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171.
T. George B. Wu A. Dax M. Schneider W. Urban 《Applied physics. B, Lasers and optics》1991,53(5-6):330-332
We recently reported the extension of CO laser operation to a variety of single-line transitions in the fundamental band (v=1 0). Now saturation stabilization of these lines could be achieved using an intracavity absorption cell with CO at low pressure. A 3f-detection technique allowed reliable frequency locking on transitions from P(8) to P(14). A frequency stability of better than 10kHz was indicated. The frequency of the P(14) transition was measured in a heterodyne experiment to be 62, 546, 358.324 (50) MHz. 相似文献
172.
173.
On divergence-free wavelets 总被引:5,自引:0,他引:5
Karsten Urban 《Advances in Computational Mathematics》1995,4(1):51-81
This paper is concerned with the construction of compactly supported divergence-free vector wavelets. Our construction is based on a large class of refinable functions which generate multivariate multiresolution analyses which includes, in particular, the non tensor product case.For this purpose, we develop a certain relationship between partial derivatives of refinable functions and wavelets with modifications of the coefficients in their refinement equation. In addition, we demonstrate that the wavelets we construct form a Riesz-basis for the space of divergence-free vector fields.Work supported by the Deutsche Forschungsgemeinschaft in the Graduiertenkolleg Analyse und Konstruktion in der Mathematik at the RWTH Aachen. 相似文献
174.
Dielectric spectroscopy in a micromachined flow cytometer: theoretical and practical considerations 总被引:3,自引:0,他引:3
We propose a model to determine the influence of different cell properties, such as size, membrane capacitance and cytoplasm conductivity, on the impedance spectrum as measured in a microfabricated cytometer. A dielectric sphere of equivalent complex permittivity is used as a simplified model to describe a biological cell. The measurement takes place between a pair of facing microelectrodes in a microchannel filled with a saline solution. The model incorporates various cell parameters, such as dielectric properties, size and position in the channel. A 3D finite element model is used to evaluate the magnitude of the electric field in the channel and the resultant changes in charge densities at the measurement electrode boundaries as a cell flows past. The charge density is integrated on the electrode surface to determine the displacement current and the channel impedance for the computed frequency range. The complete impedance model combines the finite element model, the electrode-electrolyte interface impedance and stray impedance, which are measured from a real device. The modeled dielectric complex spectra for various cell parameters are discussed and a measurement strategy for cell discrimination with such a system is proposed. We finally discuss the amount of noise and measurement fluctuations of the sensor. 相似文献
175.
Activation barriers of the title reactions are calculated using a DZ + P basis set with diffuse p functions on negative ions. In the correlation effects, which are large and negative, the importance of single and triple excitations is stressed. The barrier for the reaction of H? with CH3F is 12 kJ/mole, in good agreement with experiment, while the barrier for the reaction of F? with CH3F is predicted to be 14 kJ/mole. 相似文献
176.
The partitioning of the free energy into additive contributions originating from different groups of atoms or force field
terms has the potential to provide relationship between structure and biological activity of molecules. In this article, the
theoretical foundation for the free energy decomposition in the free energy perturbation (FEP) methodology is formulated using
Thiele cumulants, a powerful tool from the arsenal of probability theory and mathematical statistics. We establish that rigorous
decomposition of the free energy into its components is precluded by the presence of mixed potential energy terms in Thiele
cumulants of second and higher orders. However, we also show that the resultant nonadditivity error can be reduced to an arbitrary
value by increasing the number of FEP steps. Consequently, the whole system can be in the limit of small perturbation steps
adequately represented by the sum of its constituent parts. 相似文献
177.
With the availability of resolution boosting and delocalization minimizing techniques, for example, spherical aberration correction and exit-plane wave function reconstruction, high-resolution transmission electron microscopy is drawing to a breakthrough with respect to the atomic-scale imaging of common semiconductor materials. In the present study, we apply a combination of these two state-of-the-art techniques to investigate lattice defects in GaAs-based heterostructures at atomic resolution. Focusing on the direct imaging of stacking faults as well as the core structure of edge and partial dislocations, the practical capabilities of both techniques are illustrated. For the first time, we apply the technique of bright-atom contrast imaging at negative spherical aberration together with an appropriate overfocus setting for the investigation of lattice defects in a semiconductor material. For these purposes, the elastic displacements associated with lattice defects in GaAs viewed along the 110 zone axis are measured from experimental images using reciprocal space strain map algorithms. Moreover, we demonstrate the benefits of the retrieval of the exit-plane wave function not only for the elimination of residual imaging artefacts but also for the proper on-line alignment of specimens during operation of the electron microscope--a basic prerequisite to obtain a fair agreement between simulated images and experimental micrographs. 相似文献
178.
179.
We investigated the generation dependent shape and internal structure of star-burst dendrimers under good solvent conditions using small angle x-ray scattering and molecular modeling. Measurements have been performed on poly(amidoamine) dendrimers with generations ranging from g=0 up to g=8 at low concentrations in methanol. We described the static form factor P(q) by a model taking into account the compact, globular shape as well as the loose, polymeric character of dendrimers. Monomer distributions within dendrimers are of special interest for potential applications and have been characterized by the pair correlation function gamma(r), as well as by the monomer and end-group density profile, rho(r) and rho(e)(r), respectively. Monomer density profiles and gamma(r) can be derived from P(q) by modeling and via a model independent approach using the inverse Fourier transformation algorithm first introduced by Glatter. Experimental results are compared with computer simulations performed for single dendrimers of various generations using the cooperative motion algorithm. The simulation gives direct access to gamma(r) and rho(r), allows an independent determination of P(q), and yields in addition to the scattering experiment information about the distribution of the end groups. Excellent qualitative agreement between experiment and simulation has been found. 相似文献
180.
[{Cp(CO)3Mo}4In4(PSiMe3)4], an Organometallic In4P4-Heterocubane [{Cp(CO)3Mo}InCl2] reacts with P(SiMe3)3 in THF as solvent to form [{Cp(CO)3Mo}4In4(PSiMe3)4] 1. 1 crystallizes in the space group P1 . The lattice constants (at 208 K) are: a = 1 770.1(6), b = 1 490.3(6), c = 1 317.5(6) pm, α = 76.59(4),β = 88.54(3), γ = 88.98(3)°. According to the crystal structure analysis, 1 contains a slightly distorted In4P4-core with an alternating arrangement of In and P atoms. The In atoms are coordinated roughly tetrahedrally by three PSiMe3 groups (In–P: 256.9(3)–262.3(3) pm) and a {Cp(CO)3Mo} substituent (In? Mo: 278.0(2)–279.5(3) pm). 相似文献