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21.
Polyphysa peniculus was grown in artificial seawater in the presence of arsenate, arsenite, monomethylarsonate and dimethylarsinic acid. The separation and identification of some of the arsenic species produced in the cells as well as in the growth medium were achieved by using hydride generation–gas chromatography–atomic absorption spectrometry methodology. Arsenite and dimethylarsinate were detected following incubation with arsenate. When the alga was treated with arsenite, dimethylarsinate was the major metabolite in the cells and in the growth medium; trace amounts of monomethylarsonate were also detected in the cells. With monomethylarsonate as a substrate, the metabolite is dimethylarsinate. Polyphysa peniculus did not metabolize dimethylarsinic acid when it was used as a substrate. Significant amounts of more complex arsenic species, such as arsenosungars, were not observed in the cells or medium on the evidence of flow injection–microwave digestion–hydride generation–atomic absorption spectrometry methodology. Transfer of the exposed cells to fresh medium caused release of most cell–associated arsenicals to the surrounding environment. 相似文献
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Stochastic resonance is a statistical phenomenon that has been observed in periodically modulated, noise-driven, bistable systems. The characteristic signatures of the effect include an increase in the signal-to-noise of the output as noise is added to the system, and exponentially decreasing peaks in the probability density as a function of residence times in one state. Presented are the results of a numerical simulation where these same signatures were observed by adding achaotic driving term instead of a white noise term. Although the probability distributions of the noise and chaos inputs were significantly different, the stochastic and chaotic resonances were equal within the experimental error. 相似文献
27.
William M. Carroll 《School science and mathematics》1998,98(4):188-197
National and international studies have found U.S. elementary students to be weak in their understandings and applications of geometric concepts. The University of Chicago School Mathematics Project's (UCMSP) Everyday Mathematics Program is one of the current reform-based elementary curricula incorporating geometry throughout the K-6 curriculum, with an emphasis on hands-on and problem-solving activities. In this study, the geometric knowledge of fifth and sixth graders using the UCSMP curriculum is compared to the knowledge of students using more traditional curricula. Because UCSMP students had been in the program since kindergarten, this research attempts to measure the longitudinal effects of such an approach. Along with an overall score, a subset of test items was used to assign each student a van Hiele level for geometric thinking, as well as a reasoning score. On all measures, UCSMP students substantially outperformed their counterparts, and nearly all differences were significant. Aspects of the UCSMP curriculum and the van Hiele model for learning geometry are discussed relative to these results. 相似文献
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We show that a theorem of Shchepin and Repovš concerning the smoothness of compacta follows from the theory of semicontinuous relations. 相似文献
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Pawan K. Agarwal Richard T. Garner William W. Graessley 《Journal of Polymer Science.Polymer Physics》1987,25(10):2095-2111
We present an analysis of data on the intrinsic viscosity [η] of sulfo-polystyrene ionomers in several solvents for a variety of sulfonation levels and counterions. For solvents of low dielectric constant, 2 < ε < 18, [η] decreases from the base polymer value [η]0 with increasing substitution level. This behavior was attributed to intramolecular association of ionic dipoles. The ratio [η]/[η]0 was found to depend on a single reduced variable αAαSx, where x is the fractional substitution, αA depends only on the counterion, and αS ∝ ε?1 depends only on the solvent. For solvents of high dielectric constant, 36 < ε < 47, [η] increases approximately as x3, and counterion effects are small. This behavior was attributed to ionic dissociation, giving rise to a polyelectrolyte effect. Implications of the low ε results are discussed in relation to association-induced gelation behavior and possible generalizations of the reduced variables approach. 相似文献