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21.
The structure of liquid indium in a wide temperature range has been investigated by means of X-ray diffraction and reverse Monte Carlo methods. Analysis of temperature dependence of the interatomic distances and coordination numbers allowed us to determine the existence of structural transformation in a liquid state. Moreover, it was found that at a temperature of 640 K thermal expansion coefficients, estimated from temperature dependence of interatomic distances, change its sign from negative to positive confirming the transformations in structure of liquid indium which are observed by temperature variations. 相似文献
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The paper concerns the possibilities for mathematical modelling of safety related systems (equipment oriented on safety). Some mathematical models have been required by the present European Standards for the railway transport. We are interested in the possibility of using Markov's models to meet these Standards. In the text an example of using that method in the interlocking equipment life cycle is given. An efficient aggregation/disaggregation method for computing some characteristics of Markov chains is presented. 相似文献
24.
Chuprakov S Malik JA Zibinsky M Fokin VV 《Journal of the American Chemical Society》2011,133(27):10352-10355
A highly efficient enantioselective C-H insertion of azavinyl carbenes into unactivated alkanes has been developed. These transition metal carbenes are directly generated from readily available and stable 1-sulfonyl-1,2,3-triazoles in the presence of chiral Rh(II) carboxylates and are used for C-H functionalization of alkanes to access a variety of β-chiral sulfonamides. 相似文献
25.
Stepan Dmytrovych Ivasyshen Vasyl?? Vasyl??ovych Layuk 《Journal of Mathematical Sciences》2011,173(4):341-370
For a class of ultraparabolic equations of the Kolmogorov type, we prove the theorems on the correct solvability and the integral representation of solutions of the Cauchy problem, whose initial data belong to special weight spaces of functions and generalized Borel measures. On the basis of these theorems, we obtained the full characterization of appropriate classes of solutions of the equations under consideration. 相似文献
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Stepan Geri Tereza Krunclova Dr. Olga Janouskova Dr. Jiri Panek Dr. Martin Hruby Daniel Hernández-Valdés Dr. Benjamin Probst Prof. Roger A. Alberto Dr. Constantin Mamat Dr. Manja Kubeil Dr. Holger Stephan 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(48):10992-11006
Two photoactivatable dicarbonyl ruthenium(II) complexes based on an amide-functionalised bipyridine scaffold (4-position) equipped with an alkyne functionality or a green-fluorescent BODIPY (boron-dipyrromethene) dye have been prepared and used to investigate their light-induced decarbonylation. UV/Vis, FTIR and 13C NMR spectroscopies as well as gas chromatography and multivariate curve resolution alternating least-squares analysis (MCR-ALS) were used to elucidate the mechanism of the decarbonylation process. Release of the first CO molecule occurs very quickly, while release of the second CO molecule proceeds more slowly. In vitro studies using two cell lines A431 (human squamous carcinoma) and HEK293 (human embryonic kidney cells) have been carried out in order to characterise the anti-proliferative and anti-apoptotic activities. The BODIPY-labelled compound allows for monitoring the cellular uptake, showing fast internalisation kinetics and accumulation at the endoplasmic reticulum and mitochondria. 相似文献
28.
Considering a two DoF system subject to digital position control, of interest for robotic application, we analyze the dynamics of the system at the intersection of two loci of Neimark–Sacker bifurcations, where a double Neimark–Sacker bifurcation is taking place. In the system, the saturation of the control force is the only nonlinear term considered, other than this, the system is piecewise linear. Starting from the analytical investigation already performed in Part I (Habib et al. in Nonlin. Dyn., under review, 2013), in this paper the effects of an asymmetry of the saturation of the control force are investigated, both analytically and numerically. The results show the increasing complexity of the dynamics for a more and more asymmetric system. First, the asymmetry is making the bifurcation transit from supercritical to subcritical, then it generates a stable torus that breaks down into a strange attractor, associated with a chaotic motion. In the last part of the paper, the torus breakdown and the onset of chaos are investigated, furthermore the evolution of complex dynamics through regions of phase locking and higher-dimensional chaos is outlined. 相似文献
29.
Stanislav S. Bielawski Stepan G. Mulyarchik Andrew V. Popov 《Journal of Computational and Applied Mathematics》1996,70(2):189-200
In this paper we show how an algebraically reduced system can be constructed, for which the preconditioned conjugate gradient method converges faster than for the original system. For this method it is necessary that the original matrix is symmetric positive-definite. Our approach is based on an efficient projection on a well-chosen subspace and we show an application in which a cyclically reduced system is one step further reduced by this novel technique. 相似文献
30.
Stepan Boitsov Jon Songstad Karl W. Trnroos 《Acta Crystallographica. Section C, Structural Chemistry》2002,58(8):o528-o532
The molecular structures of the three title nitro‐substituted phenylacetonitriles, C8H6N2O2, at 123 K show that the molecules are linked together very differently. In the 2‐ and 4‐nitro compounds, there are both O?H and Ncyano?H interactions, whereas the crystal lattice of the 3‐nitro compound is essentially built up by O?H interactions. The O atoms seem to prefer the aromatic H atoms, while the cyano N atoms prefer the methylene H atoms. The phenyl–nitro torsion angles are ?19.83 (13), ?5.69 (12) and ?2.88 (12)°, while the phenyl–cyanomethyl torsion angles are ?62.27 (12), ?147.99 (9) and ?16.75 (14)° in the 2‐, 3‐ and 4‐NO2‐substituted compounds, respectively. 相似文献