Hydrothermal synthesis, structure and property of nano-BaTiO3-based dielectric materials

A series of Ba_1-xSr_xTi_1-yZr_yO₃ (0≤x≤0.5, 0≤y≤0.4) and BA_1?xZn_xTi_1?ySn_yO₃ (0≤x≤0.3, 0≤y≤0.3) solid solutions were synthesized by low-temperature/low-pressure hydrothermal method below 170°C, 0.8 MPa. XRD pattern and cell parameters-composition figures of these prepared powders demonstrated that they are completely miscible solid solutions based on BaTiO₃. Furthermore, TEM showed that they have a shape of uniform, substantially spherical particles with an average particle size of 70 nm in diameter. The sintered ceramics of those powders doped by Sr²⁺ and Zr⁴⁺ or Zn²⁺ and Sn⁴⁺ have dielectric constant twelve times higher than and dielectric loss 1/6 those of pure BaTiO₃ phase at room temperature.     

含硒杂环萘二酰亚胺衍生物的合成及其场效应性能研究

萘二酰亚胺(NDI)类化合物由于其较好的平面性和较强的接受电子能力,被广泛应用于有机场效应晶体管(OFETs)和有机太阳能电池中(OSCs).然而,高迁移率的n型和双极性NDI类半导体材料较少.基于此,本文设计合成了核位硒杂环修饰的NDI衍生物,通过引入1,2-二硒苯和1,2-二硒萘基团,对其能级进行了有效的调控,获得...     

闪烁体瓦片/光纤量能器辐照损伤的进一步研究

研究了由不同闪烁体瓦片/光纤材料组成,或材料相同但构造不同的量能器模型的辐照损伤.用北京正负电子对撞机(BEPC)的电子试验束(1.1或1.3GeV)辐照了十个量能器模型.通过测量在不同累积剂量和在量能器内的不同位置上的光输出,对辐照损伤作出定量分析.还研究了损伤后的恢复及损伤与环境气体的关系.通过数据拟合发展了辐照损伤对剂量及对深度断面的校正方法.     

Millimeter-wave Low Sidelobe Time Modulated Linear Arrays with Uniform Amplitude Excitations

The study of millimeter-wave low sidelobe linear arrays with time modulation technique is presented in this paper. Special emphasis is on the realization of low sidelobes with uniform amplitude excitations, which are easier for the practical implementation. Two types of time modulated linear arrays with uniform amplitude excitations, namely, the variable aperture size (VAS) linear arrays with optimized time sequences and the linear arrays with optimized random time sequences were studied. The optimized time sequences are obtained via the differential evolution (DE) algorithm and the genetic algorithm (GA). Many factors that affect the array performance are discussed. Supported by the National Natural Science Foundation of China (No. 60571023), the SRF for ROCS, SEM, and the innovative Research Team Program of UESTC, China.     

Photorefractive properties for holographic application of Ce:Fe:LiNbO3 crystals with various [Li]/[Nb] ratios

Ce:Fe:LiNbO₃ crystals with various [Li]/[Nb] ratios were grown by the Czochralski method from melts having compositions varying between 48.6 and 58 mol% Li₂O. The Ce, Li and Nb concentrations in the grown Ce:Fe:LiNbO₃ crystals were analyzed by the inductively coupled plasma atomic emission spectrometer (ICP-AES). It was found that as the [Li]/[Nb] ratio increases in the melt, the [Li]/[Nb] ratio in the crystal and the distribution coefficients of Ce ions increase also. The photorefractive properties of the Ce:Fe:LiNbO₃ crystals were experimentally studied by the two-wave coupling method. The results show that as the [Li]/[Nb] ratio increases, the dynamic range decreases, but the photorefractive sensitivity and the signal-to-noise ratio improve. In a coherent volume 0.192 cm³ of a Ce:Fe:LiNbO₃ crystal with [Li]/[Nb] ratio of 1.2, 3800 holograms with 800×600 pixels have been successfully multiplexed in a compact volume holographic data storage system.     

三维约束下幂硬化双材料界面裂尖场分析

本文用Ｊ２形变理论分析了三轴应力约束下，由具有不同硬化指数和硬化系数的幂硬化材料构成的界面裂纹问题．通过在本构方程中引入三轴应力约束因子Ｔｚ，我们考虑了三维约束效应对裂尖场的影响．计算结果表明，三轴应力约束对裂尖场的分布，尤其是对径向应力σｒ和有效应力σｅ有重要影响．本文还探讨了三轴约束和材料性能对裂尖应力奇异性的影响     

All Organic Sodium‐Ion Batteries with Na4C8H2O6

Developing organic compounds with multifunctional groups to be used as electrode materials for rechargeable sodium‐ion batteries is very important. The organic tetrasodium salt of 2,5‐dihydroxyterephthalic acid (Na₄DHTPA; Na₄C₈H₂O₆), which was prepared through a green one‐pot method, was investigated at potential windows of 1.6–2.8 V as the positive electrode or 0.1–1.8 V as the negative electrode (vs. Na⁺/Na), each delivering compatible and stable capacities of ca. 180 mAh g^?1 with excellent cycling. A combination of electrochemical, spectroscopic and computational studies revealed that reversible uptake/removal of two Na⁺ ions is associated with the enolate groups at 1.6–2.8 V (Na₂C₈H₂O₆/Na₄C₈H₂O₆) and the carboxylate groups at 0.1–1.8 V (Na₄C₈H₂O₆/Na₆C₈H₂O₆). The use of Na₄C₈H₂O₆ as the initial active materials for both electrodes provided the first example of all‐organic rocking‐chair SIBs with an average operation voltage of 1.8 V and a practical energy density of about 65 Wh kg^?1.     

m线法研究掺杂LiNbO_3晶体波导基片的光损伤

采用ｍ线法研究了掺杂ＬｉＮｂＯ３晶体波导基片的光损伤，发现抗光损伤能力依次为Ｍｇ：ＬｉＮｂＯ３、ＬｉＮｂＯ３、Ｆｅ：ＬｉＮｂＯ３（氧化），Ｆｅ：ＬｉＮｂＯ３（还原）。对于同样材料，质子交换光波导的抗光损伤能力高于钛扩散光波导。     

微管液相色谱法同时测定白术中的白术内酯Ⅲ、白术内酯I和苍术酮

采用微管液相色谱法同时测定白术中的白术内酯Ⅲ、白术内酯I和苍术酮.采用美国Micro-tech Ultra plusⅡTM微管柱通用型二元梯度高效液相色谱仪和Microsil C18微管色谱柱(150 mm×1.0 mm),以甲醇-乙腈-水(A相体积比为90:5:5;B相体积比为55:5:40)为流动相,梯度洗脱,流速50μL/mm,在220 nm波长下检测.在上述色谱条件下,3种组分分离良好,在相应的进样质量范围内具有良好的线性关系.白术内酯Ⅲ、I和苍术酮的加标回收率分别为96.86%,97.13%和98.06%;相对标准偏差分别为1.63%,1.31%和0.39%.该法简便、快捷,能够用于白术的质量控制.