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991.
Dr. Ana M. Garcia Dr. Roy Lavendomme Dr. Slavko Kralj Marina Kurbasic Ottavia Bellotto Maria C. Cringoli Dr. Sabrina Semeraro Dr. Antonella Bandiera Prof. Rita De Zorzi Prof. Silvia Marchesan 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(8):1880-1886
N-(4-Nitrobenzoyl)-Phe self-assembled into a transparent supramolecular hydrogel, which displayed high fibroblast and keratinocyte cell viability. The compound showed a mild antimicrobial activity against E. coli both as a hydrogel and in solution. Single-crystal XRD data revealed packing details, including protonation of the C-terminus due to an apparent pKa shift, as confirmed by pH titrations. MicroRaman analysis revealed almost identical features between the gel and crystal states, although more disorder in the former. The hydrogel is thermoreversible and disassembles within a range of temperatures that can be fine-tuned by experimental conditions, such as gelator concentration. At the minimum gelling concentration of 0.63 wt %, the hydrogel disassembles in a physiological temperature range of 39–42 °C, thus opening the way to its potential use as a biomaterial. 相似文献
992.
Silvia Gentiluomo Dr. Sanjay B. Thorat Dr. Antonio Esau Del Río Castillo Dr. Peter S. Toth Dr. Jaya Kumar Panda Dr. Vittorio Pellegrini Dr. Francesco Bonaccorso 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(29):6715-6725
One of the applications of graphene in which its scalable production is of utmost importance is the development of polymer composites. Among the techniques used to produce graphene flakes, the liquid-phase exfoliation (LPE) of graphite stands out due to its versatility and scalability. However, solvents suitable for the LPE process are generally toxic and have a high boiling point, making the processing challenging. The use of low boiling point solvents could be convenient for the processing, due to the easiness of their removal. In this study, the use of poly(methyl methacrylate) (PMMA) as a stabilizing agent is proposed for the production of graphene flakes in a low boiling point solvent, that is, acetone. The graphene dispersions produced in the mixture acetone-PMMA have higher concentration, +175 %, and contain a higher percentage of few-layer graphene flakes (<5 layers), that is, +60 %, compared to the dispersions prepared in acetone. The as-produced graphene dispersions are used to develop graphene/acrylonitrile-butadiene-styrene composites. The mechanical properties of the pristine polymer are improved, that is, +22 % in the Young's modulus, by adding 0.01 wt. % of graphene flakes. Moreover, a decrease of ≈20 % in the oxygen permeability is obtained by using 0.1 wt. % of graphene flakes filler, compared to the unloaded matrix. 相似文献
993.
Edgar Fuentes Kamila Boháčová Ana M. Fuentes-Caparrós Dr. Ralf Schweins Dr. Emily R. Draper Dr. Dave J. Adams Dr. Silvia Pujals Dr. Lorenzo Albertazzi 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(44):9869-9873
Self-assembly of fluorenylmethoxycarbonyl-protected diphenylalanine (FmocFF) in water is widely known to produce hydrogels. Typically, confocal microscopy is used to visualize such hydrogels under wet conditions, that is, without freezing or drying. However, key aspects of hydrogels like fiber diameter, network morphology and mesh size are sub-diffraction limited features and cannot be visualized effectively using this approach. In this work, we show that it is possible to image FmocFF hydrogels by Points Accumulation for Imaging in Nanoscale Topography (PAINT) in native conditions and without direct gel labelling. We demonstrate that the fiber network can be visualized with improved resolution (≈50 nm) both in 2D and 3D. Quantitative information is extracted such as mesh size and fiber diameter. This method can complement the existing characterization tools for hydrogels and provide useful information supporting the design of new materials. 相似文献
994.
Matteoli Enrico Lepori Luciano Porcedda Silvia 《Journal of Thermal Analysis and Calorimetry》2020,140(5):2409-2420
Journal of Thermal Analysis and Calorimetry - Excess molar volumes, VE, of binary mixtures of dibromomethane (DBM) with n-hexane, n-heptane, n-octane, cyclohexane, tetrachloromethane, dipropyl and... 相似文献
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Silva da Costa Russany Pinheiro Wandson Braamcamp de Souza Arruda Mara Silvia Pinheiro Costa Carlos Emmerson Ferreira Converti Attilio Ribeiro Costa Roseane Maria Silva Júnior José Otávio Carrera 《Journal of Thermal Analysis and Calorimetry》2022,147(1):275-284
Journal of Thermal Analysis and Calorimetry - Cupuassu (Theobroma grandiflorum Schum.) is a typical Amazonian fruit, whose seed is used as raw material to produce cupulate. The by-product of its... 相似文献
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The Skill Vehicle Routing Problem (Skill VRP) considers vehicle routing under the assumption of skill requirements given on demand nodes. These requirements have to be met by the serving vehicles. No further constraints, like capacity or cost restrictions, are imposed. Skill VRP solutions may show a tendency to have a bad load balancing and resource utilization. In a majority of solutions only a subset of vehicles is active. Moreover, a considerable share of demand nodes is served by vehicles that have a skill higher than necessary. A reason for that solution behavior lies in the model itself. As no resource restrictions are imposed, the Skill VRP tends to produce TSP-like solutions. To obtain better balanced solutions, we introduce two new approaches. First we propose a minmax model that aims at minimizing the maximal vehicle tour length. Second we suggest a two-step method combining the minmax approach with a distance constrained model. Our experiments illustrate that these approaches lead to improvements in load balancing and resource utilization, but, with different impact on routing costs. 相似文献
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