2-Amino-4,4-disubstituted-5-carboxymethyl-Δ2-1,3,4-oxadiazolin-4-ium chlorides and their recyclization in acetic anhydride

2-Methylamino-4,4-disubstituted-5-carboethoxymethyl-²-1,3,4-oxadiazolin -4-ium chlorides were obtained from the reaction of 1,1-disubstituted-4-methylsemicarbazides with ethyl propiolate in the presence of hydrochloric acid. After hydrolysis of the ester these chlorides recyclize in acetic anhydride to 1-substituted-3-acetoxy-1H-pyrazoles. The difference in the direction of ring opening with acetic anhydride in the betaines of 1,3,4-oxadiazolin-5-acetic acids and their thia-analogs has been demonstrated.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 12, pp. 1685–1688, 1992.     

Pseudo-cross-conjugated mesomeric betaines. 1. Synthesis of pseudo-cross-conjugated mesomeric betaines from quinoxaline derivatives

A new method for the synthesis of pseudo-cross-conjugated mesomeric betainic heterocyclic compounds with an angular nitrogen atom has been developed consisting in the reaction of 1,4-dielectrophile — -carbethoxy-2-(3-chloro)quinoxalylacetonitrile with azoles. Experimental regularities have been studied and a reaction mechanism has been proposed including the stage of formation of an ylide from a quaternary azolium salt. A pseudo-crossconjugated mesomeric betainic heterocyclic compound containing a thiazole ring compound has been synthesized for the first time.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 11, pp. 1528–1533, November, 1992.     

Synthesis and investigation of the mesomorphic properties of pyran derivatives

4-[(5,6-Dihydro-2H-pyran-4-yl)methoxy]benzylidene-4-alkoxyanilines, which have the properties of smectic liquid crystals, were synthesized. The effect of the pyran ring in the benzylidene component and the length of the aliphatic radical in the aniline component on the type and thermal stability of the meso phase was ascertained.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 3, pp. 327–328, March, 1992.     

Humulenoids from plants of the family Apiaceae spatial structure of α-apienes

A conformational analysis has been made by the method of molecular mechanics of the -apienes — natural sesquiterpenes isolated from plants of the Apiaceae family. The results of the mathematical method with the inclusion of those x-ray structural studies have shown that in the molecules under consideration it is possible to expect the predominant realization of four conformations of the 11-membered ring:₁₄A ₈ ⁷ ,¹⁴A ₇ ⁸ ,₁₄A ₇ ⁸ , and¹⁴A ₈ ⁷ . These four conformations of unsubstituted -apiene and its natural derivatives have been characterized energetically, and the barriers to their interconversions have been evaluated.Institute of Chemistry of Plant Substances, Uzbekistan Academy of Sciences, Tashkent. Translated from Khimiya Prirodnykh Soedinenii, No. 2, pp. 197–202, March–April, 1992.     

Synthesis of 24-epiteasterone

Starting from ergosterol, the synthesis of the brassinosteroid 24-epiteasterone has been achieved by the use of a new scheme for introducing a 3-hydroxy-6-keto group as the result of the Birch reduction of the corresponding 5-hydroxy-⁷-3,6-dione.Institute of Bioorganic Chemistry, Belorussian Academy of Sciences, Minsk. Translated from Khimiya Prirodnykh Soedinenii, No. 2, pp. 224–227, March–April, 1992.     

Synthesis of 2-R-fluorantheno[2,3-d]- and 2-R-fluorantheno[3,2-d]oxazoles

2-R-Fluorantheno[2,3-d]- and 2-R-fluorantheno[3,2-d]oxazoles were synthesized, and their UV and IR spectra were studied. Ten new compounds are described.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 7, pp. 905–907, July, 1974.     

Calculation of exclusive processes with baryons

Using the nucleon andΔ ₃₃-resonance wave functions found out in previous papers [14, 15] we calculate the electromagnetic and weak nucleon formfactors, the transition formfactorγ \(\bar N\) Δ and the decay widths of charmonium levels³ S ₁,³ P ₂ and³ P ₁ into \(\bar N\) N and \(\bar \Delta \) Δ.     

Relativistic correction to the triton binding energy in the framework of relativistic Hamiltonian dynamics

The relativistic correction to the triton binding energy approximated to the order (v/c)² is calculated in the framework of relativistic Hamiltonian dynamics. We discuss the generator representation of the Poincaré group for three relativistic particles and its connection with the Feynman diagrams in the infinite-momentum frame (the light-front dynamics). The relativistic correction enhances the attraction in the three-nucleon system. The five-channel calculation with the Reid soft-core potential yeilds the result =–0.54 MeV, which is governed mainly by theD-wave contribution. TheS-wave contributions to are only –0.10 MeV.     

Laser-pulse fluctuations due to thermal self-action in a turbulent atmosphere

Conclusions Refractive-index fluctuations caused by heating alter the intensity and phase fluctuation spectra arising from the turbulence. The large-scale part of the spectra is weakened, whereas the small-scale part is strengthened, and the spatial-frequency range in which the fluctuations are attenuated becomes narrower as the beam energy increases. Correspondingly, the fluctuation structure functions alter. For values of the arguments in those functions less than the radius of the first Fresnel zone , the thermal nonlinearity causes increases in the structural functions D_, with the energy. For , the dependence of D_, on energy is nonmonotone, with the fluctuations at first weakened but then strengthened. The reduction in fluctuation variance and the improvement in coherence is less pronounced over long lines than on short ones. The range in which geometrical optics can be used to derive the fluctuations is independent of the nonlinearity and is defined by k₂z/2k /4. The trend to the diffraction asymptote becomes slower as the nonlinearity increases.Atmospheric Physics Institute, Academy of Sciences of the USSR. Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Radiofizika, Vol. 32, No. 9, pp. 1063–1071, September, 1989.