化钛在微球表面的分散性和稳定性,使二氧化钛以30-80nm的粒径接枝在微球表面。苯乙烯又能使二氧化钛在无孔微球表面的接枝数量从10.4%增大到20.4%。平均孔径为136nm的多孔微球为支撑微球得到的复合粒子中二氧化钛最高接枝量可达26%,明显高于无孔微球和平均孔径为31nm的多孔微球。 相似文献
963.
Piçarra S Afonso CA Kurteva VB Fedorov A Martinho JM Farinha JP 《Journal of colloid and interface science》2012,368(1):21-33
We present a study of chain interdiffusion in films formed by specially architectured PBMA nanoparticles by Förster Resonance Energy Transfer – FRET. Polymer nanoparticles contained linear chains with narrower molecular weight distributions than other previous reports, allowing a more detailed study. Apparent fractions of mixing and diffusion coefficients, determined from the quantum efficiency of energy transfer, were used to characterize the interdiffusion mechanism in the different films. The resistance of the films to dissolution by a good solvent was finally correlated with the interdiffusion results, in order to get information about film healing. We concluded that whenever interdiffusion occurs between nanoparticles containing linear chains and fully cross-linked nanoparticles, healing becomes more effective in spite of showing slower interdiffusion. We also observed that particles with longer chains are more effective for film healing. Finally, we concluded that interdiffusion occurs both ways across interfaces in blends formed by particles swollen with linear chains of different molecular weights. 相似文献
964.
Hardouin-Lerouge M Chesneau B Allain M Hudhomme P 《The Journal of organic chemistry》2012,77(5):2441-2445
An efficient synthesis of unprecedented fused extended-tetrathiafulvalene-dipyridoquinoxaline (exTTF-dpq) dyad is described through the Horner-Wardsworth-Emmons olefination methodology from the dipyrido[3,2-a:2',3'-c]-benzo[3,4]phenazine-11,16-quinone (NqPhen) ligand starting material. This exTTF-dpq dyad is demonstrated to act as a dual redox and colorimetric sensor for cations exploiting the proximity between the redox tetrathiafulvalene and the optical phenanthroline detecting sites. Its ability for sensing cations from the d-group metal transitions (Fe(2+), Ni(2+), and Zn(2+)) and also with varied cations such as Ca(2+) and Pb(2+) is presented. 相似文献
965.
Hernández-Espinoza AB Piñón-Muñiz MI Rascón-Chu A Santana-Rodríguez VM Carvajal-Millan E 《Molecules (Basel, Switzerland)》2012,17(3):2428-2436
Arabinoxylan gels exhibiting different rheological and lycopene transport properties were obtained by modifying the polysaccharide concentration from 3 to 4% (w/v). The apparent lycopene diffusion coefficient decreased from 2.7 × 10?? to 2.4 × 10?? cm2/s as the arabinoxylan concentration in the gel changed from 3 to 4% (w/v). A low amount of lycopene is released by diffusion from arabinoxylan gels. These results indicate that arabinoxylan gels could be carriers for lycopene delivery in specific sites after network degradation. The possibility to modulate lycopene release from arabinoxylan gels makes these biomaterials potential candidates for the controlled delivery of biomolecules. 相似文献
966.
Henryk Paul Adam Morawiec Emmanuel Bouzy Jean-Jacques Fundenberger Andrzej Piątkowski 《Mikrochimica acta》2006,155(1-2):243-250
The texture evolution during deformation of high purity fcc single crystals with initial (112) [11
] orientation has been characterised in detail by transmission (TEM) and scanning (SEM–FEG) electron microscopes. The channel-die
deformed samples up to reduction of about 1–1.5, first developing strongly anisotropic layers of elongated cells or twin-matrix
plates and then compact clusters of SB. Substantial progress in understanding the mechanism of the SB formation was possible
thanks to systematic local orientation measurements (orientation mapping) using SEM and TEM. These two techniques of local
orientation measurements have been compared with respect to their applicability for the study of shear banding phenomenon
and for characterization of the specific nanostructure of SB in metals with fcc lattice. It was shown that well-developed
SB exhibit large orientation spreads up to 35–40° with respect to the adjacent areas outside the band. Most of these misorientations
occur by rotations about the TD‖〈110〉 axis with significant further rotations about 〈112〉 poles. This ultimately leads to
the formation of the texture components whose occurrence cannot be explained by models homogeneous deformation. 相似文献
967.
Bonfill M Mangas S Cusidó RM Osuna L Piñol MT Palazón J 《Biomedical chromatography : BMC》2006,20(2):151-153
The identification of the four principal triterpenoid components of Centella asiatica has been achieved by TLC on silica gel plates and mass spectrometry, as a modification of the method described in the European Pharmacopoeia (5th edn). A combination of ethyl acetate and methanol as the mobile phase was found to be successful in separating these compounds from the rest of the main components of the extract. The spots were detected with anisaldehyde solution. The separated compounds were confirmed by MALDI -TOF mass spectrometry. 相似文献
968.
Baffreau J Leroy-Lhez S Hudhomme P Groeneveld MM van Stokkum IH Williams RM 《The journal of physical chemistry. A》2006,110(49):13123-13125
Two n-type molecular materials are covalently combined into a new photovoltaic component for polymer solar cells. Light harvesting by the perylenediimide results in very fast energy transfer to the fullerene unit, as shown with femtosecond transient absorption spectroscopy in toluene solution. Two energy transfer rates are observed of 2.5 x 10(12) s-1 (53%) and 2 x 10(11) s-1 (47%), attributed to two conformations. The final excited state that is populated is a perylenediimide-based triplet state that is formed on the nanosecond time scale with a high yield. 相似文献
969.
970.
We present a modified Chan-Vese functional and give its theoretical proof. By using the geometric heat flow method to all the Euler-Lagrange equations, a system of evolution equations in level set formulation is derived. We study the existence of solution to this system by Schauder fixed point theorem and the implicit function theorem in Banach space. This variational formulation can detect interior and exterior boundaries of desired object(s) in color images. 相似文献