全文获取类型
收费全文 | 17303篇 |
免费 | 2514篇 |
国内免费 | 2442篇 |
专业分类
化学 | 12723篇 |
晶体学 | 245篇 |
力学 | 950篇 |
综合类 | 235篇 |
数学 | 2078篇 |
物理学 | 6028篇 |
出版年
2024年 | 33篇 |
2023年 | 198篇 |
2022年 | 408篇 |
2021年 | 475篇 |
2020年 | 501篇 |
2019年 | 568篇 |
2018年 | 505篇 |
2017年 | 503篇 |
2016年 | 769篇 |
2015年 | 807篇 |
2014年 | 1049篇 |
2013年 | 1322篇 |
2012年 | 1419篇 |
2011年 | 1571篇 |
2010年 | 1207篇 |
2009年 | 1207篇 |
2008年 | 1387篇 |
2007年 | 1242篇 |
2006年 | 1186篇 |
2005年 | 1064篇 |
2004年 | 849篇 |
2003年 | 686篇 |
2002年 | 835篇 |
2001年 | 554篇 |
2000年 | 462篇 |
1999年 | 316篇 |
1998年 | 227篇 |
1997年 | 155篇 |
1996年 | 137篇 |
1995年 | 96篇 |
1994年 | 82篇 |
1993年 | 70篇 |
1992年 | 66篇 |
1991年 | 50篇 |
1990年 | 41篇 |
1989年 | 47篇 |
1988年 | 37篇 |
1987年 | 21篇 |
1986年 | 17篇 |
1985年 | 18篇 |
1984年 | 9篇 |
1983年 | 7篇 |
1982年 | 4篇 |
1981年 | 3篇 |
1980年 | 9篇 |
1979年 | 6篇 |
1978年 | 14篇 |
1977年 | 3篇 |
1976年 | 4篇 |
1966年 | 2篇 |
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
121.
Zhi‐Yong Huang Jin‐Can Shen Zhi‐Xia Zhuang Xiao‐Ru Wang Frank S. C. Lee 《应用有机金属化学》2004,18(6):255-261
Cinnabar, as one of the most widely used mineral drugs in traditional Chinese medicines, has been proven to have prominent curative effects in clinical use for more than 2000 years. But the safety and toxicity of the drug has been under constant debate in clinic usage. Metallothionein (MT) contains about 30% of cysteine in the molecule, and plays an important detoxification role against heavy metals. In this study, it was used as a biomarker to assess mercurial accumulation in rats fed orally with cinnabar. After feeding rats with cinnabar by gastric gavage at different dosages and at different times, the distribution of heavy metals (including mercury, copper and zinc) and MT was investigated among rat tissues, including liver, kidney, heart, brain, testis and blood. Metals and MT determinations were carried out using inductively coupled plasma mass spectrometry (ICP‐MS) and a modified mercury saturation assay technique respectively. The results indicated that mercury was easily accumulated in the tissues of rats exposed to cinnabar, especially in kidney. For example: at a feeding dosage of 5 g kg?1 (bw) for 4 weeks, the mercury concentrations in kidney were 13, 8.7, 21.6 and 26 times those in liver, testis, brain and heart respectively; and at 2.5 g kg?1 (bw) for 2 weeks, the mercury concentrations in kidney were 21, 2.1, 3 and 21 times those in liver, testis, brain and heart respectively. In addition, mercury in kidney and liver of all cinnabar groups was significantly higher than that of the control group (P < 0.01). A high positive correlation observed between MT concentrations and mercury levels in both liver and kidney (R2 = 0.9299, P < 0.02 for liver; R2 = 0.9923, P < 0.0008 for kidney) indicated that MT could be used as a biomarker for mercury in tissues. Copyright © 2004 John Wiley & Sons, Ltd. 相似文献
122.
In this paper, a projection method is presented for solving the flow problems in domains with moving boundaries. In order to track the movement of the domain boundaries, arbitrary‐Lagrangian–Eulerian (ALE) co‐ordinates are used. The unsteady incompressible Navier–Stokes equations on the ALE co‐ordinates are solved by using a projection method developed in this paper. This projection method is based on the Bell's Godunov‐projection method. However, substantial changes are made so that this algorithm is capable of solving the ALE form of incompressible Navier–Stokes equations. Multi‐block structured grids are used to discretize the flow domains. The grid velocity is not explicitly computed; instead the volume change is used to account for the effect of grid movement. A new method is also proposed to compute the freestream capturing metrics so that the geometric conservation law (GCL) can be satisfied exactly in this algorithm. This projection method is also parallelized so that the state of the art high performance computers can be used to match the computation cost associated with the moving grid calculations. Several test cases are solved to verify the performance of this moving‐grid projection method. Copyright © 2004 John Wiley Sons, Ltd. 相似文献
123.
Hye-Sun Jeon 《Tetrahedron letters》2004,45(38):7023-7026
Allylic sulfones undergo the conjugate addition to diethyl chloroisopropylidenemalonate, followed by intramolecular cyclopropanation. DBU-promoted ring opening and subsequent desulfonation reactions of the resulting adduct produce the conjugated polyene chains with the 1,4-dimethyl substitution. 相似文献
124.
Seung Min Lee 《Operations Research Letters》2003,31(4):268-272
A continuum structure function is a non-decreasing mapping from the unit hypercube to the unit interval. Within the class of continuum structure functions, new axiomatic characterizations of the Natvig and the Barlow-Wu subclass are obtained. 相似文献
125.
Ha Yong Lee Se Hun Jung Soo Yong Lee Young Ho You Kyung Hyun Ko 《Applied Surface Science》2005,252(5):1891-1898
Al-Al2O3 composite coatings with different Al2O3 particle shapes were prepared on Si and Al substrate by cold spray. The powder compositions of metal (Al) and ceramic (Al2O3) having different sizes and agglomerations were varied into ratios of 10:1 wt% and 1:1 wt%. Al2O3 particles were successfully incorporated into the soft metal matrix of Al. It was found that crater formation between the coatings and substrate, which is typical characteristic signature of cold spray could be affected by initial starting Al2O3 particles. In addition, when the large hard particles of fused Al2O3 were employed, the deep and big craters were generated at the interface between coatings and hard substrates. In the case of pure soft metal coating such as Al on hard substrate, it is very hard to get proper adhesion due to lack of crater formation. Therefore, the composite coating would have certain advantages. 相似文献
126.
127.
CHEN Yong YAN Zhen-Ya 《理论物理通讯》2005,44(5):789-792
Recently some (1+1)-dimensional nonlinear wave equations with linearly dispersive terms were shown to possess compacton-like and solitary pattern-like solutions. In this paper, with the aid of Maple, new solutions of (2+1)- dimensional generalization of mKdV equation, which is of only linearly dispersive terms, are investigated using three new transformations. As a consequence, it is shown that this (2+1)-dimensional equation also possesses new compacton-like solutions and solitary pattern-like solutions. 相似文献
128.
Differential FBG sensor for temperature-compensated high-pressure (or displacement) measurement 总被引:2,自引:0,他引:2
A differential fiber Bragg grating (FBG) sensor with a free active element bulk-modulus for high-pressure (or displacement) measurement is presented. Based on the differential measurement method and an isosceles triangle cantilever structure, problems of cross-sensitivity and chirped signal in FBG sensor are improved both theoretically and experimentally. Preliminary experiments indicate that temperature-compensated measurement results agree well with the theoretical analysis. Displacement measurement sensitivity is 1.75 pm/μm, and the estimated pressure measurement resolution can reach 0.27 MPa in case the wavelength shift measurement resolution is 0.01 nm. 相似文献
129.
CunLiuZHOU YuQingZHOU ZhiYongWANG 《中国化学快报》2003,14(4):355-358
The chemoselective addition of aldehydes in aquoues medium was obtained under mild condition using improved Henry reaction. 相似文献
130.