On holonomic D-modules attached to Reiffen’s hypersurface isolated singularities

A family of hypersurface isolated singularities, called Reiffen’s examples, is considered in the context of holonomic D-modules. Algebraic local cohomology classes attached to Reiffen’s singularities and their annihilating differential operators are studied. The algebraic local cohomology solution space to the first-order holonomic D-module is determined explicitly. As an application, it is shown that the multiplicity of the holonomic D-module can be described in terms of classical invariants of singularities. Translated from Sovremennaya Matematika i Ee Prilozheniya (Contemporary Mathematics and Its Applications), Vol. 54, Suzdal Conference–2006, Part 2, 2008.     

Antiferromagnetic interaction achieved by a 3-D supramolecular CuII complex with pyrazino-fused TTF as the ligand, [CuCl2(BP-TTF)

The diffusion reaction of TBA2Cu(II)Cl4 (TBA = tetrabutylammonium) and a N-containing organic donor, BP-TTF [=bis(pyrazino)tetrathiafulvalene], yielded a 3-D supramolecular Cu complex, [CuCl2(BP-TTF)] (1). The magnetic measurement of 1 exhibits an antiferromagnetic interaction by fitting a Bonner-Fisher model from 2 to 300 K with S = 1/2 and J = -3.5 K between Cu(IotaIota) mediated by self-assembling donor columns.     

Instability-free ion acceleration by two laser pulses

We demonstrate the instability-free ion acceleration regime by introducing laser control with two parallel circularly polarized laser pulses at an intensity of I = 6.8 × 10²¹?W/cm², normally incident on a hydrogen foil. The special structure of the equivalent wave front of those two pulses, which contains Gaussian peaks in both sides and a concavity in the centre (2D), can suppress the transverse instabilities and hole boring effects to constrain a high density ion clump in the centre of the foil, leading to an acceleration over a long distance and gain above 1GeV/u for the ion bunches.     

Diastereoselective addition of allyltitanocenes to cyclic enones

The reaction of allyltitanocenes with five- to seven-membered cyclic enones proceeded with good to high diastereoselectivity depending on the ring size of enones. The stereochemistry of the major isomers produced by the reaction of cinnamyltitanocene was opposite to that of crotyltitanocene.     

Interfacial modification of organic photovoltaic devices by molecular self-organization

This feature article focuses on the relationship between the interfacial structures constructed by molecular self-organization and the properties of organic photovoltaic devices. The use of self-assembled monolayers (SAMs) is reviewed for metal and metal oxide/organic interfaces, while surface-segregated monolayers (SSMs) are introduced as a new method for the modification of organic/organic interfaces. Research up to now has clearly demonstrated the effectiveness of the control of energy levels and other properties at the interfaces to enhance photovoltaic performance. The possibility of more precise control of the interfacial structures is also discussed.     

On-chip diagnosis of subclinical mastitis in cows by electrochemical measurement of neutrophil activity in milk

Subclinical mastitis is a common infectious disease affecting dairy cows. To develop an early diagnostic device for this disease, we focused on measuring an increase in the number of neutrophils in raw milk of mastitic cows. Superoxide anions (O(2)(-)), secreted by neutrophils, can be a good indicator of neutrophil concentration, and therefore, the seriousness of the mastitis. In this study, neutrophils in raw milk samples were separated from fat globules in a flow channel using differences in specific gravity and specific adhesion of neutrophils to P-selectin. Neutrophils trapped in the flow channel were subsequently concentrated in an array of micropillars of a working electrode modified with P-selectin and superoxide dismutase. The O(2)(-) secreted from the trapped neutrophils was electrochemically detected. A difference in the detection current was observed between normal and mastitic milk samples. A clear linear relationship between the electric current and cell density was observed.     

New measurements of high-momentum nucleons and short-range structures in nuclei

We present new measurements of electron scattering from high-momentum nucleons in nuclei. These data allow an improved determination of the strength of two-nucleon correlations for several nuclei, including light nuclei where clustering effects can, for the first time, be examined. The data also include the kinematic region where three-nucleon correlations are expected to dominate.     

High-speed wavelength-division multiplexing quantum key distribution system

A high-speed quantum key distribution system was developed with the wavelength-division multiplexing (WDM) technique and dedicated key distillation hardware engines. Two interferometers for encoding and decoding are shared over eight wavelengths to reduce the system's size, cost, and control complexity. The key distillation engines can process a huge amount of data from the WDM channels by using a 1 Mbit block in real time. We demonstrated a three-channel WDM system that simultaneously uses avalanche photodiodes and superconducting single-photon detectors. We achieved 12 h continuous key generation with a secure key rate of 208 kilobits per second through a 45 km field fiber with 14.5 dB loss.     

Chemistry of fullerene epoxides: synthesis, structure, and nucleophilic substitution-addition reactivity

Fullerene epoxides, C??O(n), having epoxide groups directly attached to the fullerene cage, constitute an interesting class of fullerene derivatives. In particular, the chemical transformations of fullerene epoxides are expected to play an important role in the development of functionalized fullerenes. This is because such transformations can readily afford a variety of mono- or polyfunctionalized fullerene derivatives while conserving the epoxy ring arrangement on the fullerene surface, as seen in representative regioisomeric fullerene polyepoxides. The first part of this review addresses the synthesis and structural characterization of fullerene epoxides. The formation of fullerene epoxides through different oxidation reactions is then explored. Adequate characterization of the isolated fullerene epoxides was achieved by concerted use of NMR and LC-MS techniques. The second part of this review addresses the substitution of fullerene epoxides in the presence of a Lewis acid catalyst. Most major substitution products have been isolated as pure compounds and their structures established through spectroscopic methods. The correlation between the structure of the substitution product and the oxygenation pattern of the starting materials allows elucidation of the mechanistic features of this transformation. This approach promises to lead to rigorous regioselective production of various fullerene derivatives for a wide range of applications.     

Ultrafast all-optical signal processing with Symmetric Mach–Zehnder type all-optical switches

We present Symmetric Mach–Zehnder (SMZ) type all-optical switches: an SMZ all-optical switch, a polarization-discriminating SMZ (PD-SMZ) all-optical switch, and a delayed interference signal wavelength converter (DISC). These switches are capable of ultrafast, low control power, and low chirp switching, which is not restricted by slow relaxation of highly efficient nonlinearities. High repetition operation unrestricted by slow relaxation is also possible for these switches. This is because of a push–pull modulation scheme or sometimes called a differential phase modulation scheme. These three devices are similar, but different in some important aspects, thus a comparison is made among the three. Then semiconductor optical amplifiers (SOAs) are discussed as a nonlinear phase shifter for these devices. Then, ultrafast all-optical signal processing using SOA based SMZs is demonstrated. Error-free demultiplexing from 168 to 10.5 Gbit/s is presented, in which a hybrid-integrated SMZ (HI-SMZ) is used as a demultiplexer. In pulse regeneration experiment, the signal pulses at 84 Gbit/s are regenerated by the PD-SMZ and the regenerated pulses are demultiplexed to 10.5 Gbit/s by the HI-SMZ to verify error-free operation. The retiming capability of this scheme is quantitatively demonstrated. Also presented is error-free all-optical wavelength conversion at 168 Gbit/s using the DISC. These results represent the fastest error-free operations reported to date in each category.