Al_2O_3包覆Ba_(0.6)Sr_(0.4)TiO_3复合粉体制备及表征

采用液相包覆法制备了Al2O3包覆的Ba0.6Sr0.4TiO3复合粉体。通过SEM,TEM,TG-DSC,XRD,XPS和ζ电位测试对包覆前后粉体的表面形貌、组织结构、等电点进行了测试和分析。结果表明:Al2O3以无定形结构成功的包覆在Ba0.6Sr0.4TiO3粉体表面,形成了Ba-O-Al、Sr-O-Al和Ti-O-Al键,Ba0.6Sr0.4TiO3颗粒的等电点由包覆前的pH=3.2增大至pH=8。     

类金刚石薄膜修饰传感器在电化学中的应用

综述了类金刚石薄膜及其修饰的传感器特性以及制备工艺,介绍了类金刚石薄膜修饰的传感器在生物检测、电化学微重力测量、痕量金属检测、氢离子选择场效应晶体管和气体检测等领域的应用,并对类金刚石薄膜修饰传感器在电化学相关领域的应用进行了展望。     

聚二乙烯苯整体柱的制备及其在气相色谱分析中的应用

初步探讨了毛细管整体柱的制备方法及其在气相色谱分析中的应用。以液相色谱用毛细管整体柱作为研究基础,通过改变甲苯和十二醇的比例,使整体柱适用于气相色谱分析。通过二乙烯苯与键合在管壁上的3-(异丁烯酰氯)丙基三甲氧基硅烷(TMP)键合以及其自身的聚合,获得具有牢固结构、良好机械强度的整体柱。将其用于混合溶剂的分析和白酒标样的分析,可直接分析水中低碳醇。与现有的商品柱进行比较,结果表明所制备的整体柱均优于用以对照的商品色谱柱,其中在混合溶剂的分析中,醇类、酯类、酮类和芳烃类的峰形均优于用于比较的多孔层开口管(PLOT)柱;在白酒标样分析中,使得乙醛、甲醇、乙酸乙酯的色谱峰能够分开,比现有的聚乙二醇(PEG-20M)柱的分析方法更为便捷。     

Li2CO3添加剂对石墨电极性能的影响

运用电化学阻抗谱(EIS)和循环伏安法(CV)研究了在1mol/LLiPF6-EC(碳酸乙烯酯):DMC(碳酸二甲酯)电解液中添加Li2CO3对石墨电极性能的影响及机制.CV研究结果表明,在1mol/LLiPF6-EC:DMC电解液中添加Li2CO3能够有效抑制石墨电极首次充放电过程中碳酸乙烯酯(EC)的单电子还原过程,即还原分解产生乙烯和碳酸锂的过程,进而改善石墨电极的电化学循环性能.EIS研究结果表明,在添加Li2CO3的1mol/LLiPF6-EC:DMC电解液中,石墨电极表面的固体电解质相界面膜(SEI膜)具有较强的黏弹性,可以更好地适应锂离子嵌入过程中石墨颗粒体积的微小变化,从而使锂离子的嵌入过程更容易进行.     

Analysis of a Critical Residue Determining Herbicide Efficiency Sensitivity in Carboxyltransferase Domain of Acetyl-CoA Carboxylase from Poaceae by Homology Modeling and Free Energy Simulation

Carboxyltransferase domain(CT) of acetyl-coenzyme A carboxylase(ACCase, EC 6.4.1.2) from a family of Poaceae is an important target of commercial herbicide APPs for controlling grass weed growth. As the abuse of APPs herbicides, the resistant ACCase due to the mutation of a single residue(Ile→Leu), which is lo-cated in CT active site, is emergent in many populations and species of Poaceae. So it is urgent to understand the re-sistant mecha-nism so as to design new effect herbicides. Herein lies the complex of CT dimmer from Lolium rigi-dum and herbicide haloxyfop successfully constructed for wild type enzyme and Ile/Leu mutant, respectively, pro-viding a basis for explaining the resistance from microscopic structure. Moreover, the binding free energy difference between wild type and mutant enzymes was predicted in good agreement with the known observation, and the various contributions to it were analyzed, by Molecular mechanics-Poisson-Boltzmann surface area(MM-PBSA) method. The results indicate the van der Waals interaction difference between the protein and inhibitor, –22.94 kJ/mol of CT wild type lower than that of mutant, is the major reason for resistance. Structure analysis further suggests that van der Waals interaction difference is originated from the steric hindrance between the side chain of mutated residue Leu and the chiral methyl group of haloxyfop. All these findings enhance the understanding of resistant mechanism of ACCase to herbicide by Ile/Leu mutation and provide an important clue for the rational design of high effective herbicides.     

超疏水性材料表面的制备、应用和相关理论研究的新进展

文章总结了Wenzel方程、Cassie方程及一种具有极高精确度的,可方便测出固体表面上液滴前进角和后退角的测试方法等超疏水表面的最新理论研究成果;回顾了溶胶凝胶法、化学修饰法、喷涂法、液相法、化学蚀刻法、水热法、微相分离法、原位聚合法、静电纺丝法、阳极氧化法等近几年出现的超疏水表面的制备方法;介绍了在微物质能量、生物医学、光学、燃料以及电池应用等领域超疏水表面的最新功能性的应用。最后,客观地展望了超疏水表面制备及理论研究的发展方向。     

典型表面活性剂在玻碳电极上的电化学行为及吸附模式

随着电(分析)化学的发展,表面活性剂在电化学中的应用显得越来越重要,在金属防腐[1-2]、提高电分析测定方法的选择性[3]、电活性物质增敏检测[4-5]等方面扮演着关键角色.要搞清楚相关作用机理,就需要研究表面活性剂本身在电极表面的电化学行为,而这大都与它们在电极表面的吸附有关[6].因此,研究表面活性剂在电极表面的电化学行为及其吸附模式就显得很重要,而相关的研究报导较少.     

A New Layer W/Cu/S Polymer with Heterobimetallic Nodes and Tridentate Trithiocyanuric Acid

Solvothermal reaction of [WS4]2-with CuCN and trithiocyanuric acid(L1) in orga-nic solvents gave rise to a new W/Cu/S polymer with a 2D anionic network,namely [Et4N]2[WS4Cu3(C3N3S3H1.5)2](1).The anionic layer of 1 is constructed by the T-shaped {WS4Cu3} subunits as nodes and L1 as linkers and features a(4,4) topology.Both 1 and its isomorphous compound [Et4N]2[MoS4Cu3(C3N3S3H1.5)2](2) have been fully characterized by X-ray crystal analysis,IR and microanalyses.Compounds 1 and 2 show optical transitions with band gaps of 2.17 and 1.84 eV,respectively.     

交联聚苯乙烯微球的表面化学改性及吡啶基卟啉的固载化

以无致癌毒性的1,4-二氯甲氧基丁烷为氯甲基化试剂,先将交联聚苯乙烯(CPS)微球氯甲基化,制得氯甲基化微球CMCPS。 然后使微球CMCPS与4-吡啶甲醛进行季铵化反应,将4-吡啶甲醛键合到CPS微球表面,制得键合吡啶甲醛(PyAL)的改性微球PyAL-CPS。 考察了主要反应条件对季铵化反应的影响,最终确定季铵化反应的优化条件:溶剂CCl4,反应温度60 ℃,最后使改性微球PyAL-CPS、4-吡啶甲醛及吡咯在固-液界面上进行Adler反应,形成固载吡啶基卟啉(PyP)的微球PyP-CPS。 用IR和UV-Vis以及Zn2+配合物生成法表征了微球PyP-CPS的形成及负载量。     

Design,synthesis, and characterization of a combined main-chain/side-chain liquid-crystalline polymer based on ethyl cellulose

A novel combined main-chain/side-chain liquid-crystalline polymer based on an ethyl cellulose main chain containing azobenzene mesogens (AzoEC) was successfully synthesized. Molecular characterization of the resulting polymers with different degrees of substitution (DS) was performed with proton nuclear magnetic resonance (¹H NMR), Fourier-transform infrared spectroscopy (FTIR), and gel permeation chromatography (GPC). Thermal stability was investigated by thermogravimetric analysis (TGA). The phase transitions and liquid-crystalline behavior of these polymers were investigated by differential-scanning calorimetry (DSC), polarized optical microscopy (POM), and wide-angle X-ray diffraction (WAXD). The results indicate that DS has substantial effect on the liquid-crystalline behavior of these polymers. AzoEC with low DS only shows the cholesteric phase similar to ethyl cellulose (EC). However, when DS increases to a specific value, AzoEC begins to show fascinating supramolecular structures. The supramolecular structure of AzoEC with maximum DS consisted of a large-scale ordered lamellar structure formed by EC main chains and a small-scale ordered structure formed by azobenzene mesogens.