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71.
72.
Monomer-lsomerization Polymerization of Some Branched Internal Olefins with a Ziegler-Natta Catalyst
New examples for the monomer-isomerization polymerizations of some branched internal olefins, 4-methyl-2-pentene and 4-phenyl-2-butene, are presented. When these olefins are polymerized with A1(C2 H5)3-TiCl3 ([TiCl3] = 120 mmole/liter, A1/Ti = 3.0) catalyst at 80°C, considerable amounts of high polymers [27.5%/60 hr ([η] = 0.68 d1/g) and 35.6%/100hr, respectively] were obtained. From the additional fact that the isomerization from these 2-olefins to the mixture of their positional isomers including 1-olefins was observed during the polymerization, it is assumed that the polymerizations from these 2-olefins are performed with the 1-olefins which isomerized from the starting 2-olefins. 相似文献
73.
We propose an empirical likelihood-based estimation method for conditional estimating equations containing unknown functions, which can be applied for various semiparametric models. The proposed method is based on the methods of conditional empirical likelihood and penalization. Thus, our estimator is called the penalized empirical likelihood (PEL) estimator. For the whole parameter including infinite-dimensional unknown functions, we derive the consistency and a convergence rate of the PEL estimator. Furthermore, for the finite-dimensional parametric component, we show the asymptotic normality and efficiency of the PEL estimator. We illustrate the theory by three examples. Simulation results show reasonable finite sample properties of our estimator. 相似文献
74.
Ishida T Alexandrov M Nishimura T Minakawa K Hirota R Sekiguchi K Kohyama N Kuroda A 《Journal of fluorescence》2012,22(1):357-363
Fluorescence microscopy (FM) has recently been applied to the detection of airborne asbestos fibers that can cause asbestosis,
mesothelioma and lung cancer. In our previous studies, we discovered that the E. coli protein DksA specifically binds to the most commonly used type of asbestos, chrysotile. We also demonstrated that fluorescent-labeled
DksA enabled far more specific and sensitive detection of airborne asbestos fibers than conventional phase contrast microscopy
(PCM). However, the actual diameter of the thinnest asbestos fibers visualized under the FM platform was unclear, as their
dimensions were below the resolution of optical microscopy. Here, we used correlative microscopy (scanning electron microscopy
[SEM] in combination with FM) to measure the actual diameters of asbestos fibers visualized under the FM platform with fluorescent-labeled
DksA as a probe. Our analysis revealed that FM offers sufficient sensitivity to detect chrysotile fibrils as thin as 30–35 nm.
We therefore conclude that as an analytical method, FM has the potential to detect all countable asbestos fibers in air samples,
thus approaching the sensitivity of SEM. By visualizing thin asbestos fibers at approximately tenfold lower magnifications,
FM enables markedly more rapid counting of fibers than SEM. Thus, fluorescence microscopy represents an advanced analytical
tool for asbestos detection and monitoring. 相似文献
75.
76.
77.
Synthesis of 2,4-diiodoquinolines via the photochemical cyclization of o-alkynylaryl isocyanides with iodine 总被引:1,自引:0,他引:1
Upon photoirradiation of o-alkynylaryl isocyanides in the presence of iodine, the intramolecular cyclization of o-alkynylaryl isocyanides proceeds to afford the corresponding 2,4-diiodoquinolines in good yields. 2,4-Diiodoquinolines can be employed in transition metal-catalyzed cross-coupling reactions. 相似文献
78.
A novel saccharide sensor that shows a distinct color change resembling a "traffic signal" was developed. By copolymerizing a boronic acid monomer and an amine monomer on a glass plate, a boronic acid-containing thin film was obtained. After adsorbing anionic blue and yellow dyes, the thin film was immersed in aqueous saccharide solutions containing a cationic red dye. As saccharide concentration increased, the thin film changed its color from green to red via yellow. Origin of the distinct color change was attributed to a stepwise release and binding of dyes. 相似文献
79.
T Yano K Ohmori H Takahashi T Kusumi K Suzuki 《Organic & biomolecular chemistry》2012,10(38):7685-7688
A catechin hetero-trimer isolated from Ziziphus jujuba has been synthesized. Among three constituent monomers, (-)-epiafzelechin and (-)-epigallocatechin were prepared by de novo synthesis. Trimer formation relied on the unified approach to oligomers based on the bromo-capping and the orthogonal activation, reaching the reported structure of the natural product. 相似文献
80.
J. W. Hwang Y. Satou T. Nakamura Y. Kondo N. Matsui Y. Hashimoto T. Nakabayashi T. Okumura M. Shinohara N. Fukuda T. Sugimoto H. Otsu Y. Togano T. Motobayashi H. Sakurai Y. Yanagisawa N. Aoi S. Takeuchi T. Gomi M. Ishihara S. Kawai H. J. Ong T. K. Onishi S. Shimoura M. Tamaki T. Kobayashi Y. Matsuda N. Endo M. Kitayama 《Few-Body Systems》2013,54(7-10):1469-1472
The 16C nucleus has been investigated by the neutron knockout reaction of 17C on a liquid hydrogen target. Applying the invariant mass method in inverse kinematics and γ-ray spectroscopy, the energy spectrum was reconstructed by triple-coincidence measurement, in which neutrons, charged fragments, and γ rays from the decay of the reaction residue (16C*) were detected. A peak at 0.47 MeV was observed in the invariant mass spectrum in coincidence with a peak at 0.74 MeV in the γ-ray spectrum, which indicates the presence of an unbound state with an excitation energy of 5.46 MeV. Comparison of the experimental cross section with the value derived by a theoretical calculation provided evidence that the spin-parity of this state is 2?. 相似文献