前言

放射化学是研究放射性物质及其辐射效应的一门化学分支学科。现代放射化学主要包括核能放射化学、环境放射化学、放射性药物化学、放射分析化学、放射性元素化学及核化学等。 放射化学是19世纪末随着放射性和放射性核素的发现而诞生的一门学科。正由于核化学和放射化学的贡献, 发现了核裂变现象,从而开创了核科学时代的到来。近年来,核化学和放射化学的发展已经为国家安全、 社会和经济进步、 能源需求、人类健康、环境保护以及科学发展等做出了巨大贡献。例如在基础科学方面,与核物理学家合作将元素周期表扩展了近1/3,提出了锕系理论等。全世界现有能源的1/6来自核能, 全球具有一定规模的医院都设有核医。放射化学的特点表明,它不仅是一种重要的和不可取代的核方法,而且是一门极具生命力的前沿科学。放射化学的三大推动力是：国家需求, 基础研究, 学科交叉。它不仅蕴含着大量既有重要科学意义、又能满足国家重大需求的科学问题,而且与其他学科交叉,产生了许多新的学科生长点。     

比例边界有限元二阶灵敏度设计及断裂力学分析

比例边界有限元是一种只需在边界上划分网格且无需基本解的半解析方法,能有效处理应力奇异性和无边界问题.论文提出了一种比例边界有限元的二阶灵敏度分析方法,可以准确而高效地求解响应关于参数的二阶梯度.首先通过建立仅需右特征向量的哈密顿矩阵特征灵敏度分析方程,发展了一种改进的比例边界有限元一阶灵敏度分析方法;其次,进一步通过构建二阶哈密顿矩阵特征灵敏度分析方程,并对比例边界有限元系统方程进行一系列二次直接微分,提出了一种半解析形式的比例边界有限元二阶灵敏度分析方法.该方法被应用于线弹性裂纹结构的形状灵敏度分析和不确定性传播分析.最后,给出了两个数值算例验证论文方法的有效性.     

Some Characterizations of Left Weakly Regular Ordered Semigroups

In this paper, the notion of left weakly regular ordered semigroups is introduced. Furthermore, left weakly regular ordered semigroups are characterized by the properties of their left ideals, right ideals and (generalized) bi-ideals, and also by the properties of their fuzzy left ideals, fuzzy right ideals and fuzzy (generalized) bi-ideals.     

Characterization of a-plane orientation ZnO film grown on GaN/Sapphire template by pulsed laser deposition

In this study, the authors have investigated the structural and optical properties of ZnO layer grown by pulsed laser deposition on GaN/r-plane sapphire. X-ray diffraction results demonstrate the ZnO film to be highly preferentially deposited at a-axis orientation; the different rocking curve values along the two orthogonal directions indicate the low C_2v symmetry in the growth a-plane ZnO. From free stress to large tensile stress (about 1.34 × 10⁹ Pa) distribution along the growth direction of ZnO is revealed by visible Raman mapping spectra. The enhanced significantly high-order longitudinal-optical (LO) phonon modes up to 4th and no TO phonons have been observed in Raman spectrum under UV 325 nm by resonance conditions; an intense and broad disorder activated surface phonon mode is also observed, resulting from the increased disorder on the film surface with stripe-like growth features. Low-temperature photoluminescence measurements reveal that the band-edge emission of ZnO is dominated by neutral donor-bound exciton and free electrons to neutral acceptor emissions. Interfacial microstructure of ZnO/GaN has been examined by transmission electron microscopy, with the epitaxial relationship () ZnO//() GaN. All these results indicated that GaN template played an important role in the growth of ZnO film, with full advantage of small lattice mismatch.     

Dynamical behavior of a delay virus dynamics model with CTL immune response

In this paper, the dynamical behavior of a virus dynamics model with CTL immune response and time delay is studied. Time delay is used to describe the time between the infected cell and the emission of viral particles on a cellular level. The effect of time delay on stability of the equilibria of the CTL immune response model has been studied and sufficient criteria for local asymptotic stability of the disease-free equilibrium, immune-free equilibrium and endemic equilibrium and global asymptotic stability of the disease-free equilibrium are given. Some conditions for Hopf bifurcation around immune-free equilibrium and endemic equilibrium to occur are also obtained by using the time delay as a bifurcation parameter. Numerical simulation with some hypothetical sets of data has been done to support the analytical findings.     

Density perturbation of unparticle dark matter in the flat Universe

The unparticle has been suggested as a candidate of dark matter. We investigated the growth rate of the density perturbation for unparticle dark matter in the flat Universe. First, we consider the model in which the unparticle is the sole dark matter and find that the growth factor can be approximated well by f=(1+3ω _u )Ω _u ^γ , where ω _u is the equation of state of unparticle. Our results show that the presence of ω _u modifies the behavior of the growth factor f. For the second model where the unparticle co-exists with cold dark matter, the growth factor has a new approximation f=(1+3ω _u )Ω _u ^γ +α Ω _m and α is a function of ω _u . Thus the growth factor of the unparticle is quite different from that of the usual dark matter. This information can help us know more about unparticle and the early evolution of the Universe.     

Well vertically aligned ZnO nanowire arrays with an ultra-fast recovery time for UV photodetector

Well-crystallized ZnO nanowire arrays were grown on GaN/sapphire by one-step chemical vapor deposition under control of the fabrication pressure of 1000–2500 Pa and the best-aligned arrays were obtained at 1000 Pa. A photoluminescence study shows a red shift with nanowire diameter increase. Under 365-nm UV irradiation of 0.3 mW/cm², the photoresponse study of the best ZnO arrays shows an ultra-fast tri-exponential rise with three constants of 0.148, 0.064 and 0.613 s, and a bi-exponential decay behavior with two recovery constants of 30 and 270 ms. The ZnO/GaN heterojunction barriers could be responsible for the ultra-fast tri-exponential rise and bi-exponential decay behavior.     

Extraction,identification and antimicrobial activity of a new furanone,grifolaone A,from Grifola frondosa

A furanone (1), (S)-methyl 2-(2-hydroxy-3,4-dimethyl-5-oxo-2,5-dihydrofuran-2-yl)acetate, was isolated from the edible mushroom Grifola frondosa. Mass spectrometry and NMR analyses were used to elucidate the structure of this compound, and its absolute configuration was determined using circular dichroism spectroscopy. Compound 1 exhibited specific antifungal activity against the plant pathogens, Fusarium oxysporum, Gibberella zeae and Piricularia oryzae and the opportunistic human pathogen, Pseudallescheria boydii, resulting in minimum inhibitory concentration values of 2.5, 2.5, 1.25 and 0.15 μg/mL, respectively. In contrast, the furanone showed only weak activity towards Aspergillus spp., Candida albicans and several other fungal strains tested as well as no appreciable antibacterial activity.     

Pd/SiC催化碘代芳烃和芳基硼酸羰化Suzuki偶联反应性能

以高比表面积碳化硅为载体,通过液相还原法制备出Pd/SiC催化剂,并用于催化碘代芳烃和芳基硼酸羰化Suzuki偶联反应.利用X射线衍射、电感耦合等离子体质谱和高分辨透射电子显微镜等对催化剂进行了表征.结果表明, SiC表面的Pd纳米颗粒分散均匀,平均粒径约为2.8 nm.在优化溶剂、碱、压力和温度等反应条件后,发现以3 mmol的K2CO3和10 mL苯甲醚分别为碱和溶剂,1.0 mmol碘苯和1.5 mmol苯硼酸在3 wt% Pd/SiC催化剂存在的条件下,在CO压力为1.0 MPa和100oC下反应8 h即可实现羰化偶联,碘苯转化率为90%,二苯甲酮选择性为99%.并且, Pd/SiC对含有不同官能团的碘代芳烃和芳基硼酸羰化Suzuki偶联反应具有较好的普适性.同时, Pd/SiC也具有较好的稳定性,经5次循环反应后,碘苯转化率从90%降至76%;催化剂活性降低的主要原因是活性组分Pd在有机反应体系中的流失.