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31.
利用傅里叶变温红外光谱仪分别测定了三羟甲基甲胺(TAM)、季戊四醇(PE)及其二元体系变温红外谱。实验表明,多元醇分子中羟基吸收峰随温度升高耐发生位移向高波数移动,此结果既能反映多元醇及其二体系固-固相变的温度区间,又与转变热相对应,从而揭示了多元醇及其二元体系固-固相变贮热的机理。 相似文献
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To improve aircraft crash safety, conditions critical to occupants survival during a crash must be known. In view of the importance of this problem, studies of post-crash dynamic behavior of victims are necessary in order to reduce severe injuries. In this study, crash dynamics program SOM-LA/TA, incorporating a dynamic model of the human body with a finite element model of the seat structure was used. Modifications were performed in the program for reconstruction of an occupant's head impact with the interior walls or bulkhead. A viscoelastic-type contact force model was used to represent the compliance characteristics of the bulkhead. Correlated studies of analytical simulations with impact sled test results were accomplished. A parametric study of the coefficients in the contact force model was then performed in order to obtain the correlations between the coefficients and the Head Injury Criteria. A measure of optimal values for the bulkhead compliance and displacement requirements was thus achieved in order to keep the possibility of a head injury as little as possible. This information could in turn be used in the selection of suitable materials for the bulkhead, instrument panel, or interior walls of an aircraft. 相似文献
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Fe-doped TiO2 powder was prepared by high-energy ball milling, using TiO2 Degussa P-25 and α-Fe powders as the starting materials. The structure and magnetic properties of the Fe-doped TiO2 powder were studied by X-ray diffraction, 57Fe Mossbauer spectroscopy and vibrating sample magnetometer. The Reitveld refinement of XRD revealed that ball milling not only triggered incorporation of Fe in TiO2 lattice but also induced the phase transformation from anatase to rutile in TiO2 and consequently the milled Fe-doped TiO2 powder contained only rutile.57Fe Mössbauer effect measure showed that Fe atoms existed in Fe2+ and Fe3+ state, which were assigned to the solid solution FexTi1−xO2. The magnetization measurements indicated that the milled Fe-doped TiO2 powder was ferromagnetic above room temperature. The ferromagnetism in our milled Fe-doped TiO2 powder seemingly does not come from Fe and iron oxides particles/clusters but from the Fe-doped TiO2 powder matrices. 相似文献
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WANG Jiang-yun GU Wen WANG Wen-zhen LIU Xin LIAO Dai-zheng 《高等学校化学研究》2006,22(3):283-286
Introduction Itiswell knownthatcyanogroupsincyanometa latessuchas[Ag(CN)2]-unitscanbeusedasbridg ingligandsandapolymericstructurecanbeformed throughsilver silver(argentophilic)interactions.This propertyhasbeenexploredintheconstructionofmany oligomericandp… 相似文献
39.
Jipu Ma 《中国科学A辑(英文版)》1997,40(12):1233-1238
A generalized dimension is further developed. Here subtraction and addition of two generalized dimensions are defined, so
that the operations: ∞ ± n = ∞, ∞ + ∞ = ∞, which used to play an inflexible role, are refined and moreover, ∞ - ∞, which used
to be meaningless, is done in sense. Then generalized index for semi-Fred-holm operators is developed to wholeB(H), i.e. all of bounded linear operators in Hilbert spaceH. Theorem 2.2 is proved with an example, which is in contradiction to a known proposition for semi-Fredholm operators in form,
practically a refined result of the known proposition. Then, it is proved thatB(H) is the union of countably many disjoint arewise connected sets over all the generalized dimensions ofB(H).
Project supported by the National Natural Science Foundation of China 相似文献
40.
巯基乙酸锑配合物的合成与X射线粉末衍射数据指标化 总被引:2,自引:0,他引:2
一些锑和铋的配合物可以应用于医药研究[1,2 ] ,已合成了许多锑的有机配体配合物[3~ 7] ,但其中大多数没有生物活性。因此 ,研究锑或铋离子的配合物不仅对主族元素化学、生物无机化学而且对医药都有着非常重要的意义。我们用三氯化锑与巯基乙酸液相反应法合成的二巯基乙酸锑 (Ⅲ)配合物 ,其组成为HSb(SCH2 COO) 2 ,用X射线粉末多晶衍射数据指标化来研究配合物晶体结构[8] 。1 实验部分1 1 仪器与试剂EA - 1 1 0 6型元素分析仪 (意大利卡拉欧巴公司制造 ) ,D Max -YB型多晶X射线粉末衍射仪(日本理学 ,CuKα射线 ,… 相似文献