Study of the structure and the mechanical properties of dynamically cured PP/MAH-g-SEBS/epoxy blends

A new method concerning with the simultaneous reinforcing and toughening of polypropylene(PP) was reported.Dynamical cure of the epoxy resin was successfully applied in the PP/maleic anhydride-grafted styrene-ethylene-butylene-styrene(SEBS) triblock copolymer,and the obtained blends named as dynamically cured PP/MAH-g-SEBS/epoxy blends.The stiffness and toughness of the blends are in a good balance,and MAH-g-SEBS was acted as not only an impact modifier but also a compatibilizer. The structure of the dyn...     

二元组装体集群时的高选择性杂化重组行为

多样性自组装体在混合时,通常表现出互不干扰的自分类性,能高度选择性地自分类堆积.但结构极为相似的组装子在相互混合时,会发生交互作用并表现出重组现象.文中合成和观测了具有芳香环边墙和不同酰胺侧链的C型甘脲分子夹为组装单元的混合组装行为.研究发现,此类分子在各自以单一态物质溶解于CDCl3时,能通过π-π相互作用和氢键形成二聚自组装体;若将两种具有不同酰胺侧链的C型甘脲分子夹两两混合,从理论上推测应有三种二聚自组装堆积态存在：A·A、B·B、A·B.但经1HNMR分析发现了一个有趣的现象,即当酰胺侧链上的取代基R′分别为具有C-H结构（如1和2）与PhF5基（5）的组装体两两混合时,二聚组装主要呈现出高度选择性杂化重组的A·B结构态.这种取代基控制的高选择性重组行为可能是基于π-π相互作用、N—H…O氢键,以及C—H…π等三重作用力的协同结果.     

紫外吸收温差光谱特性与化合物的电子跃迁类型

用紫外吸收变温光谱差减法获得化合物的紫外吸收温差光谱（UVSDT）。测量了系列化合物的温差光谱。结果表明,UVSDT具有很强的特征性：n→σ^*电子跃迁的UVSDT单边红移,温差增大峰强度增加、红移增大;n-π^*电子跃迁的UVSDT为正、负两峰、温差增大,正负两峰各自向正、负方向增强;π-π^*电子跃迁的UVSDT为负峰,温差增大,峰强负向增大,峰位不移动。     

高分辨光谱的计算机自动读谱及辅助分析

本文以谱线中心位置在整个谱型中所独有的特性和噪声阈值为依据,提出了一种计算机自动获取谱线中心频率及其相对强度的简便算法,并设计了相应的计算机程序。将该方法和程序应用到具有代表性的由十多条CHF3谱线部分重迭组成的可调远红外实验谱图的预分析,结果表明所获取的谱线中心频率和相对强度与人工获取这些参数初值后经拟合得到的准确结果非常一致,验证了该方法和程序的准确性和有效性,表明其有着广泛的应用前景,可作为处理日益骤增的光谱信息的强有力工具。     

变迹啁啾Bragg光纤光栅的矩阵分析

本文用传输矩阵法分析了各种变迹与线性啁啾Bragg光纤光栅的响应特性,构造了各种变迹函数,进行了比较.分析了变迹函数、啁啾系数、折射率变化量以及光栅长度对反射带宽、最大反射率的影响.找到了最佳变迹函数和量佳啁啾系数.特例中的数值分析表明,补偿100km光纤色散带宽为1nm的最佳光栅长度是140mm,最佳啁啾系数为0.048nm/cm.     

DIFFERENTIAL INEQUALITIES OF OPERATOR-VALUED ANALYTIC FUNCTIONS

1 IntroductionLet H dellote a colllplex Hilbert space. Let B(H) be a co1llplex Banach space of all boundedliuear operators on H, alld B(H)*, tl1e co11jugate space of B(H). The real and inlaginary partsrof all operator T on H are denoted by ReT and IlllT, respectively, i.e., ReT = op, I111T =ng. A contraction is a11 operator T E B(H) with 11TI1 5 1, a proper contractioll is al1operator T 6 B(H) witl1 lITlI < 1.We say that f is all operator-val[1ed fullction on the u1lit disc A = {…     

THE EXISTENCE OF SOLUTIONS OF QUASILINEAR ELLIPTIC EQUATIONS WITH CHANGE OF SIGN

1 IntroductionIll tllis paper, we co1lsid(tr the fOllowillg elliptic prol)leInwllere n is a bOui1ded regular domai1l in RN(N > 3), N > p > 1, aild a: n - R is a Holdercontinuou8 function which chauges 8ign o11 fl so that the open setsandO-- = {z E Ola(z) < 0}are both nonemPty.We use the standard notations. Let II' lI, denote the norm of L'(o) for s21. DenoteW0lP(fl) the comPletion of C7(fl) under the norm IIuIl = llVuIl;, the norm of tlle dual spaceof WJlp(fl) will be denoted by Il…     

THE ASYMPTOTIC BEHAVIOR OF SOLUTION FOR THE NONLINEAR HEAT-CONDUCTION EQUATION AND ITS APPLICATION

1 IntroductionIn the heat-conduction equationp is the density,c is the specific heat,k is the thermal conductivityLet u = w -- wco be therelative temperature, where woo is the environmental temperature. In many cases, the thermalconductivity k is dependent of the temperature,forrexample, the heat-conduction of electron iuthe plasma body and the radiation heat-conduction in the high temperature,k(u) = uoum--' (m > 1).Assume that p, c are constants, then the equation (1.1) can be written asWe c…     

Design, synthesis and bioactivity of novel herbicides targeted ALS (Ⅶ): Quantitative structure-activity relationships of herbicidal sulfonylureas

The quantitative relationship between the structures of 20 sulfonylureas and their herbicidal activities against rape was analyzed using physicochemical parameters and regression analysis. The results showed that the electronic properties of the molecules are the dominant factor to the activity and there is apparently an optimum electronic property (∑σ or pKa) for the molecules to fit the receptor. Combined with the previous QSAR results for herbicidal triazolopyrimidine-2-sulfonamides, we can conclude that the structure-activity relationships of these two sets of compounds are identical, which suggested that these two sets of compounds acted on the same target site.     

高温超导空芯脉冲变压器的可行性研究

为了研究高温超导空心脉冲变压器的可行性,文中建立了一个由五个超导双饼组成的空芯脉冲变压器模型.采用有限元方法对变压器模型的电感矩阵进行计算,并在此基础上分析了两种不同的绕组联接方式.我们制作了一个由五个高温超导双饼组成的实验用空心脉冲变压器.由于环流的影响,实验结果部分与期望值相符,对高温超导空心脉冲变压器的设计具有一定参考意义.