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991.
Scott T. Knauert Jack F. Douglas Francis W. Starr 《Journal of Polymer Science.Polymer Physics》2007,45(14):1882-1897
Nanoparticles can influence the properties of polymer materials by a variety of mechanisms. With fullerene, carbon nanotube, and clay or graphene sheet nanocomposites in mind, we investigate how particle shape influences the melt shear viscosity η and the tensile strength τ, which we determine via molecular dynamics simulations. Our simulations of compact (icosahedral), tube or rod‐like, and sheet‐like model nanoparticles, all at a volume fraction ? ≈ 0.05, indicate an order of magnitude increase in the viscosity η relative to the pure melt. This finding evidently can not be explained by continuum hydrodynamics and we provide evidence that the η increase in our model nanocomposites has its origin in chain bridging between the nanoparticles. We find that this increase is the largest for the rod‐like nanoparticles and least for the sheet‐like nanoparticles. Curiously, the enhancements of η and τ exhibit opposite trends with increasing chain length N and with particle shape anisotropy. Evidently, the concept of bridging chains alone cannot account for the increase in τ and we suggest that the deformability or flexibility of the sheet nanoparticles contributes to nanocomposite strength and toughness by reducing the relative value of the Poisson ratio of the composite. The molecular dynamics simulations in the present work focus on the reference case where the modification of the melt structure associated with glass‐formation and entanglement interactions should not be an issue. Since many applications require good particle dispersion, we also focus on the case where the polymer‐particle interactions favor nanoparticle dispersion. Our simulations point to a substantial contribution of nanoparticle shape to both mechanical and processing properties of polymer nanocomposites. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 1882–1897, 2007 相似文献
992.
T. Ramanathan S. Stankovich D. A. Dikin H. Liu H. Shen S. T. Nguyen L. C. Brinson 《Journal of Polymer Science.Polymer Physics》2007,45(15):2097-2112
Mechanical, thermal, and electrical properties of graphite/PMMA composites have been evaluated as functions of particle size and dispersion of the graphitic nanofiller components via the use of three different graphitic nanofillers: “as received graphite” (ARG), “expanded graphite,” (EG) and “graphite nanoplatelets” (GNPs) EG, a graphitic materials with much lower density than ARG, was prepared from ARG flakes via an acid intercalation and thermal expansion. Subsequent sonication of EG in a liquid yielded GNPs as thin stacks of graphitic platelets with thicknesses of ~10 nm. Solution‐based processing was used to prepare PMMA composites with these three fillers. Dynamic mechanical analysis, thermal analysis, and electrical impedance measurements were carried out on the resulting composites, demonstrating that reduced particle size, high surface area, and increased surface roughness can significantly alter the graphite/polymer interface and enhance the mechanical, thermal, and electrical properties of the polymer matrix. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 2097–2112, 2007 相似文献
993.
M. T. Viciosa J. Quiles Hoyo M. Dionísio J. L. Gómez Ribelles 《Journal of Thermal Analysis and Calorimetry》2007,90(2):407-414
Temperature modulated differential scanning calorimetry (TMDSC) is used to study the kinetics of the free radical isothermal polymerization of triethyleneglycol dimethacrylate (TEGDMA). Azo-bis-isobutironitrile was used as initiator. The polymerization’s temperature is lower than the final glass transition temperature of the polymer network. The measurement of the average heat flow released and the heat capacity during the reaction allows identifying the different stages of the reaction. The presence of double peaks in the heat flow is ascribed to the autoacceleration. The influence of temperature, measuring conditions and oxygen are described. Vitrification is detected by the drop in heat capacity. It occurs at increasing conversion rates for increasing temperatures. After vitrification, the diffusion-controlled reaction continues. 相似文献
994.
A group of machines for processing a set of jobs in a manufacturing system is often located in a serial line. An efficient strategy for locating these machines such that the total travel distance or the cost of transporting the jobs is minimized is desired. In this research, the assumption of a linear line with equally spaced machine location is relaxed. This research addressed problems of locating unique machines. It is found that the machine distances possess unique properties in this type of a problem. Utilizing these properties, heuristic strategies are proposed to obtain efficient solution where optimal methods are expected to be computationally prohibitive. A lower bound for the optimum solution is also proposed. Results are encouraging. 相似文献
995.
Martin I. Karakhanyan 《Journal of Contemporary Mathematical Analysis (Armenian Academy of Sciences)》2007,42(3):146-150
The paper proves some general facts on commutators that refer to Fuglede-Putnam classical theorem in the spectral theory of not necessarily selfadjoint operators. 相似文献
996.
Those who have worked in the Royal Institution of Great Britain have, since its foundation in 1799, made significant contributions
to scientific knowledge, to its practical application, and to its communication to a wide variety of audiences. Such work
cannot be carried out in an architectural vacuum, and in this paper we examine how the buildings of the Royal Institution,
20 and 21 Albemarle Street in central London, have shaped the work undertaken within its walls and how, on a number of occasions,
the buildings have been reconfigured to take account of the evolving needs of scientific research and communication.
This paper is based on the Conservation Plan of the Royal Institution that we wrote during 2003. The Conservation Plan did
not examine the land owned by the Royal Institution to the north (i.e., 22 and 23 Albemarle Street; for this area see Richard Garnier, “Grafton Street, Mayfair,” Georgian Group Journal 13 (2003), 210–272), but it did discuss 18 and 19 Albemarle Street. In this paper we concentrate on the core Royal Institution
buildings at 20 and 21 Albemarle Street. Other studies of the relationship of architecture,space, and science include Crosbie
Smith and Jon Agar, ed., Making Space for Science: Territorial Themes in the Shaping of Knowledge (Basingstoke: Macmillan, 1997); Peter Galison and Emily Thompson, ed., The Architecture of Science (Cambridge, Mass.: MIT Press, 1999); and Sophie Forgan,“The architecture of science and the idea of a university,” Studies in History and Philosophy of Science 20 (1989), 405–434.
Frank A.J.L. James is Professor of the History of Science at the Royal Institution; he has written widely on the history of
nineteenth-century science in its social and cultural contexts and is editor of the Correspondence of Michael Faraday. He is President of the British Society for the History of Science. Anthony Peers is an Associate of Rodney Melville and
Partners where he works in the field of building conservation as an architectural historian. He is a Council member of the
Ancient Monument Society. 相似文献
997.
Massively parallel computational paradigms can mitigate many issues associated with the analysis of large and complex remotely sensed data sets. Recently, the Beowulf cluster has emerged as the most attractive, massively parallel architecture due to its low cost and high performance. Whereas most Beowulf designs have emphasized numerical modeling applications, the Parallel Image Processing Environment (PIPE) specifically addresses the unique requirements of remote sensing applications. Automated, parallelization of user-defined analyses is fully supported. A neural network application, applied to Along Track Scanning Radiometer-2 (ATSR-2) data shows the advantages and performance characteristics of PIPE. 相似文献
998.
François Loiseau Jean-Mary Simone David Carcache Pavel Bobal Reinhard Neier 《Monatshefte für Chemie / Chemical Monthly》2007,138(2):121-129
Summary. Free radical couplings from furan, as cheap starting material, were studied in view of developing a rapid strategy en route to the synthesis of derivatives of nonactin. The chain containing the alcohol function was introduced in one or two steps
in 86% yield. For the introduction of the second chain with the ester function two different coupling methods were tested.
Starting from the advanced intermediates obtained nonactin derivatives can be prepared by catalytic hydrogenation of the furan
ring. 相似文献
999.
Katharina Habermann Lutz Habermann Paul Rosenthal 《Calculus of Variations and Partial Differential Equations》2007,30(2):137-152
A Yang–Mills theory in a purely symplectic framework is developed. The corresponding Euler–Lagrange equations are derived
and first integrals are given. We relate the results to the work of Bourgeois and Cahen on preferred symplectic connections. 相似文献
1000.
David Worthington 《The Journal of the Operational Research Society》1991,42(10):833-843
This paper describes work carried out with hospital consultants in Lancaster District Health Authority to develop and use computerized waiting list management models. The ‘what if?’ models produced have been found to be a very useful tool in the constructive debate about problems faced by consultants and managers, and of the options available to them. 相似文献