全文获取类型
收费全文 | 482篇 |
免费 | 11篇 |
国内免费 | 2篇 |
专业分类
化学 | 394篇 |
晶体学 | 1篇 |
力学 | 17篇 |
数学 | 40篇 |
物理学 | 43篇 |
出版年
2020年 | 8篇 |
2017年 | 4篇 |
2016年 | 11篇 |
2015年 | 6篇 |
2014年 | 5篇 |
2013年 | 10篇 |
2012年 | 12篇 |
2011年 | 21篇 |
2010年 | 11篇 |
2009年 | 9篇 |
2008年 | 9篇 |
2007年 | 14篇 |
2006年 | 9篇 |
2005年 | 8篇 |
2004年 | 12篇 |
2003年 | 13篇 |
2002年 | 11篇 |
2001年 | 5篇 |
2000年 | 8篇 |
1999年 | 6篇 |
1998年 | 12篇 |
1997年 | 10篇 |
1996年 | 8篇 |
1995年 | 15篇 |
1994年 | 12篇 |
1993年 | 7篇 |
1992年 | 9篇 |
1991年 | 11篇 |
1990年 | 5篇 |
1989年 | 6篇 |
1988年 | 9篇 |
1987年 | 5篇 |
1986年 | 7篇 |
1985年 | 10篇 |
1984年 | 8篇 |
1983年 | 11篇 |
1982年 | 5篇 |
1981年 | 5篇 |
1980年 | 9篇 |
1978年 | 11篇 |
1976年 | 4篇 |
1975年 | 5篇 |
1974年 | 9篇 |
1964年 | 4篇 |
1955年 | 4篇 |
1912年 | 4篇 |
1905年 | 4篇 |
1903年 | 5篇 |
1902年 | 5篇 |
1900年 | 5篇 |
排序方式: 共有495条查询结果,搜索用时 15 毫秒
101.
Christoph Richter Frank Thiele Stefan Busse Claus Heuwinkel Ingo Röhle Lars Enghardt Ulf Michel 《PAMM》2008,8(1):10695-10696
An optimization method for the calculation of the wall impedance of a perforate from measurements under grazing flow conditions is presented. It is in particular characterized by the simultaneous eduction of the parameter set defining the impedance as function of frequency, which allows interpolation and extrapolation. The Extended Helmholtz Resonator is applied as impedance model and the simultaneous eduction is performed using a time–domain CAA method. Furthermore, the method uses processed energy data from experiments to define the objective function. The results give an insight in the effect of bias flow on the wall impedance under grazing flow conditions. It proves to be an important acoustic design parameter. (© 2008 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
102.
A Goban KS Choi DJ Alton D Ding C Lacroûte M Pototschnig T Thiele NP Stern HJ Kimble 《Physical review letters》2012,109(3):033603
We report the experimental realization of an optical trap that localizes single Cs atoms ?215 nm from the surface of a dielectric nanofiber. By operating at magic wavelengths for pairs of counterpropagating red- and blue-detuned trapping beams, differential scalar light shifts are eliminated, and vector shifts are suppressed by ≈250. We thereby measure an absorption linewidth Γ/2π=5.7±0.1 MHz for the Cs 6S_{1/2}, F=4→6P_{3/2}, F^{'}=5 transition, where Γ_{0}/2π=5.2 MHz in free space. An optical depth d?66 is observed, corresponding to an optical depth per atom d_{1}?0.08. These advances provide an important capability for the implementation of functional quantum optical networks and precision atomic spectroscopy near dielectric surfaces. 相似文献
103.
Four new low melting salts, “Ionic Liquids” consisting of the [CrIII(NCS)4(Phen)]? complex monoanion and imidazolium based cations A, with A = 1-ethyl-3-methylimidazolium (EMIm), 1-butyl-3-methylimidazolium (BMIm), 1,3-dimethyl-2,4,5-triphenylimidazolium (DML), and 1,2,3,4,5-pentamethyl-imidazolium (PMIm), were investigated. Single-crystal X-ray investigations established the structures of the four compounds. (EMIm)[Cr(NCS)4(Phen)] (I): triclinic, \(P\bar 1\), a = 8.1382(6), b = 10.4760(8), c = 16.003(1) Å, α = 90.330(4)°, β = 94.759(4)°, γ = 107.305(4)°, Z = 2, R 1(F)/wR 2(F 2) = 0.0650/0.1770; (BMIm)[Cr(NCS)4(Phen)] (II): triclinic, \(P\bar 1\), a = 8.5545(4), b = 9.8620(4), c = 16.6762(6) Å, α = 92.503(2)°, β = 97.517(2)°, γ = 91.249(2)°, Z = 2, R 1(F)/wR 2(F 2) = 0.0393/0.0848; (DML)[Cr(NCS)4(Phen)] · C3H6O (III): triclinic, \(P\bar 1\), a = 11.0475(9), b = 13.589(1), c = 14.582(1) Å, α = 83.013(4)°, β = 87.116(4)°, γ = 70.333(5)°, Z = 2, R 1(F)/wR 2(F 2) = 0.0407/0.1023; (PMIm)[Cr(NCS)4(Phen)] · C3H6O (IV): orthorhombic, Pbca, a = 17.379(1), b = 16.514(1), c = 22.304(1) Å, Z = 8, R 1(F)/wR 2(F 2) = 0.0460/0.1107 (in addition III and IV contain co-crystallized acetone molecules). Each compound was characterized by elemental analysis, NMR, IR, und UV-Vis spectroscopy. Magnetic properties were derived from NMR investigations (EVANS method). All four compounds are paramagnetic with effective magnetic moments of spin-only CrIII. Melting points were obtained from DSC measurements. All melting points are higher than required for “Ionic Liquids”, but nevertheless “low” for molten salts. 相似文献
104.
Endocrine-disrupting nonylphenols - ultra-trace analysis and time-dependent trend in mussels from the German bight 总被引:3,自引:0,他引:3
K Günther H W Dürbeck E Kleist B Thiele H Prast M Schwuger 《Fresenius' Journal of Analytical Chemistry》2001,371(6):782-786
A very sensitive and efficient analytical procedure is presented for the determination of 4-nonylphenols (NP) in blue mussels by use of off-line coupling of high-performance liquid chromatography (HPLC) and gas chromatography with mass spectrometric detection (GC-MS). Combined steam distillation and solvent extraction were used to extract the analytes from the mussel samples. Before quantification by GC-MS the raw extracts were purified by normal-phase HPLC. 4-n-Nonylphenol was used as internal standard. The detection limit was 15 ng NP absolute, calculated from the blank value. The method was applied to the determination of NP in blue mussel samples from the German North Sea sampled over a period of 10 years. Collection, homogenization, and storage of the mussels were performed according to the Standard Operating Procedures of the German Environmental Specimen Bank since 1985. The total NP concentrations in the mussels decreased significantly from 1985 (4 microgram kg (-1)) to 1995 (1.1 microgram kg (-1)). 相似文献
105.
Herm Thiele und R. Marc 《Fresenius' Journal of Analytical Chemistry》1905,44(3-4):214-215
Ohne Zusammenfassung 相似文献
106.
107.
108.
Ohne Zusammenfassung 相似文献
109.
M. Grehl R. Frhlich S. Thiele 《Acta Crystallographica. Section C, Structural Chemistry》1995,51(6):1038-1040
110.
Chamrad DC Koerting G Gobom J Thiele H Klose J Meyer HE Blueggel M 《Analytical and bioanalytical chemistry》2003,376(7):1014-1022
Recent developments in proteomics have revealed a bottleneck in bioinformatics: high-quality interpretation of acquired MS data. The ability to generate thousands of MS spectra per day, and the demand for this, makes manual methods inadequate for analysis and underlines the need to transfer the advanced capabilities of an expert human user into sophisticated MS interpretation algorithms. The identification rate in current high-throughput proteomics studies is not only a matter of instrumentation. We present software for high-throughput PMF identification, which enables robust and confident protein identification at higher rates. This has been achieved by automated calibration, peak rejection, and use of a meta search approach which employs various PMF search engines. The automatic calibration consists of a dynamic, spectral information-dependent algorithm, which combines various known calibration methods and iteratively establishes an optimised calibration. The peak rejection algorithm filters signals that are unrelated to the analysed protein by use of automatically generated and dataset-dependent exclusion lists. In the "meta search" several known PMF search engines are triggered and their results are merged by use of a meta score. The significance of the meta score was assessed by simulation of PMF identification with 10,000 artificial spectra resembling a data situation close to the measured dataset. By means of this simulation the meta score is linked to expectation values as a statistical measure. The presented software is part of the proteome database ProteinScape which links the information derived from MS data to other relevant proteomics data. We demonstrate the performance of the presented system with MS data from 1891 PMF spectra. As a result of automatic calibration and peak rejection the identification rate increased from 6% to 44%.Abbreviations 2-DE Two-dimensional gel electrophoresis - MALDI Matrix-assisted laser desorption ionisation - PMF Peptide mass fingerprinting - MS Mass spectrometry - TOF Time of flight 相似文献