低损耗193 nm增透膜

计算了适用于193nm增透膜设计与制备的基底与薄膜材料的光学常数,并在此基础上对193nm增透膜进行了设计、制备与性能分析.发现基底材料的吸收损耗对增透膜元件的影响很大,超过一定值时,增透膜元件的设计透过率将达不到理想水平.对单面增透膜的设计与制备结果表明,当吸收损耗降低到一定程度,散射损耗成为不可忽略的因素.采用热舟蒸发方法实现了性能良好的193 nm减反射膜,剩余反射率在0.2%以下. 关键词： 193nm 增透膜 光学损耗 剩余反射率     

In0.53 Ga0.47As/In0.52Al0.48As量子阱中双子带占据的二维电子气的输运特性

研究了不同沟道厚度的In0.53 Ga0.47As/In0.52Al0.48As量子阱中双子带占据的二维电子气的输运特性.在考虑了两个子带电子之间的磁致子带间散射效应后,通过分析Shubnikov-de Haas振荡一阶微分的快速傅里叶变换结果,获得了每个子带电子的浓度、输运散射时间、量子散射时间以及子带之间的散射时间.结果表明,对于所研究的样品,第一子带电子受到的小角散射更强,这与第一子带电子受到了更强的电离杂质散射有关.     

Scaling of the local convective heat flux in turbulent Rayleigh-Bénard convection

Local convective heat flux J(r) in turbulent thermal convection is obtained from simultaneous velocity and temperature measurements in a cylindrical cell filled with water. The measured J(r) in the bulk region shows a different scaling behavior with varying Rayleigh numbers compared with that measured in the plume-dominated regions near the sidewall and near the lower conducting plate. The local transport measurements thus allow us to disentangle boundary and bulk contributions to the total heat flux and directly check their respective scaling behavior against the theoretical predictions.     

光信息与光电子技术实验室建设的思考

本文简要介绍了天津工业大学光信息与光电子技术实验室的现状,并对实验室在"十一五"期间的建设思路与目标以及建设内容等进行了全面的介绍.     

A Novel Hg<Superscript>2+</Superscript> Selective Ratiometric Fluorescent Chemodosimeter Based on an Intramolecular FRET Mechanism

A irreversible Hg²⁺ selective ratiometric fluorescence probe FR, a fluorescein fluorophore linked to a rhodamine B hydrazide by a thiourea spacer, was designed and synthesized. The developed probe FR exhibited great ratiometric fluorescence enhancement and remarkable yellow-magenta color change toward Hg²⁺ with excellent selectivity in aqueous acetone solution, and the ratiometric fluorescence response to Hg²⁺ was not interfered by other metal cations including Fe³⁺, Co²⁺, Ni²⁺, Cr³⁺, Zn²⁺, Pb²⁺, Cd²⁺, Ca²⁺, Mg²⁺, Ba²⁺ and Mn²⁺. The linear range and the detection limit of this supposed ratiometric fluorescence method for Hg²⁺ were 0.0–10.0 × 10⁻⁶ and 5 × 10⁻⁸ M, respectively.     

Cohesive zone modeling of interfacial delamination in PZT thin films

Previous experimental investigations [Shang, F., Kitamura, T., Hirakata, H., Kanno, I., Kotera, H., Terada, K., 2005. Experimental and theoretical investigations of delamination at free edge of interface between piezoelectric thin films on a substrate. International Journal of Solids and Structures 42 (5–6) 1729–1741] have demonstrated that multilayered Cr/PZT/PLT/Pt/Ti thin films deposited on single-crystal silicon substrates are delaminated along the interface between Cr and PZT layers in a brittle manner. This study starts with a model based on the cohesive zone concept and carries out numerical simulations to check the fracture behavior of this interfacial delamination. Three types of cohesive zone models (CZMs) are adopted, including the exponential, bilinear, and trapezoidal models. Characteristic CZM parameters are extracted through comparisons with experimental results. The simulation results show that (i) cohesive strength and work of separation are the dominating parameters in the CZMs; (ii) the bilinear CZM more suitably describes this brittle interfacial delamination; and (iii) in comparison with typical several mm-thick film/coating materials, the fracture energy of this weak Cr/PZT interface is quite low. Our study demonstrates the applicability of CZM in characterizing the interface fracture behavior of film materials with micrometer thicknesses.     

A label-free electrochemical immunosensor based on multi-functionalized graphene oxide for ultrasensitive detection of microcystin-LR

In this paper, a label-free electrochemical immunosensor for ultrasensitive detection of microcystin-leucine-arginine (MC-LR) based on multi-functionalized graphene oxide was constructed. The graphene oxide has a large surface area for the immobilization of the antibody. Meanwhile, the introduction of the AuNPs and 1-butyl-3-methylimidazolium hexafluorophosphate could enhance the response of the current by improving the electrical conductivity. Thus the electrochemical immunosensor could be prepared through a one-step process and differential pulse voltammetry was employed to detect sensitively MC-LR. Under optimal conditions, the current response of the immunosensor decreased proportionally to the logarithmic concentrations of MC-LR in the range of 0.1–1000 ng/mL with a detection limit of 0.1 ng/mL (S/N = 3). This one-step label-free electrochemical immunosensor showed good performance in specificity, stability, reproducibility, and application.     

Site‐Selective 1,2‐Dicarbofunctionalization of Vinyl Boronates through Dual Catalysis

A modular, site‐selective 1,2‐dicarbofunctionalization of vinyl boronates with organic halides through dual catalysis is described. This reaction proceeds under mild conditions and is characterized by excellent chemo‐ and regioselectivity. It thus represents a complementary new technique for preparing densely functionalized alkyl boron architectures from simple and accessible precursors.     

机敏柔性梁的振动主动控制

提出了用于机敏结构中振动主动控制的仿人控制算法,对压电阻尼技术进行了理论和实验研究,给出了传感器,执行器和受控结构之间的关系,用ＰＺＴ作执行元件实现了柔性梁振动主动控制系统,给出了实验结果。     

The study of thermal decomposition kinetics of zinc oxide formation from zinc oxalate dihydrate

This study is devoted to the thermal decomposition of ZnC₂O₄·2H₂O, which was synthesized by solid-state reaction using C₂H₂O₄·2H₂O and Zn(CH₃COO)₂·2H₂O as raw materials. The initial samples and the final solid thermal decomposition products were characterized by Fourier transform infrared and X-ray diffraction. The particle size of the products was observed by transmission electron microscopy. The thermal decomposition behavior was investigated by thermogravimetry, derivative thermogravimetric and differential thermal analysis. Experimental results show that the thermal decomposition reaction includes two stages: dehydration and decomposition, with nanostructured ZnO as the final solid product. The Ozawa integral method along with Coats–Redfern integral method was used to determine the kinetic model and kinetic parameters of the second thermal decomposition stage of ZnC₂O₄·2H₂O. After calculation and comparison, the decomposition conforms to the nucleation and growth model and the physical interpretation is summarized. The activation energy and the kinetic mechanism function are determined to be 119.7 kJ mol^?1 and G(α) = ?ln(1 – α)^1/2, respectively.