Normal and superconducting properties of single-crystalline BaPb1−xBixO3

Hall coefficient, resistivity and superconducting upper critical field H_n2 were measured on single-crystalline BaPb_1?xBi_xO₃ of compositions x = 0.20, 0.12 and 0, of which the normal-state properties differ significantly from those of polycrystals. The slope dH_n2/dT at T_c was estimated from the normal-state parameters and was found to agree well with the observed value, suggesting that this material is a bulk BCS superconductor.     

A new level at 192.5 keV in Ge

In the experiments on ⁷⁴Ge(d, pγ)⁷⁵Ge, a 52.5±0.1 keV γ-ray was found in ⁷⁵Ge with a half-life of 216±5 ns. From the analysis of the γ-ray spectra the conversion coefficient of the 52.5 keV γ-ray was determined. Then, a new level of is confirmed to exist at 192.5 keV. The reduced transition probabilities of the 52.5 keV transition are deduced to be (6.9^+5.6 _−2.1) × 10⁻⁵ for B(M1) and 31⁺³ ₋₂ for B(E2) in Weisskopf units.     

The crystallographic symmetries of single BaPb1−xBixO3 crystals grown from BaCO3-PbO2-Bi2O3 solutions

Single crystals of Perovskite-type oxide BaPb_1−xBi_xO₃ are grown from BaCO₃-PbO₂-Bi₂O₃ solutions which are weighed in two kinds of mixing ratios: X/2 mol % BaCO₃ − (100−X) mol % PbO₂ − X/2 mol % Bi₂O₃ and (10+X/2) mol % BaCO₃ − (90−X) mol % PbO₂ − X/2 mol % Bi₂O₃ These room temperature crystal structures are examined by using an X-ray powder diffraction method. The crystals grown from X/2−(100−X)−X/2 mol % solutions are orthorhombic at room temperature, while the structures are tetragonal with crystals grown from relatively Ba rich and Pb poor ( (10+X/2)−(90−X)−X/2 mol % ) solutions. This result indicates that the difference in the mixing ratio of the initial materials brings about a drastic structural change. The orthorhombic and the tetragonal crystals of x0.25 exhibit superconducting transition at 10K and 12K, respectively. The transition temperature in the latter is 2K higher than the former. In the light of this result, some difference between orthorhombic and tetragonal crystals is considered to influence superconductivity in this system.     

Solvent effect on photoisomerisation of 3-methyl-1-phenylbutane-1,2-dione 2-oxime

Photoisomerisation of (2E)- and (2Z)-3-methyl-1-phenylbutane-1,2-dione 2-oxime (MPBDO) in several solvents was studied. With increasing dielectric constants of solvents, kinetic constants of forward reactions (E-form-->Z-form) did not change appreciably but those of reverse reactions (Z-form-->E-form) decreased. The positive correlation was found between equilibrium constants of photoisomerisation and dielectric constants of solvents.     

Ab initio molecular orbital study of the reactivity of active alkyl groups. VII. Solvent effects on the formation of enolate isomers from 2-butanone with methoxide anion in methanol

The mechanism of the deprotonation of 2-butanone (1) with methoxide anion (2) was studied by ab initio molecular orbital (MO) methods. Calculations of the thermodynamic stabilities of each complex and the regioselectivity of the reaction were performed using a static isodensity surface polarized continuum model (IPCM) which takes the solvent effect into consideration. The calculated energies of the complexes lead ultimately to the conclusion that the major deprotonation pathway in protic solvents is dependent upon thermodynamically stable complexes with small activation energies under equilibrium control.     

Materials design for Cu-based quaternary compounds derived from chalcopyrite-rule

The stability of the Cu₂-II-IV-VI₄ and Cu-III-IV-VI₄ compounds (II=Zn, Cd; III=Ga, In; IV=Si, Ge, Sn; VI=S, Se, Te) as tetrahedral coordinated structures has been investigated by means of the electronegativity combination analysis of compositional elements. As compared with the results of the products synthesized from respective elemental mixtures, the possibility of crystallization in the form of tetrahedral coordinate compounds and the crystal structure are found to be expected by this semi-theoretical analysis. These melting points and lattice constants determined from the results of differential thermal analysis and powder X-ray diffraction, respectively, are found to vary linearly with increasing of mean atomic weight, and can be established from the empirical equations.     

Analysis of melt spinning transients in Lagrangian coordinates

Transients in melt spinning of isothermal power law and Newtonian fluids were found to be governed by an extremely simple partial differential equation ² ( ^1/n )/() = 0 in Lagrangian coordinates where is the cross-sectional area,n the power law exponent, the time and the the time at which a fluid molecule constituting the spinline left the spinneret. The general integral ^1/n =f() +g () of the above governing equation containing two arbitrary functions represents physically attainable spinline transients. Hitherto unknown analytical transient solutions of the above governing equation were obtained for the response of isothermal constant tension spinlines to a stepwise change in tension, spinneret hole area, extrusion speed or extrusion viscosity and for the starting transient in gravitational spinning. Linearized perturbation solutions and the stability limit of the spinline derived from the above new found nonlinear solutions were in agreement with previous findings and the above nonlinear response of the spinline to a step increase in the spinneret hole area was found to be equivalent to Orowan's tandem cylinder model of dent growth in filament stretching.     

CFD‐based multi‐objective optimization method for ship design

This paper concerns development and demonstration of a computational fluid dynamics (CFD)‐based multi‐objective optimization method for ship design. Three main components of the method, i.e. computer‐aided design (CAD), CFD, and optimizer modules are functionally independent and replaceable. The CAD used in the present study is NAPA system, which is one of the leading CAD systems in ship design. The CFD method is FLOWPACK version 2004d, a Reynolds‐averaged Navier–Stokes (RaNS) solver developed by the present authors. The CFD method is implemented into a self‐propulsion simulator, where the RaNS solver is coupled with a propeller‐performance program. In addition, a maneuvering simulation model is developed and applied to predict ship maneuverability performance. Two nonlinear optimization algorithms are used in the present study, i.e. the successive quadratic programming and the multi‐objective genetic algorithm, while the former is mainly used to verify the results from the latter. For demonstration of the present method, a multi‐objective optimization problem is formulated where ship propulsion and maneuverability performances are considered. That is, the aim is to simultaneously minimize opposite hydrodynamic performances in design tradeoff. In the following, an overview of the present method is given, and results are presented and discussed for tanker stern optimization problem including detailed verification work on the present numerical schemes. Copyright © 2006 John Wiley & Sons, Ltd.