液体理论极限过热度的确定

本文利用统计热力学涨落理论提出一个新的假说，并由此建立了确定液体极限过热度的新方法。用导出的公式对18种液体物质极限过热度的计算结果表明，与其他作者提供的实验数据比较，其平均偏差小于0．67％，最大偏差不超过2.65％。本文给出的表达式具有普适性，可以对任何液体物质进行极限过热度预测。因此，这种新的方法在理论和应用上的价值都是显见的。     

碘冉酸阴离子桥联双核铜（Ⅱ）配合物的合成与磁性

碘冉酸阴离子桥联双核铜（Ⅱ）配合物的合成与磁性孟祥军寇会忠邹国彰廖代正姜宗慧＊王耕霖（南开大学化学系天津３０００７１）关键词碘冉酸，Ｃｕ（Ⅱ），双核配合物，合成，磁性１９９６－０８－２０收稿，１９９６－１１－１８修回国家自然科学基金资助项目随着生物无...     

Regular Semigroups with Quasi-Ideal Orthodox Transversals

We give some simple algebraic conditions on the coefficients of a boundary value problem for a differential equations of Ventcel type, depending on a spectral parameter, which guarantee the existence, uniqueness of a solution and coerciveness estimate, for a spectral parameter lying in some sector.     

新结构电致发光薄膜器件的发光区域

在发光层中插入无发光中心的ZnS薄膜,研究了新结构器件发光层中发光中心周围的广的分布与发光中心在薄膜中位置的关系,确定在SiO2/ZnS:Tb界面附近区域的发光中心周围有较多的F,远离该界面区域的发光中心周围的F-离子较少,前一区域的发光中心的发光亮度较低,后一区域的发光中心的发光亮度较高,并拟合出前一区域的厚度为18nm.     

真空升华条件对C_（60）／C_（70）薄膜成份的影响

通过热重分析测定ＴＣ６０／Ｃ７０混合物的明显升华起始温度约为６００℃．在高真空（１０（－３）Ｐａ）中加热Ｃ６０／Ｃ７０混合物使其升华，在ＫＢｒ晶体上形成薄膜，对不同升华条件下所得薄膜的傅里叶变换红外光谱（ＦＴＩＲ）进行比较，得出了薄膜成分变化规律．发现６００℃加热混合物足够长时间，能去除混合物中低碳素富勒烯杂质，再恒温７００℃升华混合物，薄膜主要由Ｃ６０组成．     

夸克的半经典输运方程

对夸克的量子输运方程取半径典近似时保留到Wigner函数的一次微商项;在色空间和自旋空间展开这个半经典输运方程,得到了色单态自旋标量和色单态自旋矢量的输运方程:并把得到的结果和阿贝尔等离子体进行比较讨论了QGP的非阿见尔性质.     

QGP中胶子的经典输运方程

建立了夸克胶子等离子体中胶子的经典输运方程, 并讨论了它与胶子的量子输运方程以及它与夸克的经典输运方程之间的关系.     

Uniform-sized molecularly imprinted polymer for metsulfuron-methyl by one-step swelling and polymerization method

Uniform-sized molecularly imprinted polymer (MIP) beads for metsulfuron-methyl (MSM) were firstly prepared by one-step swelling and polymerization method using 4-vinylpyridine (4-VPY) and ethylene glycol dimethacrylate (EDMA) as functional monomer and cross-linker, respectively. The preparation was optimized by varying the ratio of MSM to 4-VPY. The chromatographic behaviors of MSM and other structurally related sulfonylureas (SUs) on the resultant MIP column were evaluated. The imprinted polymer revealed specific affinity to the template and the fair resolution of SUs was also obtained. Furthermore, the uniform-sized MSM-MIP was used as the solid phase extraction (SPE) material to enrich MSM in real water samples before reversed-phase HPLC (RP-HPLC) analysis. The recovery of MSM from 100 mL of drinking water at a 50 ng/L spike level was 99.59% with R.S.D. of 1.13%. The detection limit was about 6.0 ng/L of MSM when enriching a 100 mL water sample.     

溶胶-凝胶法制备纳米二氧化钛颗粒的研究

本文采用钛酸丁脂等原料,利用sol-gel方法制备了TiO2纳米颗粒.研究了不同实验顺序(滴入方式)和工艺参数对制备效果的影响.通过实验和对TiO2纳米粉末的TEM分析,获得了粒度(30-40nm)比较均匀的球型TiO2纳米颗粒.     

Orthogonal array design experiments for optimizing the separation of nine pesticides by micellar electrokinetic chromatography

Separation in micellar electrokinetic chromatography is influenced by many factors. The separation of 9 pesticides was optimized using orthogonal array designs (OADs), five relevant factors were investigated: type and concentration of surfactant, concentration of buffer, pH and concentration of urea modifier. In the first experiment, five factors were examined at two levels using an OA₁₆(2¹⁵) matrix, by which the effect of each factor was estimated using individual contributions as response function, based on the results of the first experiment, three more important factors were chosen for further optimization using OA₉(3⁴) matrix to locate the exact levels for each variable. Finally, 9 pesticides achieved baseline-separation within 15 min.