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91.
Strange hadronic matter 总被引:1,自引:0,他引:1
92.
[formula: see text] The total synthesis of the marine sesquiterpene quinone (+)-puupehenone, a promising new antituberculosis agent, was achieved in 10 steps starting from commercially available (+)-sclareolide. The key feature of this synthesis is the construction of the heterocycle via an intramolecular attack of the terpenoid-derived C-8 oxygen function onto an oxidatively activated 1,2-dihydroxyphenyl unit. 相似文献
93.
The development of a one-pot tandem intramolecular conjugate addition/nucleophilic acyl substitution using samarium(II) iodide is reported. The reaction relies on the reagent’s unique ability to mediate both radical and anionic pathways, which are likely integral to the mechanism of this transformation. The tricyclic hemiacetal product was formed in good yield, with excellent diastereoselectivity, and its structure was verified by X-ray crystallographic analysis. 相似文献
94.
V. P. Gupta L. E. St. Pierre 《Journal of polymer science. Part A, Polymer chemistry》1979,17(3):797-806
On the basis of the simultaneously measured free radical generation and HCl evolution a mechanism accounting for the effect of the oxygen on the degradation of poly(vinyl chloride) (PVC) is proposed. The mechanism is based on the reaction of oxygen with radicals generated in PVC to form unstable peroxy radicals. In addition, it is proposed that oxygen reacts directly with conjugated polyenes to form peroxy linkage. 相似文献
95.
L. Dobrzynski B. Djafari-Rouhani J. Vasseur R. Kucharczyk M. St
licka 《Progress in Surface Science》1995,48(1-4):213-218
We study the electronic properties of a mesoscopic system composed of an array of straight, infinite rods made of an isotropic medium and embedded in a regular way in an isotropic background. Such a composite system has two-dimensional periodicity in the plane perpendicular to the rods. Using a Fourier series expansion, the corresponding Schrödinger equation is solved within the effective-mass approximation. The electronic band structure
is computed for the wave vector
in the transverse plane, and is illustrated by dispersion curves along the principal directions of the two-dimensional Brillouin zone as well as by the histograms of the density of states. The main result is the appearance of absolute energy gaps in the two-dimensional band structure. 相似文献
96.
Baudron SA Batail P Rovira C Canadell E Clérac R 《Chemical communications (Cambridge, England)》2003,(15):1820-1821
Neutral pi-conjugated molecules and their radical cations co-exist in [(EDT-TTF-CONHMe+*)4(EDT-TTF-CONHMe0)2] [Re6Se8(CN)6]4- (CH3CN)2(CH2Cl2)2 whose crystal structure reveals that, upon one-electron oxidation, an activation of the N-H and C-H hydrogen bond donor ability is coupled to a deactivation of the hydrogen bond acceptor character of the carbonyl oxygen atom: this is expressed in the supramolecular hydrogen bond pattern and, ultimately, into charge localisation and partition in the solid state. 相似文献
97.
Vyskocil S Meca L Tislerová I Císarová I Polásek M Harutyunyan SR Belokon YN Stead RM Farrugia L Lockhart SC Mitchell WL Kocovský P 《Chemistry (Weinheim an der Bergstrasse, Germany)》2002,8(20):4633-4648
The title binaphthyls 19 and 26, which are the positional isomers of 2-methoxy-2'-(diphenylphosphino)-1,1'-binaphthyl (MOP, 19) and 2-amino-2'-hydroxy-1,1'-binaphthyl (NOBIN, 26), have been synthesized by Suzuki coupling as the key step (10 + 15-->18), followed by functional group transformations, involving C-P and C-N bond formation (18-->19 and 18-->23). Racemic intermediate 22 was resolved by co-crystallization with N-benzylcinchonidinium chloride and the absolute configuration determined by X-ray crystallography. These novel binaphthyls are configurationally stable and, as such, potentially usable as chiral ligands in asymmetric reactions. Michael addition of the glycine-derived enolate 40 to methyl acrylate, carried out in the presence of (R)-(-)-27 as the chiral phase-transfer catalyst, afforded L-glutamic acid (S)-(+)-43 of 92% ee (after hydrolysis of the primary product). 相似文献
98.
Ståhlberg J 《Journal of chromatography. A》2000,887(1-2):187-198
The fundamental migration theories for chromatography and electrophoresis are both based on a solution of the mass balance equation. The corresponding analysis for an electrochromatographic system has previously been published and is analysed in more detail in this paper. It is shown that the resulting equation, Eq. (8) in this paper, is in agreement with both electrophoretic and chromatographic theories and that when these migration modes are mixed a complicated migration behaviour emerge. These complications arise, if the comparison is done with electrophoretic theory, because the presence of the stationary phase creates a number of new restrictions on the system (electroneutrality on the stationary phase and simultaneous equilibrium for all components between the eluent and stationary phase). From a mathematical point of view, these restrictions make it difficult for the system to satisfy the coherence condition and this in turn may lead to an anomalous behaviour. To minimise the possibility for a complicated behaviour it is advisable to avoid too much mixing of the two migration mechanisms and/or to match the mobilities of the ionic components in the eluent phase with the mobility of the analyte ion. 相似文献
99.
Massue J Bellec N Chopin S Levillain E Roisnel T Clérac R Lorcy D 《Inorganic chemistry》2005,44(24):8740-8748
The reaction of tris(alkylthio)tetrathiafulvalene thiolates with 3-chloro-2,4-pentanedione affords tetrathiafulvalene (TTF) moieties substituted by the acetylacetone function (TTFSacacH), precursors of novel redox-active ligands: the acetylacetonate ions (TTFSacac). These TTFSacacHs have been characterized by X-ray diffraction analyses, and similar trends have been observed, such as a TTF core almost planar and the acetylacetone substituent located in a plane almost perpendicular to the plane formed by the TTF core. Their chelating ability has been demonstrated by the formation of the corresponding M(TTFSacac)2(pyridine)2 complexes in the presence of M(II)(OAc)2.H2O (M = Ni2+, Zn2+). These complexes with TTFSacac moieties, Ni(TTFSacac)2(pyridine)2, 6b, and Zn(TTFSacac)2(pyridine)2, 7b, have been characterized by X-ray diffraction analyses, showing in all structures the metal(II) center chelated by two TTFacac units in the equatorial plane and the octahedral coordination geometry around the metal completed by two axial pyridine ligands. Cyclic voltammetry and UV-visible-near infrared spectroscopic measurements have evidenced a sizable interaction between the two electroactive ligands and the stabilization of a mixed-valence state in the one-electron oxidized complexes. 相似文献
100.