Molisch反应:发现、原理及应用

Molisch反应发现于1886年,此后对糖和苷类化合物的研究提供了强大的定性鉴别工具.本文回顾了Molisch反应的发现过程、反应机理研究及应用,并对该反应在未来的应用进行了展望.     

关于波导管的格林张量函数

本文以本征函数展开的方法,研究了波导管中格林函数的一般性质和形式。为了得到波导管的本征函数(简正波)和格林张量函数的一些关系,我们首先对格林函数作富氏变换,它的象函数在各向同性介质波导中以并矢形式作为最简单的表达方法,而在充有各向异性介质波导中可以表为ABA⁺e^-ikz₀的形式,这里A是坐标矩阵。用这种方法详细推导了均匀各向同性介质波导中的并矢格林函数。 关键词：     

青藏铁路多年冻土区工程复杂性分析

青藏铁路穿越550km多年冻土区,多年冻土地温、冻土类型以及沿线生态环境等存在较大的差异,使多年冻土区工程较为复杂。因此本文提出了冻土工程复杂性概念,建立冻土工程复杂性评价模型,并利用GIS平台对青藏铁路沿线唐古拉山越岭地段工程复杂性进行了分析和研究。研究结果表明,青藏铁路穿越的唐古拉山越岭地段工程复杂性相对较小,而青藏公路的工程复杂性相对较大。这表明了青藏公路沿线冻土工程比青藏铁路沿线更为复杂,在各种因素的影响下,青藏公路路基稳定性变化比青藏铁路更加复杂。     

线性分式规划问题的多项式时间近似算法

本文针对线性比式和分式规划问题,提出一种求其全局最优解的完全多项式时间近似算法,并从理论上证明该算法的收敛性和计算复杂性,数值算例也说明了算法是可行的.     

螺丝钉连结的组合樑

In this paper, it is proved that the problem of composite beams jointed by bolts can be solved in terms of certain equivalent continuous beams. The equivalent beam is specified as follows: 1) It consists of supports of the original beam and equivalent supports situated at the points where bolts are used. 2) It is loaded by the given load on the original beam.Then the reactions at the bolts in the original composite beam are equal to a constant C times the reactions at various supports of the equivalent continuous beam. The constant is equal to C=(E′J′-k(EJ+E′J′))/(EJ+E′J′), where EJ and E′J′ are flexaral rigidities of the first and second parts of the composite beam respectively, and k is the distributing ratio of load on the second part.The solution of the problem is then greatly simplified.This method can be generalized for composite beams consisting of more than two parts, on which the given load is not proportionately distributed.     

Nanogel Multienzyme Mimics Synthesized by Biocatalytic ATRP and Metal Coordination for Bioresponsive Fluorescence Imaging

The design of enzyme mimics from stable and nonprotein systems is especially attractive for applications in highly specific cancer diagnosis and treatment, and it has become an emerging field in recent years. Herein, metal crosslinked polymeric nanogels (MPGs) were prepared using Fe^II ion coordinated biocompatible acryloyl‐lysine polymer brushes obtained from an enzyme‐catalyzed atomic transfer radical polymerization (ATRPase) method. The monoatomic and highly dispersed Fe ions in the MPGs serve as efficient crosslinkers of the gel network, and also as active centers of multienzyme mimics of superoxide dismutase (SOD) and peroxidase (POD). The catalytic activities were compared to those of conventional Fe‐based nanozymes. Studies on both cells and animals verify that efficient reactive oxygen species (ROS) responsive biofluorescence imaging can be successfully realized using the MPGs.     

电荷转移盐(C_3H_5N_2H)_3[PMo_(12)O_(40)]的合成与热分解及光致变色反应动力学

用磷钼酸与咪唑合成了一种新的杂多酸-有机电荷转移盐(C3H5N2H)3[PMo12O40]。通过元素分析、红外光谱、固体漫反射光谱、电子自旋共振及热分析等测试技术对其进行了表征,用单扫描法(Achar法和Coats-Redfern法)对合成化合物的TG分析结果进行了非等温热分解动力学研究。推断结果表明,合成化合物的第1步热分解为球对称的三维扩散机理(n=2),其动力学方程为dα/dt=1.58×108[1-(1-α)1/3]-1(1-α)2/3exp(-40931.0/T),求得分解反应的表观活化能E=340.30kJ/mol,指前因子A=1.05×108s-1。标题化合物对紫外光具有光致变色性质,用固体漫反射光谱研究了其光致变色反应动力学。结果显示,其光致变色反应表现为一级或准一级动力学,速率常数k=9.80×10-5s-1。