EDGE PERMEABILITY AND POPULATION PERSISTENCE IN ISOLATED HABITAT PATCHES

ABSTRACT. Population persistence in isolated habitat fragments is investigated using integrodifference equations. The propensity of individual dispersers encountering the boundary of the patch to emigrate is defined by edge permeability. A dispersal model incorporating movement, settlement and edge permeability defines dispersal success as a function of a disperser's starting location. This dispersal model is used to generate dispersal kernels for integrodifference equation models, analysis of which gives a condition for population persistence in terms of edge permeability, patch size and average dispersal distance. An approximation reduces the spatial problem to a simple nonspatial model that can be easily analyzed.     

AN IMPLICIT SURFACE TENSION ALGORITHM FOR PICARD SOLVERS OF SURFACE–TENSION–DOMINATED FREE AND MOVING BOUNDARY PROBLEMS

One of the methods for solving a free or moving boundary problem is the use of Picard solvers which solve the geometry and the velocity field successively. When, however, the kinematic condition is used for updating the geometry in this technique, numerical stability problems occur for surface-tension-dominated flow. These problems are shown here to originate from the unstable integration of the local smoothing of the surface by surface tension. By an extension of the surface tension contribution to the flow field an implicit treatment of surface tension is obtained which overcomes these stability problems. The algorithm is applicable to both free and moving boundary problems, as will be shown by examples in this paper.     

Behavior in Repeated Prisoner's Dilemma Games with Shifted Outcomes Analyzed with a Statistical Learning Model

A fuzzy set theoretical framework is proposed for the analysis of sociometric structure characterized by vagueness of liking between individuals and a person's relative degree of belonging to a social group. Max‐min transitivity of a fuzzy relation is employed as a basic concept to examine the degree of liking and clustering in group structures. A distance model based on min‐max transitivity is also formulated as a special case of transitivity analysis. Other notions of transitivity such as the max‐product and the max‐* are also discussed. An empirical analysis is performed to examine the applicability of the proposed transitivity concepts. It appears that the current methodological construct provides a more appropriate perspective in the analysis of the group structure properties.     

Sequential Power-Dependence Theory

Existing methods for predicting resource divisions in laboratory exchange networks do not take into account the sequential nature of the experimental setting. We extend network exchange theory by considering sequential exchange. We prove that Sequential Power-Dependence Theory—unlike Power-Dependence Theory and most other exchange theories—has a unique point prediction for resource divisions in every network, and we show that these point predictions fare well in comparison to those from established theories.     

Antenna coupling study for ICWC plasma characterization in TEXTOR

Ion cyclotron wall conditioning (ICWC) discharges, in pulsed-mode operation, were carried out in the limiter tokamak TEXTOR to explore safe operational regimes for the experimental parameters for possible ICWC-discharge cleaning in International Thermonuclear Experimental Reactor (ITER) at half field. Antenna coupling properties obtained during the ion cyclotron range of frequencies (ICRF) wall conditioning experiments performed in helium–hydrogen mixture in TEXTOR were analysed in relation to the obtained ICWC-plasma characterization results. Satisfactory antenna coupling in the mode conversion scenario along with reproducible generation of ICRF plasmas for wall conditioning, were achieved by coupling radio frequency (RF) power from one or two ICRF antennas. The plasma breakdown results obtained in the TEXTOR tokamak have been compared with the predictions of a zero-dimensional RF plasma production model. The present study of ICWC emphasizes the beneficial effect of application of an additional (along with toroidal magnetic field) stationary vertical (B _V???B _T) or oscillating poloidal magnetic field (B _P???B _T) on antenna coupling and relevant plasma parameters.     

Rotational spectra of the Kr-H2O van der Waals complex

Rotational spectra of the Kr-H₂O van der Waals complex were measured in the frequency range 4–19 GHz using a pulsed jet cavity Fourier transform microwave spectrometer. The isotopomers studied include those of H₂O, HDO, D₂O, H₂ ¹⁷O and H₂ ¹⁸O with the six most abundant isotopes of Kr. A tunnelling splitting due to a large amplitude internal motion of the H₂O subunit that exchanges bonded and non-bonded hydrogen atoms was observed. Nuclear quadrupole hyperfine structure was resolved and measured for the complexes containing ⁸³Kr, D, and ^l7O, and the corresponding nuclear quadrupole coupling constants were determined. These were used to estimate structural parameters and to derive information about the intermolecular dynamics. The results, and in some instances the spectroscopic constants themselves, were compared with experimental and theoretical data previously reported for Ar-H₂O.     

The direct CI method. A detailed analysis

A thorough analysis of the direct CI method as applied to the case of a general set of reference configurations coupled to all single and double substitutions is presented. It is pointed out that there is no single strategy which proves optimal under all circumstances. A variety of procedures are therefore presented together with rules to enable the selection of the most favourable under a given circumstance. Much emphasis has been placed on organizing the calculations via a series of matrix multiplications, which enables a vector or array processing computer to be used to best effect. Some consideration is given to using an atomic integral (rather than molecular integral) driven scheme for some interactions, thus removing the necessity for a complete transformation of the molecular integrals to a molecular orbital basis, and the advantages and disadvantages of so doing are discussed. Improved procedures for carrying out both full and partial transformations of the molecular integrals are described. A number of test case calculations involving configuration lists of the order of 10⁴ to 10⁵ have been analysed in detail, to give a clear picture of the cost of the various interaction types which arise, and indicating that integrals carrying two external molecular orbital indices account for approximately 60 per cent of the cost in typical cases. Typically, a calculation involving 10⁵ configurations requires approximately two minutes of CRAY-1 computer time, allowing for ten iterations of the diagonalization procedure. The cost of the calculations are found, somewhat surprisingly, to be approximately linear in the dimension of the configuration space, indicating that calculations involving 10⁶ configurations are now quite feasible.     

Molecular relativistic electric field gradient calculations suggest revision of the value of the nuclear electric quadrupole moment of 127I

Relativistic ab initio methods are used to compute the electric field gradient at the iodine nucleus in nine different closed-shell diatomic molecules. Combining these theoretical electric field gradients with experimental nuclear quadrupole coupling constants gives a consistent value of the nuclear quadrupole moment of ¹²⁷I of—696(12)millibarn. We argue that this value is more precise than the current standard value of the nuclear quadrupole moment of ¹²⁷I and recommend adjusting the reference value accordingly. The precision of this determination is still determined by technical limitations in the theoretical work, in particular the neglect of the two-electron Gaunt interaction in the Hamiltonian and correlation contributions beyond those described at the CCSD(T) level of theory, but the errors are reduced relative to the theoretical work that underlies the current standard value of this nuclear quadrupole moment. As a secondary study we also considered the calculation of the small electric field gradient at the gold nucleus in the AuI molecule and conclude that this computation remains a challenge for theoreticians.     

Substituent effects on gas-phase acidities of formic acid and its silicon and sulphur derivatives R − M(= X)XH(M = C., Si; X = O,S; R = H,F, CI,OH, NH2 and CH3)

Ab initio molecular orbital methods at the CBS-Q level of theory have been used to study the effect of substituent (F, Cl, NH₂, OH and CH₃) on the gas-phase acidities of formic acid, HCOOH, its silicon and sulphur derivatives R-M(= X)XH(M = C., Si; X = 0, S; R = F, Cl, OH, NH₂ and CH₃). For formic acid and its thio and dithio derivatives the acidity changes upon substitution are irregular and depend on both the type of substituent, position and degree of replacement of oxygen atoms by sulphur atoms. For sila carboxylic acids and their thio and dithio derivatives the calculated acidities regularly increase in the order: R-SiOOH < R-Si(=S)OH ? R-Si(=O)SH < R-SiSSH(R = H, F, Cl, OH, NH₂ and CH₃). The chloro derivatives are the strongest among the acids studied. The highest gas phase acidity (1277.6 kJmol^?1) has been calculated for ClC(=S)OH.