全文获取类型
收费全文 | 10447篇 |
免费 | 1911篇 |
国内免费 | 1255篇 |
专业分类
化学 | 7679篇 |
晶体学 | 68篇 |
力学 | 656篇 |
综合类 | 80篇 |
数学 | 1068篇 |
物理学 | 4062篇 |
出版年
2024年 | 26篇 |
2023年 | 274篇 |
2022年 | 319篇 |
2021年 | 404篇 |
2020年 | 488篇 |
2019年 | 420篇 |
2018年 | 342篇 |
2017年 | 299篇 |
2016年 | 495篇 |
2015年 | 438篇 |
2014年 | 536篇 |
2013年 | 764篇 |
2012年 | 962篇 |
2011年 | 978篇 |
2010年 | 644篇 |
2009年 | 635篇 |
2008年 | 710篇 |
2007年 | 624篇 |
2006年 | 553篇 |
2005年 | 477篇 |
2004年 | 367篇 |
2003年 | 325篇 |
2002年 | 273篇 |
2001年 | 216篇 |
2000年 | 215篇 |
1999年 | 256篇 |
1998年 | 216篇 |
1997年 | 191篇 |
1996年 | 205篇 |
1995年 | 175篇 |
1994年 | 142篇 |
1993年 | 124篇 |
1992年 | 102篇 |
1991年 | 74篇 |
1990年 | 84篇 |
1989年 | 57篇 |
1988年 | 49篇 |
1987年 | 44篇 |
1986年 | 29篇 |
1985年 | 28篇 |
1984年 | 14篇 |
1983年 | 9篇 |
1982年 | 13篇 |
1981年 | 8篇 |
1980年 | 5篇 |
1979年 | 2篇 |
1957年 | 2篇 |
排序方式: 共有10000条查询结果,搜索用时 734 毫秒
11.
In this Letter,a novel system for adaptively correcting the phase of a dynamic multimode beam is proposed.While using merely one spatial light modulator,the phase measurement of the first-order diffraction pattern and the correction of the zeroth diffraction order are simultaneously realized.The real-time experimental result is obtained at a control rate of 10 Hz.The power-in-the-bucket value is improved from 38.5%to 61.8%,even with fundamental mode content that is consistently below 30%.To the best of our knowledge,this is the first implementation of real-time adaptive correction of the entire multimode beam. 相似文献
12.
Zhang Kailun Wu Hongjuan Wang Tian Yao Meng Xie Jixing Jiao Yunhong 《Journal of Thermal Analysis and Calorimetry》2021,145(6):3067-3075
Journal of Thermal Analysis and Calorimetry - A phosphazene-based flame retardant (PBFA) was synthesized by hexachlorocyclotriphosphazene and N-aminoethylpiperazine. To improve the flame retardancy... 相似文献
13.
Dongping Wang Jie Dong Wenjing Fan Prof. Dr. Xiang-Ai Yuan Prof. Dr. Jian Han Prof. Dr. Jin Xie 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(22):8508-8512
An unprecedented Mn(I)-catalyzed selective hydroarylation and hydroalkenylation of unsaturated amides with commercially available organic boronic acids is reported. Alkenyl boronic acids have been successfully employed for the first time in Mn(I)-catalyzed carbon–carbon bond formation. A wide array of β-alkenylated amide products can be obtained in moderate to good yields, which offers practical access to five- and six-membered lactams. This protocol has predictable regio- and chemoselectivity, excellent functional group compatibility and ease of operation in air, representing a significant step-forward towards manganese-catalyzed C−C coupling. 相似文献
14.
15.
Jin Xie Yun-Wei Song Dr. Bo-Quan Li Dr. Hong-Jie Peng Prof. Jia-Qi Huang Prof. Qiang Zhang 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(49):22334-22339
Polysulfide intermediates (PSs), the liquid-phase species of active materials in lithium–sulfur (Li-S) batteries, connect the electrochemical reactions between insulative solid sulfur and lithium sulfide and are key to full exertion of the high-energy-density Li-S system. Herein, the concept of sulfur container additives is proposed for the direct modification on the PSs species. By reversible storage and release of the sulfur species, the container molecule converts small PSs into large organosulfur species. The prototype di(tri)sulfide-polyethylene glycol sulfur container is highly efficient in the reversible PS transformation to multiply affect electrochemical behaviors of sulfur cathodes in terms of liquid-species clustering, reaction kinetics, and solid deposition. The stability and capacity of Li-S cells was thereby enhanced. The sulfur container is a strategy to directly modify PSs, enlightening the precise regulation on Li-S batteries and multi-phase electrochemical systems. 相似文献
16.
采用密度泛函方法(B3P86)对 Fe_2分子结构进行了优化.计算结果中未观察到自旋污染,基态波函数与高态波函数并未混杂,结果表明,Fe_2中有8个未配对电子,这些电子空间分布不同和自旋平行产生的自旋极化效应,使 Fe_2能量最低.计算结果表明,Fe_2分子的基态是~9∑_g~ ,并非~7Δ_u,进而表明 Fe_2的自旋平行效应比电子自旋配对效应要强.计算得到该分子基态的二阶、三阶和四阶力常数分别为1.4115×10~(-2)aJ/nm~2、-37.1751×10~3aJ/nm~3和 98.7596×10~4aJ/nm~4;光谱数据ω_eχ_e、B_e、α_e分别为0.3522、0.0345、 0.4963×10~(-4)cm~(-1);离解能为3.5522eV,平衡键长为0.2137nm,振动频率为292.914cm~(-1);并得到了 Murrel-Sorbie 函数. 相似文献
17.
18.
本文讨论中立型大系统,获得了这类问题稳定性的一些充分判据,作为特殊情况,还得到了与[1-11]中相应的一些不同的结果.这些结果并不象文献[1]和[2]那样,要求a_(ii)的上界q_(ii)小于零. 相似文献
19.
20.
This paper reports that the m-plane GaN layer is grown on (200)-plane LiAlO2 substrate by metal-organic chemical wpour deposition (MOCVD) method. Tetragonal-shaped crystallites appear at the smooth surface. Raman measurement illuminates the compressive stress in the layer which is released with increasing the layer's thickness. The high transmittance (80%), sharp band edge and excitonic absorption peak show that the GaN layer has good optical quality. The donor acceptor pair emission peak located at -3.41 eV with full-width at half maximum of 120 meV and no yellow peaks in the photoluminescence spectra partially show that no Li incorporated into GaN layer from the LiAlO2 substrate. 相似文献