3,4-二(3-苯氧基-4-氟苯基)-2,5-二苯基苯基接枝聚硅氧烷气相色谱固定相的合成与表征（英文）

合成了一种耐高温的3,4-二(3-苯氧基-4-氟苯基)-2,5-二苯基苯基接枝聚硅氧烷(DPFP)固定相,使用静态涂渍法将其涂渍到毛细管柱内壁上,制成气相色谱柱。分离裂解乙烯的色谱图显示DPFP固定相在360℃时仍具有良好的分离能力。DPFP固定相的柱效为3 324块/米(保留因子(k)4.24,萘,0.25 mm i.d.)。麦克雷诺常数计算结果显示DPFP固定相属中等极性。溶剂化参数模型结果显示DPFP固定相与溶质之间的主要作用力为偶极-诱导偶极作用力、氢键碱性作用力。Grob试剂分离结果显示DPFP色谱柱具有良好的选择性与惰性。另外,芳香族同分异构体、苯取代物、多环芳烃、脂肪酸酯及脂肪醇都得到了良好的分离,表明DPFP固定相在应用方面有巨大的潜力。     

直接进样-超高效液相色谱-三重四极杆质谱法同时快速测定水中12种微囊藻毒素和1种节球藻毒素

建立了超高效液相色谱-三重四极杆质谱快速检测水中12种微囊藻毒素(MCs)和1种节球藻毒素(NOD)的分析方法。水样经甲醇等体积稀释,聚醚砜(PES)滤膜过滤,滤液直接进样分析,以0.1%(v/v)甲酸乙腈溶液和0.2%(v/v)甲酸水溶液作为流动相进行梯度洗脱,采用ACQUITY UPLC BEH 300 C18柱(100 mm×2.1 mm,1.7μm)进行分离,在电喷雾正离子模式下以MRM方式进行检测,标准溶液外标法定量。方法的检出限为0.03~0.1μg/L,定量限为0.1~0.3μg/L。对自来水和河水样品进行加标回收试验,目标物的平均加标回收率为79.5%~123%,相对标准偏差为1.0%~20%(n=6)。该法简单、灵敏、准确,适用于水中12种微囊藻毒素和1种节球藻毒素的快速测定。     

A novel lipase-based stationary phase in liquid chromatography

A streptavidin functionalized capillary immune microreactor was designed for highly efficient flow-through chemiluminescent (CL) immunoassay. The functionalized capillary could be used as both a support for highly efficient immobilization of antibody and a flow cell for flow-through immunoassay. The functionalized inner wall and the capture process were characterized using scanning electron microscopy. Compared to conventional packed tube or thin-layer cell immunoreactor, the proposed microreactor showed remarkable properties such as lower cost, simpler fabrication, better practicality and wider dynamic range for fast CL immunoassay with good reproducibility and stability. Using α-fetoprotein as model analyte, the highly efficient CL flow-through immunoassay system showed a linear range of 3 orders of magnitude from 0.5 to 200 ng mL⁻¹ and a low detection limit of 0.1 ng mL⁻¹. The capillary immune microreactor could make up the shortcoming of conventional CL immunoreactors and provided a promising alternative for highly efficient flow-injection immunoassay.     

Dynamics and pattern formations in diffusive predator‐prey models with two prey‐taxis

A reaction‐diffusion two‐predator‐one‐prey system with prey‐taxis describes the spatial interaction and random movement of predator and prey species, as well as the spatial movement of predators pursuing preys. The global existence and boundedness of solutions of the system in bounded domains of arbitrary spatial dimension and any small prey‐taxis sensitivity coefficient are investigated by the semigroup theory. The spatial pattern formation induced by the prey‐taxis is characterized by the Turing type linear instability of homogeneous state; it is shown that prey‐taxis can both compress and prompt the spatial patterns produced through diffusion‐induced instability in two‐predator‐one‐prey systems.     

关于带运输的单机调度在线问题的研究

本文研究了带运输机的单机在线调度问题。问题假设工件实时在线到达,系统中有一台运输机,该运输机每次最多运输$k$个工件,每个工件需要先在单机上完成加工,然后再被运输机运往目的地,问题的优化目标为最小化完工时间,即所有工件被加工完并且运往目的地的时间最短。针对该问题,作者研究了工件满足一致性条件的模型,并且基于贪心思想给出了竞争比为$\frac{\sqrt{5}+1}{2}$的在线算法,并且证明该算法是最优在线算法。     

一类具有两个抛物线解的中心对称三次系统存在极限环的条件

本文给出了具有两个抛线解的中心对称三次系统存在在极限环的条件，它可能也是充要条件。     

圆筒形半透明介质内非稳态复合导热与辐射的研究

本文研究细长电加热体在圆筒形半透明介质中的温度响应，通过对控制非稳态导热与辐射复合传热过程的积分-微分方程直接进行数值求解，分析了热辐射对内部径向热流及温度变化的影响．模拟计算结果对热线法测量半透明介质导热系数的研究具有理论指导意义。     

不同形状的光斑触发砷化镓光导开关

为研究使用不同形状光斑触发光导开关对光电导特性的影响,研制了12 mm间隙的半绝缘砷化镓光导开关,在不同的偏置电压下,使用波长为1 064 nm的不同能量的激光触发光导开关并进行了光电导测试。使用了不同形状的光斑(包括面状、线状和点状光斑)触发光导开关并进行了光电导特性的比较,讨论了触发光参数对光导开关特性的影响。对处于开关电极间不同位置的线状光斑触发特性进行了比较,结果显示,本征光电导和非本征光电导情况下光斑位置对光电流的影响正好相反。     

箍缩背光照相

 利用PPG-Ⅰ脉冲功率装置（500 kV,400 kA,100 ns）驱动X箍缩负载,得到了μm量级的亚纳秒脉冲X射线辐射点源。在阴阳极轴线和回流柱上同时安装X箍缩负载,前者可作为背光照相的X射线点源;后者可作为被拍照的目标X箍缩。获得了X箍缩发展过程不同时刻的时间序列图像,在背光照相的图像中可以清晰观察到X箍缩交叉点处等离子体的外爆、箍缩以及最终的崩溃阶段。将阴阳极轴线上的X箍缩负载用Z箍缩丝阵负载代替,实现了对丝阵负载Z箍缩放电起始阶段的X射线背光照相,观察到了最初的各单丝电爆炸、等离子体膨胀及融合过程,同时观察到了双丝Z箍缩发展过程中的等离子体不稳定性。实验结果有助于深入理解Z箍缩发展的物理过程,同时可为有效的模拟建模分析提供基本的实验数据。     

A consecutive one-pot two-step approach to novel trifluoromethyl-substituted bis(indolyl)methane derivatives promoted by Sc(OTf)3 and p-TSA

A one-pot two-step reaction of 3-(trifluoroacetyl)coumarin and indole afforded trifluoromethyl-substituted bis(indolyl)methane compounds containing coumarin skeleton. The atomic economic and simply manipulative reaction involved premier treatment of reaction mixtures with Sc(OTf)₃, followed by p-TSA in one-pot process. The reaction proceeded to give the title compounds in high yields (up to 95% yield).