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111.
A new coordination mode of hydrotris(2-mercaptoimidazolyl)borate ligands was found in the reaction of [Na(Tm(tBu))] with Me(2)BiCl to form a trinuclear organobismuth complex [(Me(2)Bi)(3)(Tm(tBu))(2)](+)[Me(2)BiCl(2)](-)(Tm(tBu)= hydrotris(2-mercapto-1-tert-butylimidazolyl)borate). 相似文献
112.
A new aromadendrane-type sesquiterpenoid, 4(15)-aromadendren-12,5alpha-olide and an aromadendrane-guaianolide dimer have been isolated from the New Zealand liverwort Chiloscyphus subporosus. Their structures were established by extensive NMR techniques and X-ray crystallographic analysis. 相似文献
113.
It was found that the periodic change of the solution viscosity and density was generated in the Belousov-Zhabotinsky (BZ) reaction. This rhythmic phenomenon was observed in both the iron catalyst [[Fe(Phen)(3)](2+)-[Fe(Phen)(3)](3+)] and the cerium catalyst [Ce(III)-Ce(IV)] system, where the solution viscosity and density were synchronized with the redox potential in the in-phase mode. However, the time delay existed between the redox potential and the solution viscosity and density. The behavior of the BZ reaction was also monitored in the presence of the nonionic surfactant. This experiment revealed that, beyond the critical micelle concentration, the phase between the redox potential and the solution viscosity and density was synchronized into the antiphase mode. We suggested that the variation of the catalyst drove the oscillation of the solution viscosity and density in the BZ reaction. 相似文献
114.
Matsunaga S Watanabe S Sakaushi S Miyamura S Hori T 《Photochemistry and photobiology》2003,77(3):324-332
We found diaphototactic behavior (i.e. the cells swim perpendicularly with respect to the incident light) in a strain with colorless eyespot of a unicellular disk-shaped green flagellate Mesostigma viride. Lacking pigments completely in the eyespot, the screening effect in this strain was due only to the central part of the chloroplast whose cross section was thin. The diaphototaxis was most obvious when unilateral green stimulus light (520-580 nm) was given, whereas positive phototaxis appeared when given blue light (430-490 nm). The choice between diaphototaxis and (ordinary) phototaxis depended entirely on the transmission (%T) of the cell body against each wavelength of the stimulus: the green light penetrated well (%T > 90%), whereas the blue light was considerably shaded by the chloroplast (50% < %T < 70%). The fraction of positive phototactically behaving cells against each wavelength was in proportion to the front-to-back contrast value obtained at each individual wavelength. The fraction of diaphototaxis was inversely proportional to it. In addition, bilateral stimulus irradiations to wild-type cell with colored eyespot provided useful information about the principle of the diaphototactic steering. 相似文献
115.
Signal denoising and baseline correction by discrete wavelet transform for microchip capillary electrophoresis 总被引:1,自引:0,他引:1
Signal denoising and baseline correction using discrete wavelet transform (DWT) are described for microchip capillary electrophoresis (MCE). DWT was performed on an electropherogram describing a separation of nine tetramethylrohodamine-5-isothiocyanate labeled amino acids, following MCE with laser-induced fluorescence detection, using Daubechies 5 wavelet at a decomposition level of 6. The denoising efficiency was compared with, and proved to be superior to, other commonly used denoising techniques such as Fourier transform, Savitzky-Golay smoothing and moving average, in terms of noise removal and peak preservation by directly visual inspection. Novel strategies for baseline correction were proposed, with a special interest in baseline drift that frequently occurred in chromatographic and electrophoretic separations. 相似文献
116.
Hori A Kataoka H Okano T Sakamoto S Yamaguchi K Fujita M 《Chemical communications (Cambridge, England)》2003,(2):182-183
The reversible cross-catenation of two different coordination rings (Pd(II)- and Pt(II)-linked rings) has been achieved by using the labile nature of the Pd-N interaction and efficient hydrophobic contact between the rings. 相似文献
117.
118.
Guangming Xie Shigeru Kobayashi Hidetoshi Marubayashi Nicolea Popescu Constantin Vraciu 《Results in Mathematics》2003,43(3-4):373-379
We consider extensions of a total valuation ring V of a skew field K to the Ore extension K(X;σ, δ) for an endomorphism σ of K and a σ-derivation δ. It is shown that there exists an extension R of V with X ∈ R, such that ${\overline X}$ is transcendental over V/J(V) if and only if (σ,δ) is compatible with V, where ${\overline X} = X + J(R^(1))$ . In the case V is invariant, it is established that there is an invariant extension R of V in K(X;σ,δ) such that ${\overline X}$ is transcendental if and only if σ(a)V = aV and δ(a) ∈ aV for all a ∈ K. 相似文献
119.
Shigeru Odaka Yoshimasa Kurihara 《The European Physical Journal C - Particles and Fields》2007,51(4):867-873
We are developing a consistent method to combine tree-level event generators for hadron collision interactions with those
including one additional QCD radiation from the initial-state partons, based on the limited leading-log (LLL) subtraction
method, aiming at an application to NLO event generators. In this method, a boundary between non-radiative and radiative processes
necessarily appears at the factorization scale (μF). The radiation effects are simulated using a parton shower (PS) in non-radiative processes. It is therefore crucial in our
method to apply a PS which well reproduces the radiation activities evaluated from the matrix-element (ME) calculations for
radiative processes. The PS activity depends on the applied kinematics model. In this paper we introduce two models for our
simple initial-state leading-log PS: a model similar to the ’old’ PYTHIA-PS and a pT-prefixed model motivated by ME calculations. PS simulations employing these models are tested using W-boson production at
LHC as an example. Both simulations show a smooth matching to the LLL subtracted W+1 jet simulation in the pT distribution of W bosons, and the summed pT spectra are stable against a variation of μF, despite that the pT-prefixed PS results in an apparently harder pT spectrum. 相似文献
120.
Shigeru Sasaki 《Journal of organometallic chemistry》2011,696(21):3307-3315
The sterically crowded triarylphosphines bearing formyl and benzoyl groups were synthesized and characterized by X-ray crystallography. The benzoyl derivative was converted to the p-quinomethane conjugated with the triarylphosphine. The McMurry coupling of the formyl derivative afforded the diarylethene bearing the two sterically-crowded-triarylphosphine moieties. The cyclic voltammograms of these compounds show reversible redox waves corresponding to the oxidation to the radical cations of the triarylphosphines and irreversible or quasi-reversible waves corresponding to the reduction of the acceptor moieties. The electronic and the fluorescence spectra of these π-conjugated systems, especially push-pull substituted derivatives, exhibit bathochromic shift typical of the extended π-conjugated systems especially in the polar solvent, and the large Stokes shift typical of the crowded triarylphosphines is enhanced by conjugation with the acceptor moiety. 相似文献